Electronic waste (e-waste) from nonbiodegradable products present a significant global problem due to its toxic nature and substantial environmental impact. In this study novel electrically conductive biodegradable films of uncured natural rubber (NR) incorporating graphite platelets and chitosan were developed via a latex aqueous microdispersion method. Chitosan was added as a dispersing and thickening agent to encourage the uniform distribution of graphite in the NR matrix at loadings of 20-60 parts per hundred rubbers (phr). FTIR confirmed interactions between NR, graphite, and chitosan. FE-SEM and Synchrotron XTM analyses demonstrated uniform graphite dispersion. The result of XRD revealed the greatest crystallinity at 86.9% with 60 phr graphite loading. Mechanical properties testing indicated a significant increase in Young's modulus to 58.2 MPa, or about 470-fold improvement over the pure NR film. The composite films demonstrated improved thermal and chemical resistance, and their electrical conductivity could rise dramatically to 1.22 x 10-5 S cm-1 at 60 phr graphite loading, or about six orders of magnitude higher than pure NR film. The composite films exhibit antibacterial activity against Staphylococcus aureus and some inhibition against Escherichia coli. In addition, the NR composite films exhibited biodegradability ranging from 16.7% to 25.1% after three months of soil burial, declining with increased graphite loading. These results demonstrate the potential of NR-graphite composites as conductive materials for flexible electronics, such as thin-film electrodes in energy storage devices and sensors.

Granite residual soil exhibits a tendency to collapse and disintegrate upon exposure to water, displaying highly unstable mechanical properties. This makes it susceptible to landslides, mudslides, and other geological hazards. In this study, three common biopolymers, i.e., xanthan gum (XG), locust bean gum (LBG), and guar gum (GG), are employed to improve the strength and stability of granite residual soil. A series of experiments were conducted on biopolymer-modified granite residual soil, varying the types of biopolymers, their concentrations, and curing times, to examine their effects on the soil's strength properties and failure characteristics. The microscopic structure and interaction mechanisms between the soil and biopolymers were analyzed using scanning electron microscopy and X-ray diffraction. The results indicate that guar gum-treated granite residual soil exhibited the highest unconfined compressive strength and shear strength. After adding 2.0% guar gum, the unconfined compressive strength and shear strength of the modified soil are 1.6 times and 1.58 times that of the untreated granite residual soil, respectively. Optimal strength improvements were observed when the biopolymer concentration ranged from 1.5% to 2%, with a curing time of 14 days. After treatment with xanthan gum, locust bean gum, and guar gum, the cohesion of the soil is 1.36 times, 1.34 times, and 1.55 times that of the untreated soil, respectively. The biopolymers enhanced soil bonding through cross-linking, thereby improving the soil's mechanical properties. The gel-like substances formed by the reaction of biopolymers with water adhered to encapsulated soil particles, significantly altering the soil's deformation behavior, toughness, and failure modes. Furthermore, interactions between soil minerals and functional groups of the biopolymers contributed to further enhancement of the soil's mechanical properties. This study demonstrates the feasibility of using biopolymers to improve granite residual soil, offering theoretical insights into the underlying microscopic mechanisms that govern this improvement.

Problematic soils like expansive soils cause significant damages to civil infrastructure. The use of calcium-based stabilizers in the treatment of sulfate-rich expansive soils is not suggested due to the formation of ettringite. Infrastructure such as pavements and embankments built on expansive soil are often exposed to the damaging impacts of freeze-thaw cycles in areas prone to seasonal freezing, making them vulnerable to cracking and spalling. A native expansive soil from South Dakota with a sulfate content of more than 10,000 ppm was stabilized using biopolymer (BP) and cement in this study. A comparison of the geotechnical properties of the untreated and treated soil such as Atterberg limits, one-dimensional (1D) swell, linear shrinkage, unconfined compressive strength (UCS), and resilient modulus (MR) for curing periods of 7 and 28 days were presented in the study. The swelling in cement-stabilized soil specimens was observed to increase after a long period due to the formation of ettringite. The study investigated the effectiveness of cement and biopolymers as co-additives to treat the sulfate-rich expansive soil. The experimental study investigated the strength and stiffness properties of the control and treated soil after the various freeze-thaw (F-T) cycles. The reduction of strength and stiffness properties of soil for 6% cement and the co-addition of 3% cement and 1.5% biopolymer after the F-T cycles were found to be comparatively less. Soil morphology provided insights into the configuration of biopolymer networks and the development of ettringite within treated soils. Biopolymers were used as an environmentally friendly substitute for traditional energy-intensive stabilizers in expansive soil stabilization, and potentially reducing carbon footprints. The study found that the incorporation of biopolymer as a co-additive with cement can be a viable alternative for stabilizing sulfate-rich expansive soil subgrade.

Currently, the primary composition of fibrous filter materials predominantly relies on synthetic polymers derived from petroleum. The utilization of these polymers, as well as their production process, has a negative impact on the environment. Consequently, the adoption of air filter media fabricated from natural fibers would yield significant environmental benefits. Nowadays not only particle and odour capture performance but also ensuring a high energy efficiency and flame retardant properties in air filters is of utmost importance for automotive and HVAC filters. In this study, for the production of biodegradable and flame retardant air filters with a high quality factor, free standing gelatin/sodium alginate blend fibers were successfully produced via centrifugal spinning. The water-soluble mats were stabilized by physical methods using both thermal and ionic crosslinking. The CGCA (Crosslinked-Gelatin/Calcium Alginate) mat exhibited exceptional filtration performance for PM0.3 particles, achieving a 94.2 % efficiency rating at a pressure drop of 135 Pa. Moreover, blending of biopolymers and subsequent calcination provided V0 level flame retardancy according to UL94 standard. The preliminary biodegradation studies showed that proposed nanofibrous filters were completely degraded in soil in 7 days.

The increasing demand for sustainable civil engineering solutions requires balancing present-day infrastructure needs with environmental preservation for future generations. This study explores the potential of xanthan gum, an eco-friendly biopolymer, for stabilizing clayey sand as an alternative to traditional soil stabilizers. Various concentrations of xanthan gum (0.25 % to 1.5 %) and curing durations (7, 14, and 28 days) were evaluated using standard geotechnical testing methods, including compaction, unconfined compressive strength (UCS), indirect tensile strength (ITS), ultrasonic pulse velocity (UPV), and scanning electron microscopy (SEM) analysis. The soil samples comprised 80 % poorly graded sand and 20 % high-plasticity clay. Results showed a significant improvement in soil properties, with just 0.25 % xanthan gum after a 7-day curing period leading to notable increases in UCS and tensile strength. However, further increases in xanthan gum concentration yielded diminishing returns in strength enhancement. Extending the curing time from 7 to 28 days improved compressive strength and stiffness. Additionally, xanthan gum-enhanced samples exhibited increased energy absorption, stiffness, and brittle behavior, forming a denser soil matrix and improving the particle bonding, supported by UPV results and SEM imagery. Also, the relationship between the stiffness from UCS tests and the ultrasonic pulse velocity was obtained. The findings underscore xanthan gum's potential as a sustainable and effective soil stabilizer for geotechnical applications.

Bacterial poly-3-hydroxybutyrate is a thermoplastic biopolyester that is considered a potential alternative to traditional fossil-based plastics due to its rapid biodegradation performance in both soil and marine environments and its compostability. Due to problems in thermal and crystallization behaviors of the bacterial poly-3-hydroxybutyrate polymer, an improvement has been made in the cooling channel of the conventional fiber spinning process. Using an enhanced quench channel, named as a half tube on a conventional melt spinning line, melt spinning of the bacterial poly-3-hydroxybutyrate multifilament fibers is successfully carried out. The maximum crystallization temperature of polymers was taken into account while adjusting the quenching process. The study examined the impact of varying drawing ratios and the designed quenching apparatus on the thermal (differential scanning calorimetry), mechanical (tensile and drawing force tests), morphological, and crystal structure characteristics of fibers. The quenching apparatus has visibly created a homogeneous melt flow under the spinnerets. While it has a negative impact on fiber cross-sectional formation, raising the draw ratio greatly enhances mechanical properties.

This study investigated potato starch/agar-based bioplastics' structure, properties, and biodegradability by adding ZnO nanoparticles (NPs) biogenically synthesized using Coriandrum sativum extract. ZnO NPs presented crystalline structure, good optical properties, and a size of 6.75 +/- 1.4 nm, which were added at various concentrations (419.66-104.23 ppm) in bioplastics and their presence was confirmed via EDS elemental analysis and X-ray fluorescence. The highest NPs concentration contributed to a smoother surface, while FTIR and Raman analyses suggested interactions between the NPs and functional groups of the biopolymeric matrix. ZnO NPs addition slightly reduced bioplastic transparency but significantly improved UV-A and UV-B blocking capacities. It also increased hydrophobicity, evidenced by a 22 % reduction in water absorption and a 55 % increase in contact angle. Thermogravimetric analysis (TGA) indicated that NPs raised the bioplastic's thermal stability. Mechanical property tests showed that ZnO NPs concentrations had negligible or negative effects probably due to the heterogeneous distribution of NPs, or the non-isotropic characteristic of the bioplastic. Finally, biodegradability assays in seawater and soil revealed over 43.5 % and 66 % degradation after 15 and 28 days, respectively. Therefore, biosynthesized ZnO NPs mainly enhanced the bioplastic's UV-blocking capacity, hydrophobicity, and thermal properties, offering an eco-friendly option for future studies/applications.

Waste from the fishing industry is disposed of in soils and oceans, causing environmental damage. However, it is also a source of valuable compounds such as chitin. Although chitin is the second most abundant polymer in nature, its use in industry is limited due to the lack of standardized and scalable extraction methods and its poor solubility. The deacetylation process increases its potential applications by enabling the recovery of chitosan, which is soluble in dilute acidic solutions. Chitosan is a polymer of great importance due to its biocompatible and bioactive properties, which include antimicrobial and antioxidant capabilities. Chitin extraction and its deacetylation to obtain chitosan are typically performed using chemical processes that involve large amounts of strongly acidic and alkaline solutions. To reduce the environmental impact of this process, extraction methods based on biotechnological tools, such as fermentation and chitin deacetylase, as well as emerging technologies, have been proposed. These extraction methods have demonstrated the potential to reduce or even avoid using strong solvents and shorten extraction time, thereby reducing costs. Nevertheless, it is important to address existing gaps in this area, such as the requirements for large-scale implementation and the determination of the stoichiometric ratios for each process. This review highlights the use of biotechnological tools and emerging technologies for chitin extraction and chitosan production. These approaches truly minimize environmental impact, reduce the use of strong solvents, and shorten extraction time. They are a reliable alternative to fishery waste valorization, lowering costs; however, addressing the critical gaps for their large-scale implementation remains challenging.

For almost a decade, various studies have been carried out to prove the suitability of nano additives in enhancing the geotechnical properties of soil. Yet, this line of research is still in its elementary stage, restricting itself to laboratory tests to determine soil's index and engineering properties blended with varying dosages of nano additives. In other words, research on practical applications of nano additives for soil stabilization is scarce. The present work attempts to investigate the suitability of three different nanomaterials as a load-bearing stratum for shallow foundations. The nano additives were chosen in such a way that each of them is from a different origin. One of them is nano calcium carbonate (inorganic) whereas the other two are nano-sized varieties of natural biopolymers, namely nano chitosan (crustacean-based) and nano carboxymethyl cellulose (plant-based). A series of laboratory tests were initially conducted to determine the strength of all three nano-additive-treated soils at different dosages, which were investigated for 180 days to ensure their long-term performance. This was followed by a foundation model study on untreated soil and on soil treated with optimal dosages of nano additives. The results were validated using finite element software followed by a parametric study to optimize the depth of soil stabilization. It was observed that all three nano additives exhibited a better performance when the top layer had the optimal dosage and the subsequent layers had a relatively lesser dosage.

The structural properties of loess are susceptible to change when subjected to external loads and complex environments, leading to various geological disasters. To investigate the mechanical behavior and strengthening mechanism of loess stabilized with biopolymers such as xanthan gum and guar gum, especially for soils with low bearing capacity and stability in engineering applications, we conducted research on the improvement of soil with xanthan gum and guar gum, tests including unconfined compressive strength, disintegration, direct shear, and microstructure tests were conducted. Among the four different dosages of biopolymers (0%, 0.5%, 1%, 2%) and four different curing ages (1 day, 3 days, 7 days, 14 days), the 2% content of biopolymer and 14 days had the greatest impact on the mechanical properties of loess, Both the compressive and shear strength, as well as the water stability of solidified loess, improve with higher content of xanthan gum and guar gum or prolonged curing time; however, the disintegration rate decreases. Microscopic analysis indicates that the biopolymers effectively fill the gaps between soil particles and attach to the particle surfaces, forming fibrous and reticular structures that improve the interparticle bonding and ultimately increase the strength and water stability of the loess. Xanthan gum and guar gum biopolymers can improve the mechanical properties and water stability of loess, enhance the erosion resistance and improve the water-holding capacity. These outcomes suggest that guar gum and xanthan gum biopolymers have the potential to serve as environmentally sustainable alternatives to conventional soil stabilizers.