Electronic waste (e-waste) from nonbiodegradable products present a significant global problem due to its toxic nature and substantial environmental impact. In this study novel electrically conductive biodegradable films of uncured natural rubber (NR) incorporating graphite platelets and chitosan were developed via a latex aqueous microdispersion method. Chitosan was added as a dispersing and thickening agent to encourage the uniform distribution of graphite in the NR matrix at loadings of 20-60 parts per hundred rubbers (phr). FTIR confirmed interactions between NR, graphite, and chitosan. FE-SEM and Synchrotron XTM analyses demonstrated uniform graphite dispersion. The result of XRD revealed the greatest crystallinity at 86.9% with 60 phr graphite loading. Mechanical properties testing indicated a significant increase in Young's modulus to 58.2 MPa, or about 470-fold improvement over the pure NR film. The composite films demonstrated improved thermal and chemical resistance, and their electrical conductivity could rise dramatically to 1.22 x 10-5 S cm-1 at 60 phr graphite loading, or about six orders of magnitude higher than pure NR film. The composite films exhibit antibacterial activity against Staphylococcus aureus and some inhibition against Escherichia coli. In addition, the NR composite films exhibited biodegradability ranging from 16.7% to 25.1% after three months of soil burial, declining with increased graphite loading. These results demonstrate the potential of NR-graphite composites as conductive materials for flexible electronics, such as thin-film electrodes in energy storage devices and sensors.
