Reactive magnesium oxide (MgO) and ground granulated blast furnace slag (GGBS) are cementitious materials introduced into sludge solidification, which not only reutilizes solid waste but also reduces cement consumption. Through the carbonation of reactive MgO and GGBS, the strength of the solidified sludge is further improved and CO2 is stably sequestrated in carbonate minerals. This paper investigates the strength and microstructural development and CO2 uptake of solidified sludge with varying water content, binder content, and ratio of MgO to GGBS. According to unconfined compressive strength (UCS) tests, when the binder content is 20% and the ratio of reactive MgO to GGBS is 2 & ratio;8, the strength of carbonated samples increases the most, which is six times that of the sample without reactive MgO. With binder content, the CO2 uptake of sample increases up to 2.1 g. Scanning electron microscope (SEM), X-ray diffractometer (XRD), and thermogravimetry-differential thermogravimetry analysis (TG-DTG) tests were conducted to systematically elucidate the micromechanism of carbonation of sludge solidified by reactive MgO and GGBS. Various carbonation and hydration products enhance the soil strength through filling pores and integrating fine particles into bulk aggregates. As the ratio of reactive MgO to GGBS increases, dypingite and hydromagnesite were converted into nesquehonite with better morphological integrity, and thus strengthens the soil skeleton. Diverse calcium carbonate polymorphs from carbonated GGBS also promote sludge strength growth and CO2 sequestration. Test results indicate that the addition of reactive MgO further improves the hydration and carbonation properties of GGBS, so the CO2 uptake grows with the ratio of reactive MgO to GGBS. The synergistic effect of reactive MgO and GGBS increases the carbonation performance of the mixed binder, so likewise the compressive strength.
Sodium hydroxide (NaOH)-sodium silicate-GGBS (ground granulated blast furnace slag) effectively stabilises sulfate-bearing soils by controlling swelling and enhancing strength. However, its dynamic behaviour under cyclic loading remains poorly understood. This study employed GGBS activated by sodium silicate and sodium hydroxide to stabilise sulfate-bearing soils. The dynamic mechanical properties, mineralogy, and microstructure were investigated. The results showed that the permanent strain (epsilon(p)) of sodium hydroxide-sodium silicate-GGBS-stabilised soil, with a ratio of sodium silicate to GGBS ranging from 1:9 to 3:7 after soaking (0.74%-1.3%), was lower than that of soil stabilised with cement after soaking (2.06%). The resilient modulus (E-d) and energy dissipation (W) of sodium hydroxide-sodium silicate-GGBS-stabilised soil did not change as the ratio of sodium silicate to GGBS increased. Compared to cement (E-d = 2.58 MPa, W = 19.96 kJ/m(3)), sulfate-bearing soil stabilised with sodium hydroxide-sodium silicate-GGBS exhibited better E-d (4.84 MPa) and lower W (15.93 kJ/m(3)) at a ratio of sodium silicate to GGBS of 2:8. Ettringite was absent in sodium hydroxide-sodium silicate-GGBS-stabilised soils but dominated pore spaces in cement-stabilised soil after soaking. Microscopic defects caused by soil swelling were observed through microscopic analysis, which had a significant negative impact on the dynamic mechanical properties of sulfate-bearing soils. This affected the application of sulfate-bearing soil in geotechnical engineering.
This research examines the influence of blast furnace slag (BFS) on the physico-mechanical properties of compressed earth blocks (CEBs) stabilised with cement and/or lime. A three-factor mixture design is employed to assess the effects of BFS, cement and lime on key properties such as dry density, water content and compressive strength at 28 and 90 days. The study maintains a constant dune sand proportion with soil substitutions up to 20% (420 grams), while the BFS, lime and cement proportions vary with soil substitutions up to 15% (315 g). The findings indicate that mixtures with over 7.5% cement and equal proportions of lime and BFS, as well as a ternary mixture of 10% cement, 2.5% lime and 2.5% BFS, deliver superior strength. Notably, the optimal compressive strength with a high desirability score of 0.93 is achieved using around 14% cement and 1% lime. Proctor curve analysis shows that BFS-cement-lime substitution reduces water content and increases dry density. Statistical analysis confirms the model's robustness in predicting compressive strength, supported by high F-values and low probabilities, and highlights its effectiveness in guiding design decisions. Additionally, the study's evaluation of rupture types offers further insights into material strength and validates adherence to testing standards.
The purpose of this study was to evaluate the sustainability benefits of Class F fly ash (FA), lime sludge (LS), and ground granulated blast furnace slag (GGBS)-based geopolymer-stabilized Edgar plastic kaolin (EPK) clay using the sustainability index (ISus) approach. Geotechnical engineering operations usually precede most infrastructural projects, making pavement construction an integral contributor to various environmental effects, due to the production of enormous quantities of greenhouse gas emissions through soil stabilization activities. To nip these concerns in the bud, effective integration of these environmental implications must be achieved during the geotechnical planning phase. The life cycle assessment (LCA) method was used to assess a wide range of environmental effects of a project, from raw material procurement, manufacturing, transportation, construction, and maintenance to final disposal. It is a well-recognized tool for designing environmentally sustainable projects. Experimental results from the geopolymer-stabilized EPK clay showed a notable improvement in unconfined compressive strength of the geopolymer-stabilized clay with 15% (FA + LS) and 5% (FA + GGBS) contents of up to 697% and 464%, respectively, after 28 days of curing at elevated temperature, 70 degrees C. The sustainability index (ISus) of geopolymer and lime treatment methods was analyzed based on the concept of environmental, resource consumption, and socioeconomic concerns, which quantifies the sustainability through greenhouse gas emission, environmental impacts, and the cost of utilizing FA, LS, and GGBS in soil stabilization compared with traditional lime. LCA was conducted for traditional lime treatment, FA-LS, and FA-GGBS geopolymer-stabilized subgrades to determine the most sustainable treatment method. From the sustainability analysis, using FA, LS, and GGBS as geopolymer stabilizers for kaolin clay reduced the global warming potential by 98.03% and 77.55% over the traditional lime stabilizers at 8% dosage. More importantly, results from the sustainability index (ISus) computations showed that FA-LS (ISus = 12.88) and FA-GGBS (ISus = 29.72) geopolymer treatment methods of EPK clay subgrade soils are more sustainable alternatives compared to the traditional lime (ISus = 48.07) treatment method.
Civil engineering structures made upon expansive soils known in India as Black Cotton (BC) soils are susceptible to structural damages due to their seasonal swell-and-shrink behaviour. This study focuses on assessing the mechanical performance of BC soil stabilised using unconventional binders, specifically Sugarcane Bagasse Ash (SCBA) and Ground Granulated Blast Furnace Slag (GGBS) with different proportions. The experimental evaluation included Compaction tests, Unconfined Compressive Strength (UCS) tests, Triaxial tests, and Atterberg's limits tests. Additionally, mineralogical and morphological studies were carried out using x-ray diffraction (XRD), scanning electron microscopy (SEM), energy-dispersive x-ray spectroscopy (EDS), and chemical analysis using x-ray fluorescence spectroscopy analysis (XRF). The results showed that the mixture containing 21% SCBA and 9% GGBS produced cementitious-siliceous-hydrate (C-S-H) molecule, which improved the strength. Based on the soil-binder percentage ratio obtained from UCS tests, a regression equation was developed to estimate consolidated soil strength. The regression model, exhibiting an impressive R2 value of 93.69%, was analysed within the framework of existing empirical correlations by other researchers. This statistical model, with its good fit, is a useful tool for evaluating the compressive strength of stabilised expansive soil. The findings provide insights into successful stabilisation solutions for expansive soils found locally and globally.
Expansive soils swell when wet and shrink when dry, causing differential settlements that can lead to structural failures in roads and buildings. In cases where these soils cannot be avoided, improving their stability is essential. This study investigates the use of two binders, ground granulated blast-furnace slag (GGBS) and bagasse ash (BA), byproducts of steel and sugarcane processing, respectively, to reduce soil swelling and enhance stability by assessing the mechanical behavior of reinforced expansive soil. To evaluate the behavior of reinforced expansive soils, tests such as Atterberg limits, compaction, swelling potential, and direct shear were conducted. Results indicated that as reinforcement levels increased to an optimal threshold (3 % GGBS and 12 % BA), the optimum moisture content rose, while maximum dry unit weight generally decreased. A 15 % increase in moisture content and a 3.16 % decrease in maximum dry unit weight were observed with reinforcement. Cohesion decreased by 27 % in soaked conditions and 31 % in unsoaked, while the angle of internal friction rose by 106 % and 111 %, respectively, at the maximum reinforcement threshold. These additives also improved shear strength, reduced swelling potential, and lowered plasticity index, shifting the soil behavior from clay-like to silty. The results show that bagasse ash and GGBS effectively enhance soil properties and provide a sustainable solution for soil stabilization in construction.
High plasticity clay soils have low bearing and high swelling potential, which can lead to major problems if used in embankment layers. In current study, recycled concrete aggregates (RCA) were used as the most important part of construction and demolition (C&D) wastes in order to reduce the swelling potential and improve the mechanical strenght of high plasticity clay soil, and to achieve these goals, granulated blast furnace slag (GBS) was used as chemical additive. A set of laboratory tests including standard proctor, unconfined compression strength (UCS) and CBR tests were conducted to investigate the mechanical properties of the treated soil. Laboratory observations showed that by adding of RCA wastes to high plasticity clay, the UCS value increased up to 20% RCA content and then decreased with further RCA. Also, adding GBS and prolonged curing time improves the UCS of the clay - RCA mixture, and addition of 9% GBS can be suggested as the optimal content to achieve the design criteria of the subbase and subgrade layers. The use of RCA improves the secant modulus of elasticity (E50) and reduces the deformability index (DI), and these parameters are improved more significantly in the presence of GBS additive.
To address environmental concerns related to cement-stabilized expansive soil and the safety risks of caustic-activated blast furnace slag, this study explores the use of lime-activated blast furnace slag as an alternative stabilizer in northern Hebei, China. The effects of slag dosage, curing time, and osmotic pressure on the expansion, osmotic properties, and strength of the improved soil were evaluated through free expansion rate, permeability coefficient, and unconfined compressive strength tests. Results show that adding slag-lime significantly reduces soil expansion. As slag content increases, the free expansion rate decreases exponentially. During the curing period of 3-7 days, expansion declines and stabilizes between 7-14 days. Similarly, the permeability coefficient permeability coefficient decreases with higher slag content, following a quadratic trend. Under osmotic pressures of 0.1-0.2 MPa, the permeability coefficient permeability coefficient increases but stabilizes between 0.2-0.4 MPa.Furthermore, slag-lime significantly enhances unconfined compressive strength, which increases linearly with slag content. The stress-strain curve follows a logistic function in the rising stage and a rational fractional equation in the descending stage.This study demonstrates that lime-activated blast furnace slag is a sustainable and effective alternative for stabilizing expansive soils while reducing dependence on cement.
In this research, a combined method of chemical and physical stabilisation has been used to investigate the effect of using recycled concrete aggregate (RCA) and granulated blast furnace slag (GBS) in improving the strength properties of subgrade soil. A comprehensive series of compaction, uniaxial compressive strength (UCS) and California bearing ratio tests were performed on different mixtures. The results show that UCS values increased for clay subgrade with up to 20% RCA content and decreased after that. The subgrade soil with 20% RCA was treated with GBS to obtain the target uniaxial strength for stabilised subgrade soils. Also, the results obtained from investigating the effect of freeze-thaw cycle on the UCS of the optimum combination with different GBS content show that the F-T cycle reduces the value of the UCS from 32% to 53% after 12 F-T cycles.
This study utilizes polymers based on coal gangue and blast furnace slag to solidify engineering slurry with high silt content. Response surface methodology was employed to investigate the effects of polymer composition, alkali activator modulus, and coal gangue calcination temperature on the unconfined compressive strength of stabilized soil. Additionally, the study comprehensively characterized the thermal stability, pore structure, molecular bonds, mineral composition, and micro-morphology of the stabilized soils, and explored the mechanisms governing their strength development. The results demonstrate that the highest strength of stabilized soils is achieved with a slag to coal gangue ratio of 2.5:7.5, a water glass modulus of 1.2, and a coal gangue calcination temperature of 750 degrees C. Formation of calcium-aluminum-silicate-hydrate (C-A-S-H) and sodium-aluminum-silicate-hydrate (N-A-S-H) contributes significantly to the strength development. The presence of slag promotes early strength through C-A-S-H formation, while coal gangue facilitates N-A-S-H formation, supporting later-stage strength development by filling micropores. By applying alkali-activated calcined coal gangue-slag based cementitious materials to solidify engineering slurry, this research not only elucidates the mechanism of alkaliactivated calcined coal gangue-granulated blast furnace slag in slurry solidification but also promotes the utilization of industrial solid waste, providing new insights for environmental protection and resource recovery.