The interface between geotextile and geomaterials plays a crucial role in the performance of various geotechnical structures. Soil-geotextile interfaces often suffer reduced performance under environmental stressors such as rainfall and cyclic loading, limiting the reliability of geotechnical structures. This study examines the influence of gravel content (Gc), compaction degree (Cd), and rainfall duration (Rd) on the mobilized shear strength at the silty clay-gravel mixture (SCGM)- geotextile interface through a comprehensive series of direct shear tests under both static and cyclic loadings. A novel approach using Polyurethane Foam Adhesive (PFA) injection is introduced to enhance the interface behavior. The results reveal that increasing Gc from 0 % to 70 % leads to a 35-70 % improvement in mobilized shear strength and friction angle, while cohesion decreases by 15 %-60 %, depending on Cd. A higher Cd further boosts shear strength by 6 %- 70 %, influenced by Gc and normal stress levels. Under cyclic loading, increasing displacement amplitude reduces shear stiffness (K), while having minimal impact on the damping ratio (D); K and D appear unaffected by the number of cycles in non-injected samples. Rainfall reduces mobilized shear strength by 8 %-25 %, depending on the normal stress, with a 47 % drop in friction angle and a 24 % increase in cohesion after 120 minutes of rainfall exposure. In contrast, PFA-injected samples exhibit a marked increase in mobilized shear strength under both dry and wet conditions, primarily attributed to enhanced cohesion. Notably, PFA treatment proves particularly effective in maintaining higher shear strength and stiffness in rainfall-affected interfaces, demonstrating its potential in improving geotextile-soil interaction under challenging environmental conditions.

Sulfate saline soil is considered as an inferior subgrade construction material that is highly susceptible to damage from salt heaving and dissolution. Polyurethane/water glass (PU/WG) is an efficient grouting material widely used in underground engineering; however, its application in saline soil reinforcement has not yet been reported. In this study, PU/WG was used to solidify sulfate-saline soils. The influence of the dry density, curing agent ratio, and salt content on the strength was evaluated. The mechanical properties of the solidified soil were determined by conducting uniaxial compression strength tests, and crack development was detected using acoustic emission technology. The reinforcing mechanism was revealed by scanning electron microscopy tests and mercury intrusion porosimetry. The results indicated that the peak stress, peak strain, and ultimate strain increased with increasing dry density and PU/WG content, whereas they decreased with increasing salt content. The relationship between the peak stress, density, and PU/WG can be described using linear functions. The relationship between the peak stress and salt content can be described by a second-order polynomial function. The larger the dry density and the higher the PU/WG content, the steeper the stress-strain curves and the lower the ductility. Further, the higher the salt content, the higher the ductility. Soil with a higher dry density, more PU/WG, and less salt content exhibited higher brittleness. Thus, PU/WG can fill in the original disorganized and large pores, thereby increasing the complexity of the internal pore structure via organic-inorganic gel reactions.

Phenolic foam (PF) produces much PF waste during processing because of its friability and tendency to pulverize. Currently, commonly used disposal methods like incineration and landfill cause air and soil pollution. Moreover, protective polyurethane foam (PUF) requires both excellent acoustic insulation and mechanical strength in scenarios, such as factories and roads, to enhance environmental comfort and safety. In this study, PF waste was recycled via a mechanical method, and compounding the recycled PF powder as a functional filler with PUF significantly improved its mechanical and acoustic properties. The sample (PUFB-2.5) with 2.5 g PF powder added achieved a compressive strength of 372.19 kPa, 99.03% higher than the standard foam sample (PUFB-0). Additionally, the sample (PUFB-10) with 10.0 g PF powder added achieved an optimal average sound absorption coefficient (alpha) of 0.59, 63.89% higher than PUFB-0. In the 400-2400 Hz frequency range, sample PUFB-2.5 displayed superior sound absorption properties, with alpha reaching 0.78. This study not only achieves the recyclable and circular utilization of PF waste but also enhances the mechanical and acoustic properties of PUF and offers new paths for the convergence of material science and environmental engineering industries.

3D printed concrete has emerged as one of the most hotly researched 3D printing technologies due to its advantages of shaping without molds and intelligent construction. Given its low heat of hydration and low carbon emissions slag-based cement is becoming more widely used for 3D printing concrete. However, in the formwork-free shaping process, freshly printed slag-based concrete is immediately exposed to air and loses moisture much earlier than traditional cast-in-formwork concrete. As a result, there is a greater risk of drying shrinkage and cracking and poor volumetric stability of the printed part. This study investigated applicability of photo-polymerization technology in improving the volumetric stability of 3D printed concrete by using UV-curable polyurethane-acrylate (PUA) resin as in-situ sprayed coating on the surface of freshly printed slag-based cement samples. The results show that, in comparison with the uncoated 3D printed cement samples, the volumetric shrinkage of the coated 3D printed cement samples significantly reduced by 44 % after 28 days of environmental curing. For samples of the same age, the compressive strength of the coated test block was increased by 27 % from 20.03 MPa to 25.49 MPa, and the interlayer bond strength was increased by 41 % from 1.46 MPa to 2.06 MPa. The sprayed UV-curable polyurethane-acrylate resin can cure rapidly on the specimen surface within seconds under the irradiation of UV light to form an in-situ protective coating, which is tightly bonded to the surface of the cement, effectively reducing water dissipation and promoting hydration, allowing more even and condense microstructures to form during hydration from the outer surface to the inner part of the printed sample, resulted in a higher strength.

Polyurethane foam, when used as a compressible layer in deep soft rock tunnels, offers a feasible solution to reduce the support pressure on the secondary lining. The foam spraying method using sprayed polyurethane material is convenient for engineering applications; however, the compressive behaviour and feasibility of sprayed polyurethane material as a compressible layer remain unclear. To address this gap, this study conducts uniaxial compression tests and scanning electron microscope (SEM) tests to investigate the compressive behaviour of the rigid foams fabricated from a self-developed polyurethane spray material. A peridynamics model for the composite lining with a polyurethane compressible layer is then established. After validating the proposed method by comparison with two tests, a parametric study is carried out to investigate the damage evolution of the composite lining with a polyurethane compressible layer under various combinations of large deformations and compressible layer parameters. The results indicate that the polyurethane compressible layer effectively reduces the radial deformation and damage index of the secondary lining while increasing the damage susceptibility of the primary lining. The thickness of the polyurethane compressible layer significantly influences the prevention effect of large deformation-induced damage to the secondary lining within the density range of 50-100 kg/m3. In accordance with the experimental and simulation results, a simple, yet reasonable and convenient approach for determining the key parameters of the polyurethane compressible layer is proposed, along with a classification scheme for the parameters of the polyurethane compressible layer. (c) 2025 Institute of Rock and Soil Mechanics, Chinese Academy of Sciences. Published by Elsevier B.V. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/ 4.0/).

Coral sand is characterized by low cohesion and high porosity, posing a potential liquefaction risk. Thus, coral sand stabilization is necessary in coastal construction projects. Polyurethane, with its excellent toughness, rapid reaction speed, and strong adhesive properties, is an ideal choice for reinforcing coral sand. However, the diffusion range of non-water reacting foamed polyurethane in coral sand is limited. This study explored the use of water-reacting polyurethane (PRP) to solidify coral sand. PRP is known for its high permeability and bonding strength. Despite its potential, the dynamic mechanical properties and reinforcing mechanism of PRP-solidified coral sand, which are crucial for site seismic analysis and seismic design, have not yet been fully understood. Thus, the resonance column and uniaxial compression tests were conducted to investigate the variations in dynamic shear strain, dynamic shear modulus, damping ratio, and uniaxial compressive strength of the solidified material under different confining pressures, PRP incorporation ratios, and mass moisture contents of coral sand. To further investigate the underlying mechanisms of the variations in its mechanical properties, scanning electron microscopy (SEM) and mercury intrusion tests were conducted to analyze the morphology and pore characteristics of the PRP-solidified material. The results show that, at a constant moisture content, increasing the PRP proportion enhanced the dynamic shear modulus, damping ratio, and uniaxial compressive strength of the coral sand. However, excess moisture content reduced these properties. The pore ratio decreased with the increase of PRP and moisture content, with a larger reduction before drying and a smaller one after drying. The tortuosity of the specimens was mainly affected by the incorporation ratio of PRP, which increased with the increase of the incorporation ratio. However, the moisture content of coral sand had a fewer effect on the tortuosity. The permeability gradually decreased with the increase of the PRP incorporation ratio and the moisture content of coral sand. PRP strengthened the coral sand, primarily through its covering, filling, and bonding effects, enhancing the friction and mechanical occlusion. These findings are significant for the applications of PRP in future coastal engineering projects.

While traditional methods of soil stabilization using cement or lime have been extensively researched, there is a notable gap in understanding the mechanical behavior of soil stabilized with innovative materials. This study aims to investigate the mechanical properties of soil stabilized with polyurethane (PU) foam, nanosilica, and basalt fiber. Unconfined compressive strength (UCS) and direct shear tests were conducted on reconstituted silica and calcareous samples treated with various combinations of these additives. Various parameters, including additive content, curing time, and freeze-thaw cycles, were thoroughly examined. The findings demonstrate a significant increase in UCS and shear strength parameters (c and phi) with the addition of PU foam, nanosilica, or their combination with fiber. Notably, the combination of PU and basalt fiber exhibits the most promising performance in improving the mechanical behavior and freeze-thaw durability of silica and calcareous sand, especially for short curing times. Additionally, calcareous samples consistently exhibit higher UCS, and shear strength compared to silica samples. Furthermore, the analysis of failure patterns and the microstructure of the samples using scanning electron microscopy provides insights into the effectiveness of these stabilizing agents and their influence on the mechanical properties of the soil.

To address the depletion of non-renewable resources and align with the principles of green development, researchers increasingly turned to natural plant extracts to synthesise bio-based waterborne polyurethanes (BWPU) as a sustainable alternative to conventional petroleum-derived BWPUs. Although BWPU demonstrated low emissions and non-toxic characteristics, they still exhibited limitations in heat resistance and relatively reduced biodegradability. Thus, to enhance the overall performance of BWPU, sorbitan monooleate (SP) and quercetin (QC) were incorporated into the formulation of hybrid waterborne polyurethane (CWPU). As natural bio-based hybrid materials, QC and SP facilitated the formation of cross-linking networks and hydrogen bonds, enhancing intermolecular interactions and conformational stability in self-cross-linking CWPU. The research concentrated on investigating the chemical structure, mechanical properties, thermal characteristics, and biodegradability of CWPU. The results demonstrated that the introduction of QC constructed a dense cross-linking network, leading to an increase in elongation at the break of CWPU from 460 % to 864 %. Under the condition of 5 % weight loss (T5%), the thermal stability of CWPU was significantly enhanced, with the decomposition temperature increasing from 200 to 243 degrees C. In addition, after degradation in soil and in a 0.6 % lipase PBS buffer for 28 days, the weight of CWPU decreased to 53 % and 48 %, respectively. CWPU can optimise the utilisation of BWPU in biomedical and packaging applications, thereby contributing to innovations in environmentally friendly materials.

Featured Application The findings of this study establish the behavior of sanitary landfill cover materials, such as compacted clay and compacted polyurethane-clay, in unsaturated conditions under several wet-dry cycles, which would aid in predicting the performance of the material under varying environmental conditions. By predicting the unsaturated hydraulic conductivity and understanding the effects of environmental stresses, the findings can aid in the design and implementation of more durable and efficient landfill liners and covers.Abstract Sanitary landfill covers are exposed to varying environmental conditions; hence, the state of the clay layer also changes from saturated to unsaturated. The study aimed to predict the unsaturated hydraulic conductivity of the locally available compacted clay and clay with polyurethane to determine their behavior as they change from wet to dry using matric suction and empirical models proposed through other studies. The specimens underwent three wet-dry cycles wherein the matric suction was determined for several moisture content levels as the specimen dried using the filter paper method or ASTM D5298. The results showed that the factors affecting the soil structure, such as grain size difference between clay and polyurethane-clay, varying initial void ratios, and degradation of the soil structure due to the wet-dry cycles, did not affect the matric suction at the higher suction range; however, these factors had an effect at the lower suction range. The matric suction obtained was then used to establish the best fit water retention curve (WRC) or the relationship between the matric suction and moisture content. The WRC was used to predict the unsaturated hydraulic conductivity and observe the soil-water interaction. The study also observed that the predicted unsaturated hydraulic conductivity decreases as the compacted specimen moves to a drier state.

The mechanical properties and envelope curve predictions of polyurethane-improved calcareous sand are significantly influenced by the magnitude and direction of principal stress. This study conducted a series of directional shearing tests with varying polyurethane contents (c = 2.5%, 5%, and 7.5%), stress Lode angles (theta sigma = -19.1 degrees, 0 degrees, 19.1 degrees, and 30 degrees), and major principal stress angles (alpha = 0 degrees, 30 degrees, 45 degrees, 60 degrees, and 90 degrees) to investigate the strength and non-coaxial characteristics of calcareous sand improved by polyurethane foam adhesive (PFA). Key findings revealed that failure strength varied significantly with the major principal stress axis direction, initially decreasing to a minimum at alpha = 45 degrees before increasing, with a 30% decrease and 25% increase observed at c = 5%. Non-coaxial characteristics between strain increment and stress directions became more pronounced, with angles varying up to 15 degrees. Increasing polyurethane content from 2.5% to 7.5% enhanced sample strength by 20% at theta sigma = -19.1 degrees and alpha = 60 degrees. A generalized linear strength theory in the pi-plane accurately described strength envelope variations, while a modified Lade criterion, incorporating polymer content, effectively predicted multiaxial strength characteristics with less than 10% deviation from experimental results. These contributions provide quantitative insights into failure strength and non-coaxial behavior, introduce a robust strength prediction framework, and enhance multiaxial strength prediction accuracy, advancing the understanding of polyurethane-improved calcareous sand for engineering applications.