Abandoned farmlands are increasing due to socio-economic changes and land marginalization, and they require sustainable land management practices. Biocrusts are a common cover on the topsoil of abandoned farmlands and play an important role in improving soil stability and erosion resistance. The critical functions of biocrusts are known to mostly rely on their biofilaments and extracellular polymeric substances (EPS), but how these components act at microscopic scale is still unknown, while rheological methods are able to provide new insights into biocrust microstructural stability at particle scale. Here, bare soil and two representative types of biocrusts (cyanobacterial and moss crusts) developed on sandy (Ustipsamments) and sandy loam (Haplustepts) soils in abandoned farmlands in the northern Chinese Loess Plateau were collected at a sampling depth of 2 cm. Changes in the rheological properties of the biocrusts were analyzed with respect to their biofilament network and EPS contents to provide possible explanations. The rheological results showed that compared with bare soil, storage and loss moduli were decreased by the biocrusts on sandy soil, but they were increased by the biocrusts on sandy loam soil. Other rheological parameters tau max, gamma L, gamma YP, and Iz of biocrusts on both soils were significantly higher than those of bare soil, showing higher viscoelasticity. And the moss crusts had about 10 times higher rheological property values than the cyanobacterial crusts. Analysis from SEM images showed that the moss crusts had higher biofilament network parameters than the cyanobacterial crusts, including nodes, crosslink density, branches, branching ratio and mesh index, and biofilament density, indicating that the biofilament network structure in the moss crusts was more compact and complex in contrast to the cyanobacterial crusts. Additionally, EPS content of the moss crusts was higher than that of the cyanobacterial crusts on both soils. Overall, the crosslink density, biofilament density, and EPS content of the biocrusts were significantly and positively correlated with their gamma YP and Iz. The interaction between crosslink density and biofilament density contributed 73.2 % of gamma YP, and that between crosslink density and EPS content contributed 84.0 % of Iz. Our findings highlight the biocrusts-induced changes of abandoned farmland soil rheological properties in drylands, and the importance of biocrust biofilament network and EPS in maintaining abandoned farmland soil microstructural stability to resist soil water/wind erosion and degradation, providing a new perspective for sustainable management of abandoned farmlands.

Knowledge Gap: The aggregation of clay minerals-layered silicate nanoparticles-strongly impacts fluid flow, solute migration, and solid mechanics in soils, sediments, and sedimentary rocks. Experimental and computational characterization of clay aggregation is inhibited by the delicate water-mediated nature of clay colloidal interactions and by the range of spatial scales involved, from 1 nm thick platelets to flocs with dimensions up to micrometers or more. Simulations: Using a new coarse-grained molecular dynamics (CGMD) approach, we predicted the microstructure, dynamics, and rheology of hydrated smectite (more precisely, montmorillonite) clay gels containing up to 2,000 clay platelets on length scales up to 0.1 mu m. Simulations investigated the impact of simulation time, platelet diameters (6 to 25 nm), and the ratio of Na to Ca exchangeable cations on the assembly of tactoids (i.e., stacks of parallel clay platelets) and larger aggregates (i.e., assemblages of tactoids). We analyzed structural features including tactoid size and size distribution, basal spacing, counterion distribution in the electrical double layer, clay association modes, and the rheological properties of smectite gels. Findings: Our results demonstrate new potential to characterize and understand clay aggregation in dilute suspensions and gels on a scale of thousands of particles with explicit representation of counterion clouds and with accuracy approaching that of all-atom molecular dynamics (MD) simulations. For example, our simulations predict the strong impact of Na/Ca ratio on clay tactoid formation and the shear-thinning rheology of clay gels.

The long-term settlement of subsea pipelines on a clayey seabed is crucial for the on-bottom stability of the pipelines, especially in deep waters. In this study, a poro-elasto-viscoplastic finite element analysis is performed for predicting long-term settlement of subsea pipelines by incorporating a rheological constitutive model. A method for identifying the creep-settlement (Sc) from the total-embedment (Sk) is proposed on the basis of the obtained linear relationship between the secondary consolidation coefficient (C alpha e) of the clayey soil and the total-embedment (Sk) of the pipe. The identifying method is validated with the existing theoretical solutions and experimental data. Parametric study is then performed to investigate the key influential parameters for long-term settlement of subsea pipeline. A non-dimensional parameter Gc is introduced to quantitatively characterize the soil rheology effect on pipeline settlement. The relationship between the proportion of creep-settlement in the total-embedment (Sc/Sk) and Gc is eventually established for identifying whether the proportion of creep-settlement in the total-embedment is remarkable.

Self-consolidating earth concrete (SCEC) addresses the long construction process of conventional earthen constructions and their structural limitations, while further efforts are needed to enhance its sustainability. This study explores the development of a kaolinite-based self-consolidating earth paste (SCEP) due to their blended powder system, incorporating raw and treated (calcined and ground-calcined) kaolinite under various activation techniques, such as water hydration, sodium hexametaphosphate (NaHMP), and sodium hydroxide (NaOH) activation. The synergistic effect of calcination and mechanosynthesis on rheological, mechanical, structural, and microstructural properties of SCEP were investigated. Mechanically treated kaolinite increased yield stress, plastic viscosity, storage modulus evolution, and build-up index, while delayed the strength development compared to the calcined kaolinite samples. Among the investigated activators, NaOH resulted in more promising structural build-up, storage modulus, and compressive strength development. These findings were elaborated with X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), calorimetry, thermogravimetric analysis (TGA), and scanning electron microscopy (SEM).

This study investigated the rheological and compression-permeability attributes of dredged slurry reinforced using waste rice straws. Recognizing the potential of natural waste fibers in geotechnical applications, this study aimed to elucidate the effects of fiber length and pretreatment processes on the relocation dynamics of the cemented slurry. A series of laboratory evaluations were conducted to gauge critical parameters such as flow consistency, viscosity, one-dimensional compression, and hydraulic conductivity. Results indicated that straw lengths greater than 0.075 mm significantly increased slurry slump flow due to altered surface area and water adsorption. Dynamic viscosity decreased with increasing straw length, yet overall performance improved with straw inclusion. The influence of immersing straws in pure water emerged as a determinant in the study. A 24-h pretreatment duration influenced the flowability, viscosity, and the structural integrity of the fibers. Based on the observations, the study deduces that straw powder finer than 0.075 mm, subjected to a 24-h immersion in pure water, optimally bolsters the flow properties of cemented waste slurry. While the benefits associated with elongated straw fibers necessitate exploration and validation, this work underscores the potential of rice straw as a sustainable reinforcement material in geotechnical endeavors, promoting waste recycling and reducing environmental impact.

Structural colors are bright and possess a remarkable resistance to light exposure, humidity, and temperature such that they constitute an environmentally friendly alternative to chemical pigments. Unfortunately, upscaling the production of photonic structures obtained via conventional colloidal self-assembly is challenging because defects often occur during the assembly of larger structures. Moreover, the processing of materials exhibiting structural colors into intricate 3D structures remains challenging. To address these limitations, rigid photonic microparticles are formulated into an ink that can be 3D printed through direct ink writing (DIW) at room temperature to form intricate macroscopic structures possessing locally varying mechanical and optical properties. This is achieved by adding small amounts of soft microgels to the rigid photonic particles. To rigidify the granular structure, a percolating hydrogel network is formed that covalently connects the microgels. The mechanical properties of the resulting photonic granular materials can be adjusted with the composition and volume fraction of the microgels. The potential of this approach is demonstrated by 3D printing a centimeter-sized photonic butterfly and a temperature-responsive photonic material.

Soil structural stability is fundamentally linked to soil functionality and sustainable productivity. Rheological properties describe the deformation and flow behavior of soil under external stress, playing a crucial role in understanding soil structure stability. Despite their importance, the studies about rheological properties of black soils in Northeast China remain limited. This study aims to assess the rheological properties of two kinds of black soil with different degrees of degradation in Northeast China. The rheological parameters of these soils under various water contents and shearing were quantified by conducting Amplitude Sweep Tests (ASTs) and Rotational Sweep Tests (RSTs). Both AST and RST results showed that as soil water content and shear rate increased, shear strength, viscosity, and hysteresis area all decreased in Keshan and Binxian black soils. The increase in soil water content reduces the friction between soil particles, leading to a decrease in soil structure stability. Additionally, the viscosity and hysteresis area of the two soils decreased with the increase in water content, making it more flowable and exhibiting shear-thinning behavior. Keshan black soil exhibited stronger recovery and shear strength compared to Binxian black soil; this is mainly due to the higher organic matter content in Keshan soil, which could increase structural stability by bonding the soil particles at the micro-level. These findings enhance our understanding about the structure stability of the black soils based on the rheological parameters via rheometer.

We present a constitutive model for the mechanical behavior of granular flow for both solid-like and fluid-like regimes. The stress rate tensor is decomposed into rate-independent and rate-dependent parts. The hypoplastic model is used for the rate-independent part, while the mu(I)$\mu (I)$-type rheological model is employed for the rate-dependent part. The Stokes number is introduced to capture the influence of interstitial fluid viscosity within the rate-dependent part of the model. The model performance is demonstrated through numerical simulations of element tests, encompassing both granular materials and granular-fluid mixtures.

The need for renewable and biodegradable materials for packaging applications has grown significantly in recent years. Growing environmental worries over the widespread use of synthetic and non-biodegradable polymeric packaging, particularly polyethylene, are linked to this increase in demand. This study investigated the degradation properties of low-density polyethylene (LDPE), a material commonly used in packaging, after incorporating various natural fillers that are sustainable, compatible, and biodegradable. The LDPE was mixed with 2.5, 5, and 10 wt.% of sawdust, cellulose powder, and Nanocrystalline cellulose (CNC). The composites were melted and mixed using a twin-screw extruder machine with a screw speed of 50 rpm at 190 degrees C to produce sheets using a specific die. These sheets were used to prepare samples for rheological tests that measured the viscosity curve, the flow curve, and a non-Newtonian mathematical model using a capillary rheometer at 170, 190, and 210 degrees C. X-ray diffraction analysis was carried out on the 5 wt.% samples, and a short-term degradation test was conducted in soil with a pH of 6.5, 50% humidity, and a temperature of 27 degrees C. The results revealed that the composite melts exhibited non-Newtonian behavior, with shear thinning being the dominant characteristic in the viscosity curves. The shear viscosity increased as the different cellulose additives increased. The 5% ratio had a higher viscosity for all composite melts, and the LDPE/CNC melts showed higher viscosities at different temperatures. The curve fitting results confirmed that the power-law model best described the flow behavior of all composite melts. The LDPE/sawdust and cellulose powder melts showed higher flow index (n) and lower viscosity consistency (k) values compared with LDPE/CNC melted at different temperatures. The sawdust and powder composites had greater weight loss compared with the LD vbbPE/CNC composites; digital images supported these results after 30 days. The degradation test and weight loss illustrated stronger relations with the viscosity values at low shear rates. The higher the shear viscosity, the lower the degradation and vice versa.

Gaining insights into landslide deposits form can help achieve a better understanding of the overall landslide dynamics. Previous studies have focused on understanding global characteristics of the runout process and final deposit, without attempting to comprehend the deposition process and the underlying mechanisms. Here, we employed a combination of flume experiments and numerical simulations based on the material point method (MPM) to investigate the influence of friction on the characteristics of rock avalanche deposits and gain a deeper understanding of the mechanisms involved. MPM simulations have generally relied on simple soil constitutive models, which cannot capture the rate-, pressure-, and size-dependent characteristics of geomaterials. Thus, we adopted a viscoplastic non-local mu(I) rheology model, which has been proven to be able to reproduce depositional characteristics with high accuracy. We identified two stages during deposition, namely a translational stage, primarily influenced by the basal frictional resistance, and a subsequent impact shear stage, governed by the internal frictional resistance.