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Lime-activated ground granulated blast furnace slag (GGBS) is usually used to treat gypseous soils. However, sulphate-bearing soils often contain other sulphates, e.g., sodium sulphate (Na2SO4), potassium sulphate (K2SO4) and magnesium sulphate (MgSO4). Therefore, in this study, lime-GGBS was used as a curing agent for stabilising four sulphate-bearing soils, which were named as Na-soil, K-soil, Mg-soil, and Ca-soil. Unconfined compressive strength (UCS), swelling, X-ray diffraction, scanning electron microscopy and inductively coupled plasma spectroscopy tests, were conducted to explore the macro- and micro-properties of the lime-GGBS-stabilised soils. The results showed that at 5000 ppm sulphate, stabilised Mg-soil had the lowest swelling and highest UCS. At 20,000 ppm sulphate, stabilised Ca-soil had the lowest swelling, while stabilised Na-soil had the highest UCS. Generally, increasing sulphate concentration decreased swelling for Ca-soil but increased for other three soils, and decreased UCS for Mg-soil but increased for other three soils. This was because less ettringite was generated in the stabilised Ca-soil and the formation of magnesium silicate hydrate (MSH) in the stabilised Mg-soil. Therefore, the sulphate type had a significant impact on the swelling and strength properties of lime-GGBS-stabilised sulphate-bearing soil. It is essential to identify the sulphate type before stabilising the soil on-site.

期刊论文 2025-12-31 DOI: 10.1080/10298436.2025.2464203 ISSN: 1029-8436

To study the degree of strength parameter deterioration (DSPD) of Lushi swelling rock in the high slope area under wetting-drying cycles, 114 samples are remodeled. Wetting-drying cycle and triaxial tests are conducted to comprehensively analyze the influence of dry density, wetting-drying cycle path, and number of wetting-drying cycles on the strength deterioration characteristics of Lushi swelling rock. Using the fitting analysis and function superposition methods, the DSPD model of Lushi swelling rock under wetting-drying cycles is established, which considers the previous four influencing factors. The influence of the DSPD of Lushi swelling rock on the stability of high slopes under rainfall seepage and circulation conditions is studied. Lushi swelling rock exhibits significant strength deterioration characteristics under wetting-drying cycles. The overall DSPD for cohesion is higher than that of the internal friction angle. Under rainstorm conditions, strength deterioration leads to a shallower depth of the critical slip surface of the slope and a smaller safety factor. After eight rounds of rainfall seepage and circulation, the safety factor gradually decreases by approximately 14%-28%. This study provides and verifies the DSPD model of Lushi swelling rock under wetting-drying cycles, and the results could provide a basis for disaster prediction and the optimization design of swelling rock slopes.

期刊论文 2025-08-01 DOI: 10.1061/IJGNAI.GMENG-10701 ISSN: 1532-3641

Conventional in-situ light non-aqueous phase liquid (LNAPL) remediation techniques often face challenges of high costs and limited efficiency, leaving residual hydrocarbons trapped in soil pores. This study investigates the efficiency of an alcohol-in-biopolymer emulsion for enhancing diesel-contaminated soil remediation. The emulsion, formulated with xanthan gum biopolymer, sodium dodecyl sulfate surfactant, and the oil-soluble alcohol 1-pentanol, was evaluated through rheological tests, interfacial tension measurements, and onedimensional sand-column experiments under direct injection and post-waterflooding scenarios. The emulsion exhibited non-Newtonian shear-thinning behavior with high viscosity, ensuring stable propagation and efficient delivery of 1-pentanol to mobilize trapped diesel ganglia. It achieved 100 % diesel recovery within 1.2 PV during direct injection, outperforming shear-thinning polymer-only and polymer-surfactant solutions, which achieved recovery factors of 83.4-92.9 %. Post-waterflooding experiments also demonstrated 100 % diesel recovery within 1.3 PV, regardless of initial diesel saturation. Key mechanisms include reduced interfacial tension, diesel swelling and mobilization induced by 1-pentanol, and uniform displacement facilitated by the emulsion's viscosity. Additionally, the emulsion required lower injection pressures compared to more viscous alternatives, enhancing its injectability into the soil and reducing energy demands. These findings highlight the emulsion's potential to overcome conventional remediation limitations, offering a highly effective and sustainable solution for diesel-contaminated soils and groundwater.

期刊论文 2025-07-15 DOI: 10.1016/j.jhazmat.2025.138183 ISSN: 0304-3894

To overcome the limitations of microscale experimental techniques and molecular dynamics (MD) simulations, a coarse-grained molecular dynamics (CGMD) method was used to simulate the wetting processes of clay aggregates. Based on the evolution of swelling stress, final dry density, water distribution, and clay arrangements under different target water contents and dry densities, a relationship between the swelling behaviors and microstructures was established. The simulated results showed that when the clay-water well depth was 300 kcal/mol, the basal spacing from CGMD was consistent with the X-ray diffraction (XRD) data. The effect of initial dry density on swelling stress was more pronounced than that of water content. The anisotropic swelling characteristics of the aggregates are related to the proportion of horizontally oriented clay mineral layers. The swelling stress was found to depend on the distribution of tactoids at the microscopic level. At lower initial dry density, the distribution of tactoids was mainly controlled by water distribution. With increase in the bound water content, the basal spacing expanded, and the swelling stresses increased. Free water dominated at higher water contents, and the particles were easily rotated, leading to a decrease in the number of large tactoids. At higher dry densities, the distances between the clay mineral layers decreased, and the movement was limited. When bound water enters the interlayers, there is a significant increase in interparticle repulsive forces, resulting in a greater number of small-sized tactoids. Eventually, a well-defined logarithmic relationship was observed between the swelling stress and the total number of tactoids. These findings contribute to a better understanding of coupled macro-micro swelling behaviors of montmorillonite-based materials, filling a study gap in clay-water interactions on a micro scale. (c) 2025 Institute of Rock and Soil Mechanics, Chinese Academy of Sciences. Published by Elsevier B.V. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/ 4.0/).

期刊论文 2025-06-01 DOI: 10.1016/j.jrmge.2024.11.027 ISSN: 1674-7755

This experimental study is to find a solution to reduce the amount of waste and at the same time improve the geotechnical properties of fine soils. Compaction, odometer, direct shear tests, and unconfined compression tests were carried out on a clay with a very high degree of plasticity mixed with 0%, 10%, 20%, 30%, and 40% of recycled concrete aggregates (RCA). The addition of concrete aggregates to the clayey soil shows an increase in the maximum dry density and a reduction in the optimum water content. The odometer tests results showed that the increase in the recycled material content leads to a decrease in the compression index, swelling index and creep index. On the other hand, the pre-consolidation stress, the odometric modulus, the consolidation coefficient and the permeability coefficient increase with increasing RCA content. According to the direct shear test, the higher RCA content provided an improvement in shear strength which is accompanied by an increase in the dilatant character. For different curing times and for a content of 10% recycled concrete aggregate, the unconfined compressive strength increased compared to the untreated soil.

期刊论文 2025-06-01 DOI: 10.1007/s40515-025-00622-8 ISSN: 2196-7202

Due to economic and demographic growth, there is a rising demand for land reclamation in coastal cities of East and Southeast Asia. Marine clays typically play a critical role in these projects, and the deformation characteristics of marine clays become a crucial problem in terms of the quality of the subsoil conditions. The long-term loading behavior of marine clays has been studied by many researchers. However, relatively few studies have been done on the unloading behavior of these clays after preloading; and thus, the strain rate dependency on the unloading behavior of marine clays remains unclear. The aim of this study was to accumulate experimental data on the unloading behavior of marine clays and to develop a strain rate-based model for improving the accuracy of the predictions of the swelling behavior of marine clays during unloading. The authors conducted a series of constant rate of strain (CRS) consolidation tests from loading to unloading, and long-term unloading oedometer tests on Ariake clay, which is a well-known sensitive marine clay, to observe the swelling behavior during in unloading. The preloading time, corresponding to different strain rates at the end of preloading, was controlled to elucidate the effect of the stress history. Moreover, instead of parameter r ' p (preconsolidation pressure) for the normal consolidation visco-plastic behavior, the authors developed and proposed a new visco-plastic model by introducing the concept of a plastic rebound boundary and a new parameter R for swelling behavior during unloading. Parameter R represents the normalized distance from the current stress state to the plastic rebound boundary in logarithmic effective consolidation stress. Therefore, the visco-plastic model for the behavior in the loading stage was developed into the swelling visco-plastic behavior in the unloading stage for Ariake clay. Comparing the simulation and test results, the simplified visco-plastic swelling model was found to agree well with the test results. (c) 2025 Published by Elsevier B.V. on behalf of Japanese Geotechnical Society. This is an open access article under the CC BY license (http:// creativecommons.org/licenses/by/4.0/).

期刊论文 2025-06-01 DOI: 10.1016/j.sandf.2025.101594 ISSN: 0038-0806

Sodium hydroxide (NaOH)-sodium silicate-GGBS (ground granulated blast furnace slag) effectively stabilises sulfate-bearing soils by controlling swelling and enhancing strength. However, its dynamic behaviour under cyclic loading remains poorly understood. This study employed GGBS activated by sodium silicate and sodium hydroxide to stabilise sulfate-bearing soils. The dynamic mechanical properties, mineralogy, and microstructure were investigated. The results showed that the permanent strain (epsilon(p)) of sodium hydroxide-sodium silicate-GGBS-stabilised soil, with a ratio of sodium silicate to GGBS ranging from 1:9 to 3:7 after soaking (0.74%-1.3%), was lower than that of soil stabilised with cement after soaking (2.06%). The resilient modulus (E-d) and energy dissipation (W) of sodium hydroxide-sodium silicate-GGBS-stabilised soil did not change as the ratio of sodium silicate to GGBS increased. Compared to cement (E-d = 2.58 MPa, W = 19.96 kJ/m(3)), sulfate-bearing soil stabilised with sodium hydroxide-sodium silicate-GGBS exhibited better E-d (4.84 MPa) and lower W (15.93 kJ/m(3)) at a ratio of sodium silicate to GGBS of 2:8. Ettringite was absent in sodium hydroxide-sodium silicate-GGBS-stabilised soils but dominated pore spaces in cement-stabilised soil after soaking. Microscopic defects caused by soil swelling were observed through microscopic analysis, which had a significant negative impact on the dynamic mechanical properties of sulfate-bearing soils. This affected the application of sulfate-bearing soil in geotechnical engineering.

期刊论文 2025-05-30 DOI: 10.1680/jcoma.24.00124 ISSN: 1747-650X

Swelling soils are increasingly recognized as a critical issue in geotechnical engineering, as their presence can lead to substantial damage to built structures. When structures are built on such soils and free swelling is prevented, stresses can develop that may lead to significant damage to the structure. Soil stabilization through the use of additive materials has garnered considerable attention as an effective method for mitigating this problem. The objective of this study was to stabilize the clay soil (CH) with high swelling potential by using sea shell, lime and zeolite additives in two stages. In the initial phase, consistency limits were tested by mixing high plasticity clay soil mixed with 8-10-12-14-16% sea shell 0-3-5-6-8% lime (one of the most used soil stabilizer) and 0-5-10-15-20% zeolite by weight. The three mixtures and the two best percentages determined for each mixture were then combined. Upon completing these steps, five experimental sets were prepared by combining the percentages that yielded the best results. Compaction test, percent swelling test and swelling pressure tests were performed with these datas. According to the test results, adding 14% sea shell, 6% lime and 5% zeolite by weight (SS14L6Z5) gave the smallest swelling value as 1,07% and highes swelling pressure as 23 kPa. This study concludes that the combined use of these additives led to a substantial 96% increase in swelling pressure, along with a marked reduction in swelling potential.

期刊论文 2025-05-01 DOI: 10.18400/tjce.1464572 ISSN: 2822-6836

Conventional pump-and-treat technologies have demonstrated limited effectiveness in remediating soils contaminated with light non-aqueous phase liquids (LNAPLs), such as petroleum hydrocarbons. Nonconventional in-situ flushing with shear-thinning fluids, such as polymers, offers a promising alternative. However, even with polymer flushing, residual LNAPL ganglia may remain trapped in porous media, requiring further improvement of the flushing fluid to enhance remediation efficiency. In this study, we present a novel alcohol-in-biopolymer emulsion developed to enhance the recovery of residual diesel oil from porous media. Batch experiments were conducted to evaluate the partitioning behavior of fifteen different alcohols between the aqueous and diesel phases. The results revealed that 1-pentanol preferentially partitions into the diesel phase rather than the aqueous phase, leading to an increase in diesel oil volume via a swelling mechanism. Furthermore, 1-pentanol forms a stable and homogeneous emulsion when combined with an aqueous solution of the biopolymer xanthan gum, and the surfactant sodium dodecyl sulfate. The emulsion demonstrated high stability for over 30 days, ensuring its suitability for prolonged remediation processes. Rheological experiments confirmed the emulsion's shear-thinning behavior, which ensures stable and uniform displacement within porous media. A two-dimensional cell packed with silica sand was used to evaluate the efficiency of the emulsion in removing residual diesel oil. The results demonstrated that the emulsion propagates uniformly throughout the porous media, effectively achieving complete removal of residual diesel within 1.15 pore volumes of injection. Porescale visualizations revealed the swelling and subsequent mobilization of entrapped diesel ganglia induced by the emulsion, further confirming its efficacy. These findings highlight the potential of this novel alcohol-inbiopolymer emulsion to significantly improve diesel oil recovery from contaminated soils.

期刊论文 2025-05-01 DOI: 10.1016/j.hazadv.2025.100616 ISSN: 2772-4166

The development of cracks and deterioration of mechanical properties in aeolian deposits are common phenomena during dry-wet cycles. The redistribution of soil particles and the change of clay mineral aggregates are some of the reasons for the change in soil properties in this process. In this paper, the physical and mechanical properties, apparent digital images, and scanning electron microscopy (SEM) were used jointly to analyze the properties of silty clays (Xiashu loess) during the dry-wet cycle. The amplitude design of the dry-wet cycle is 2.52%-28.39%, and the number of cycles was designed to be 2,4,6,8and 10 times. The results show that the shrinkage and breakage of clay minerals and the release of pore water stress are caused by the change in water content leading to the redistribution of aggregate particles. The permeability and swelling ability of soil tend to be stable, indicating the stable trend of particle redistribution. The soil cohesion and internal friction angle have an exponential relationship with the number of dry-wet cycles, and the exponential relationship parameters are related to the soil type. Based on the analysis of particle migration, it can better explain the reasons for the deterioration of soil mechanical properties.

期刊论文 2025-05-01 DOI: 10.1007/s10064-025-04250-x ISSN: 1435-9529
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