Silica fume and carbide slag can be used to modify waste mud soil (WMS), which can not only improve the mechanical properties of WMS, but also broaden resource utilization ways of silica fume and carbide slag. For that, in this paper, WMS was modified by adopting 8 % carbide slag and silica fume with different dosages (0, 3 %, 5 %, 7 %, 9 %, and 11 %). Then the small-strain dynamic properties of modified WMS were investigated by using resonance column test, and the microscopic mechanism of modified WMS was analyzed based on Scanning electron microscopy (SEM), Energy dispersive X-ray spectrometer (EDS), Transmission electron microscopy (TEM), X-ray diffraction test (XRD) and Mercury intrusion porosimetry (MIP). It can be found from the resonance column test that the dynamic shear modulus and the damping ratio show an increasing and decreasing trend with the increase of the confining pressure respectively, and both increase with increasing silica fume dosage in the range of 0 to 11 %. A kinetic model applicable to modified WMS was established by introducing the effects of confining pressure and silica fume into the Hardin-Drnevich model. Microscopic testing experiments indicate that there is a reaction between reactive SiO2 in silica fume and Ca(OH)2 in carbide slag, and calcium hydrated silicate (CSH) was generated, which improved the specimen density.
This study developed a novel geopolymer (RM-SGP) using industrial solid wastes red mud and slag activated by sodium silicate, aiming to remediate composite heavy metal contaminated soil. The effects of aluminosilicate component dosage, alkali equivalent, and heavy metal concentration on the unconfined compressive strength (UCS), toxicity leaching characteristics, resistivity, pH, and electrical conductivity (EC) of RM-SGP solidified composite heavy metal contaminated soil were systematically investigated. Additionally, the chemical composition and microstructural characteristics of solidified soil were analyzed using XRD, FTIR, SEM, and NMR tests to elucidate the solidification mechanisms. The results demonstrated that RM-SGP exhibited excellent solidification efficacy for composite heavy metal contaminated soil. Optimal performance occurred at 15 % aluminosilicate component dosage and 16 % alkali equivalent, achieving UCS >350 kPa and compliant heavy metal leaching (excluding Cd in high-concentration groups). Acid/alkaline leaching tests revealed distinct metal behaviors: Cu/Cd decreased progressively, while Pb initially declined then rebounded. Microstructural analysis indicated that RM-SGP generated abundant hydration products (e.g., C-A-S-H, N-A-S-H gels), which acted as cementitious substances wrapping soil particles and filling and connecting pores, thereby increasing the soil's compactness and improving the solidification effect. Furthermore, heavy metal ions were solidified through adsorption, encapsulation, precipitation, ion exchange, and covalent bond et al., transforming their active states into less bioavailable forms, proving novel insights into the remediation of composite heavy metal contaminated soils and the resource utilization of industrial solid wastes.
Water-induced disintegration is a critical issue in soil stabilization. In this study, soda residue (SR) and fly ash (FA) were mixed to improve the properties of high liquid limit clay (HLC), forming soda residue-fly ash stabilized clay (SRFSC), with cement and/or lime for further stabilization. The mix proportions of the SRFSC were optimized by the orthogonal method, using the compaction, unconfined compressive strength, shear, and disintegration tests. Meanwhile, microscopic tests were performed to reveal the possible mechanical mechanisms. The results showed that the SR and FA content are the primary determinants influencing the mechanical properties of SRFSC. When the base proportion is 70 % SR + 20 % FA + 10 % HLC, the strength is highest (2.45 MPa). At this proportion, the specimen with no cementitious material exhibits the best water disintegration resistance (WDR), reaching 107 min. Adding cement and lime can significantly enhance the WDR of the SRFSC, from complete disintegration at 0.28 min to remaining intact after soaking for 28 days. During field application, the cementitious materials content can be adjusted according to the actual conditions. The superior mechanical properties and WDR of SRFSC are mainly due to the good gradation and dense microstructure. The soda residue can provide abundant Ca2+ to enhance both the mechanical properties and WDR of SRFSC.
Red mud is a kind of solid waste, which can be used as engineering roadbed filler after proper treatment. Due to the special physical and chemical properties of red mud, such as high liquid limit and high plasticity index, it may affect the stability of soil. Therefore, red mud can be improved by adding traditional inorganic binders such as lime and fly ash to improve its road performance as roadbed filler. Red mud-based modified silty sand subgrade filler will be affected by dry-wet alternation caused by various factors in practical application, thus affecting the durability of the material. In order to study the strength degradation characteristics and microstructure changes of red mud, lime and fly ash modified silty sand subgrade filler after dry-wet cycle, the samples of different curing ages were subjected to 0 similar to 10 dry-wet cycles, and their compressive strength, microstructure and environmental control indexes were tested and analyzed. The results show that the sample cured for 90 days has the strongest toughness and the best ability to resist dry and wet deformation. With the increase of the number of dry-wet cycles, the mass loss rate of the sample is in the range of 6 similar to 7 %, and the unconfined compressive properties and tensile properties decrease first and then increase. There are continuous hydration reactions and pozzolanic reactions in the soil, but the degree of physical damage in the early stage of the dry-wet cycle is large, and the later cementitious products have a certain offsetting effect on the structural damage. The internal cracks of the sample without dry-wet cycle are less and the structure is dense. After the dry-wet cycle, the microstructure of the sample changed greatly, and the cracks increased and showed different forms. Through SEM image analysis, it was found that the pore structure of the sample changed during the dry-wet cycle, which corresponded to the change law of mechanical properties. After wetting-drying cycles, the leaching concentration of heavy metals in the modified soil increased slightly, but the overall concentration value was low, which was not a toxic substance and could be used as a roadbed material. The study reveals the influence of dry-wet cycle on the strength characteristics and microstructure of red mud, lime and fly ash synergistically improved silty sand, which provides a technical reference for the engineering application of red mud-based materials.
The infiltration and degradation of domestic contaminants have a substantial influence on the mechanical properties of soil. Sucrose is one of the oligosaccharide contaminants with high content and is prone to degradation in domestic-source contaminants. In this study, a series of tests were conducted to investigate the changes in the mechanical properties of clayey soil during the sucrose degradation process. First, in different concentrations of sucrose-contaminated soil, the organic matter content during the sucrose degradation process was measured to analyze its degradation characteristics. During the degradation process, the unconfined compressive strength and compression coefficient of the soil were measured to analyze the changes in its mechanical properties. Finally, the changes in the permeability coefficient and microstructure of the soil were analyzed in depth. The findings indicated that the degradation of sucrose and the associated alterations in the mechanical properties of contaminated soil were concentration-dependent. The effect mechanism involved the formation of organic-clay flocs during the early stages of degradation and the alkaline oxides' dissolution in the later stages. These findings contribute to a deeper understanding of the impact of domestic-source pollution on soil and provide references for the reinforcement of contaminated soil.
This study developed all-solid-waste-based curing agents using industrial solid wastes-ground granulated blastfurnace slag (GGBS), carbide slag (CS), and sulfate solid wastes (electrolytic manganese residue (EMR), desulfurized-gypsum (DG), and phosphogypsum (PG))-to stabilize engineering sediment waste (ESW). Based on the simplex centroid design, three ternary curing agents (GGBS-EMR-CS (GEC), GGBS-DG-CS (GDC), and GGBSPG-CS (GPC)) were prepared. The optimal ratios for GEC, GDC, and GPC are 60:12:28, 70:27:3, and 70:21:9, respectively. Compared to ordinary Portland cement (OPC), the unconfined compressive strength (UCS) of ESW stabilized with these curing agents increased by 78 %, 178 %, and 98 %, respectively. Sulfate components synergistically activates GGBS and CS, promoting needle-like ettringite (AFt) formation, which fills pores and enhances strength. Meanwhile, COQ emissions and costs were reduced up to 99 % and 73 %, respectively. This study developed all-solid-waste-based curing agents with excellent mechanical performance, low costs, and near net-zero emissions, which provided a sustainable solution for ESW stabilization.
As a prevalent problematic soil in geotechnical engineering, organic-rich soil exhibits inferior engineering characteristics that necessitate stabilization treatment in practical applications. Among various soil improvement techniques, chemical stabilization using Portland cement (PC) has gained widespread adoption due to its operational convenience. However, conventional PC involves not only environmental burdens associated with resource- and energy-intensive production processes and carbon emissions but also substantial interference from organic matter (OM) during its hydration process, inhibiting the formation of cementitious bonds. To address these challenges, this study proposes an innovative green stabilization approach using reactive MgO carbonation technology. A comprehensive investigation was conducted to evaluate the physicochemical evolution, mechanical behavior, and microstructural characteristics of organic soils under varying OM contents and carbonation durations. Key findings revealed that unconfined compressive strength demonstrated a linear inverse relationship with OM content while exhibiting time-dependent enhancement during carbonation. Strength development correlated positively with mass gain and dry density but inversely with water content. Microanalytical results indicated OM-dependent phase transformations, showing decreased nesquehonite crystallization and increased dypingite/hydromagnesite formation with ascending OM content. Mechanism analysis suggested that OM content regulated carbonation product speciation and aggregate morphology, thereby governing the coupled processes of particle cementation, pore structure refinement, and mechanical strengthening. This research demonstrates the technical viability of MgO carbonation for organic soil stabilization while contributing to sustainable geotechnical practices through carbon sequestration.
Expanded Polystyrene (EPS) granular lightweight soil (ELS) is an eco-friendly material made of EPS particles, cement, soil, and water. This study investigates the modification of ELS using a silane coupling agent (SCA) solution to improve its performance. Various tests were performed, including flowability, dry shrinkage, unconfined compressive strength (UCS), triaxial, hollow torsional shear, and scanning electron microscopy (SEM) analysis, to evaluate the physical and mechanical properties at different SCA concentrations. The results show that the optimal SCA concentration was 6%, improving flowability by 13% and increasing dry shrinkage weight by 4%. The UCS increased with SCA concentration, reaching 266 and 361 kPa after 7 and 28 days, respectively, at 6% SCA. Triaxial and shear tests indicated improved shear strength, with the maximum shear strength reaching 500 kPa, internal friction angle rising by 4%, and cohesion reaching 114 kPa at 6% SCA. Hollow torsion shear tests showed that 6% SCA enhanced stiffness and resistance to deformation, while reducing the non-coaxial effect. SEM analysis revealed that SCA strengthened the bond between EPS particles and the cement matrix, improving the interfacial bond. This study highlights the potential of modified ELS for sustainable construction.
Foamed lightweight soil (FLS) is frequently used for roadbed backfilling; however, excessive cement use contributes to higher costs and energy consumption. Desulfurized gypsum (DG), a by-product of industrial processing with a chemical composition similar to natural gypsum, presents a viable alternative to cement. This study evaluates the potential of DG to replace cement in FLS, creating a new material, desulfurized gypsum foamed lightweight soil (DG-FLS). This article is conducted on DG-FLS with varying DG content (0-30%) to assess its flowability, water absorption, unconfined compressive strength (UCS), durability, and morphological characteristics, with a focus on its suitability for roadbed backfilling, though its performance over the long term in engineering applications was not evaluated. Results show that as DG content increased, flowability, water absorption, and UCS decreased, with values falling within the range of 175-183 mm, 8.24-12.49%, and 0.75-2.75 MPa, respectively, all of which meet embankment requirements. The inclusion of DG enhanced the material's plasticity, improving failure modes and broadening its applicability. Durability tests under wet-dry and freeze-thaw cycles showed comparable performance to traditional FLS, with UCS exceeding 0.3 MPa. Additionally, the incorporation of SO42- in DG-FLS reduced sulfate diffusion, decreased C-S-H content, and increased calcium sulfate content, improving sulfate resistance. After 120 days of exposure to sulfates, the durability coefficient of DG-FLS surpassed 100%, with a 25% improvement over traditional FLS. A sustainability analysis revealed that DG-FLS not only meets engineering strength requirements but also offers economic and environmental benefits. Notably, DG-12 showed a 20% reduction in environmental impact compared to conventional FLS, underscoring its potential for more sustainable construction.
Targeting the engineering properties of poor strength and susceptibility to damage in roadbeds and slopes within clay regions, xanthan gum is employed as a soil enhancer, concurrently addressing the issue of the low utilization rate of plant coir fiber. The unconfined compressive strength test (UCS) is used to analyze the influence of different maintenance methods, maintenance duration, xanthan gum dosage, and coconut fiber dosage on the mechanical properties of the enhanced soil. Furthermore, based on scanning electron microscope (SEM) tests, the underlying mechanisms governing the mechanical properties of fiber-reinforced xanthan gum-improved soil are uncovered. The results indicated that the compressive strength of amended soil is significantly enhanced by the incorporation of xanthan gum and coir fiber. After 28 days of conditioning, the compressive strength of the amended soil under dry conditions (conditioned in air) was significantly higher (3 MPa) than that under moist conditions (conditioned in plastic wrap) (0.57 MPa). Xanthan gum influenced both the compressive strength of the specimens and the degree of strength enhancement, whereas coir fibers not only augmented the strength of the specimens but also converted them from brittle to ductile, thereby imparting residual strength post-destruction. Microscopic analysis indicates that the incorporation of xanthan gum and coconut shell fiber significantly diminishes the number of pores and cracks within the soil matrix, while enhancing the internal inter-particle cementation. This synergistic effect contributes to soil improvement, providing theoretical and technical guidance for roadbed enhancement and slope repair.