Compared to the limited performance of other high-efficiency urea products, humic acid urea (HAU) increased the grain yield of winter wheat as well as of summer maize. However, the effect of adding different amounts of humic acid (HA) on the fate of urea and comprehensive economic and environmental evaluations remains unclear. Four treatments (no urea (CK), common urea (U), HAU0.5, and HAU5) were compared in a 2-year winter wheat-summer maize rotation system. Compared to U, the grain yield of HAU treatments increased by 4.48-11.25 %, regardless of crop type, planting year, or HA addition level; this was partly attributable to the increased storage of soil available N, as confirmed by a simultaneous 15N tracing microplot experiment in the first winter wheat season. HAU inhibited the loss of reactive N (NH3 volatilization, N2O emission, and NO3--N leaching loss). The C footprint based on the yield and areas calculations for HAUs was 7.01-13.48 % and 3.53-5.54 % lower than that of U, respectively. Annual environmental damage costs and annual net ecosystem economic benefits were decreased and increased by 14.89 %- 19.11 % and 6.38 %-9.23 %, respectively. Few agronomic and environmental differences were found between HAU5 and HAU0.5, although the former locked more 15N nutrients in the topsoil. This combined experiment using 15N tracer and field lysimeters showed that more nutrients from HAU were absorbed by crops and converted into grains, reducing the environmental risk of greenhouse gas emissions due to the release of unused nutrients from common U into farmland.

The increasing production of waste glass fiber reinforced polymer (GFRP) is causing severe environmental pollution, highlighting the need for an effective treatment method. This study explores recycling waste GFRP powder to substitute ground granulated blast furnace slag (GGBS) in synthesizing geopolymers, aiming to rapidly stabilize clayey soil. The impact of GFRP powder replacement, alkali solution concentration, alkaline activator/precursor (A/P) ratio, and binder content on the geomechanical properties and permeability of stabilized soil was thoroughly examined. The findings revealed that replacing GFRP powder from 20 wt% to 40 wt% lowered the unconfined compressive strength (UCS). However, soil stabilized with 30 wt% GFRP powder displayed the highest shear strength. This indicates that the incorporation of an appropriate amount of GFRP powder elevates clay cohesion. Furthermore, an increase in GFRP powder replacement improved permeability coefficient in the early stages, with minimal impact observed after 28 days. Scanning electron microscopy with energy dispersive spectroscopy (SEM-EDS) analysis revealed a microstructural evolution of the stabilized soil, transitioning from a porous to a denser, more homogeneous composition over the curing period, which can be attributed to the formation of cluster gels enveloping the soil particles. Life cycle assessment (LCA) analysis indicated that the GFRP powder/GGBS geopolymer presents an alternative option to traditional Ordinary Portland Cement (OPC) binder, featuring a global warming potential (GWP)/strength ratio reduction of 6 %-40 %. This research offers a practical solution for effectively utilizing GFRP waste in a sustainable manner, with minimal energy consumption and pollution, thereby contributing to the sustainable development of soil stabilization.

A novel MgO-mixing column was developed for deep soft soil improvement, utilizing in-situ deep mixing of MgO with soil followed by carbonation and solidification via captured CO2 injection. Its low carbon footprint and rapid reinforcement potential make it promising for ground improvement. However, a simple and cost-effective quality assessment method is lacking. This study evaluated the electrical properties of MgO-mixing columns using electrical resistivity measurements, exploring relationships between resistivity parameters and column properties such as saturation, strength, modulus, CO2 sequestration and uniformity. Microscopic analyses were conducted to elucidate the mechanisms underlying carbonation, solidification, and electrical property changes. The life cycle assessment (LCA) was performed to assess its carbon reduction benefits and energy consumption. The findings reveal that the electrical resistivity decreases rapidly with increasing test frequency, remaining constant at 100 kHz, with the average electrical resistivity being slightly higher in the upper compared to the lower section. Additionally, electrical resistivity follows a power-law decrease with increasing saturation. Both electrical resistivity and the average formation factor exhibit strong positive correlations with unconfined compressive strength (UCS) and deformation modulus, enabling predictive assessments. Furthermore, CO2 sequestration in MgO-mixing columns is positively correlated with electrical resistivity, and the average anisotropy coefficient of 0.96 indicates good column uniformity. Microstructural analyses identify nesquehonite, dypingite/hydromagnesite, and magnesite as significant contributors to strength enhancement. Depth-related changes in electrical resistivity parameters arise from variations in the amount and distribution of carbonation products, which differently impede current flow. LCA highlights the significant low-carbon advantages of MgOmixing columns

The use of ordinary Portland cement for the stabilisation of granular materials in road construction undermines the effort on sustainability made by using recycled aggregate in substitution of natural ones. This requires the use of low-impact binders so that the road construction industry complies with the prevailing environmental regulations. This study compares the mechanical and environmental properties of construction and demolition waste (CDW) aggregates stabilised with different binders: (i) a Portland-limestone cement as a reference, (ii) a pozzolanic cement, (iii) an experimental pozzolanic cement containing waste clay from the lightweight aggregate production, and (iv) a binder with alkali-activated CDW fines. In the laboratory experiments, both strength and resilient properties were considered, while the environmental impact was assessed in a cradle-to-gate scenario through a life cycle analysis (LCA). The stabilised mixture with pozzolanic cement achieved comparable strength and stiffness while exhibiting a lower environmental impact than the mixture containing Portland-limestone cement. The addition of waste clay to the pozzolanic cement significantly reduces its environmental impact albeit more binder is required to compensate for the lower mechanical properties. The alkaline activation of the fine particles in the CDW aggregate enabled the creation of a stabilised mixture with high strengths and resilient modulus. However, this alternative stabilisation technique requires further optimisation to mitigate the significant environmental impact. The engineering evaluations of the stabilised granular mixtures studied have considered both mechanical and environmental factors intending to contribute to the scientific debate on how to make roadworks sustainable and conserve natural resources.

The purpose of this study was to evaluate the sustainability benefits of Class F fly ash (FA), lime sludge (LS), and ground granulated blast furnace slag (GGBS)-based geopolymer-stabilized Edgar plastic kaolin (EPK) clay using the sustainability index (ISus) approach. Geotechnical engineering operations usually precede most infrastructural projects, making pavement construction an integral contributor to various environmental effects, due to the production of enormous quantities of greenhouse gas emissions through soil stabilization activities. To nip these concerns in the bud, effective integration of these environmental implications must be achieved during the geotechnical planning phase. The life cycle assessment (LCA) method was used to assess a wide range of environmental effects of a project, from raw material procurement, manufacturing, transportation, construction, and maintenance to final disposal. It is a well-recognized tool for designing environmentally sustainable projects. Experimental results from the geopolymer-stabilized EPK clay showed a notable improvement in unconfined compressive strength of the geopolymer-stabilized clay with 15% (FA + LS) and 5% (FA + GGBS) contents of up to 697% and 464%, respectively, after 28 days of curing at elevated temperature, 70 degrees C. The sustainability index (ISus) of geopolymer and lime treatment methods was analyzed based on the concept of environmental, resource consumption, and socioeconomic concerns, which quantifies the sustainability through greenhouse gas emission, environmental impacts, and the cost of utilizing FA, LS, and GGBS in soil stabilization compared with traditional lime. LCA was conducted for traditional lime treatment, FA-LS, and FA-GGBS geopolymer-stabilized subgrades to determine the most sustainable treatment method. From the sustainability analysis, using FA, LS, and GGBS as geopolymer stabilizers for kaolin clay reduced the global warming potential by 98.03% and 77.55% over the traditional lime stabilizers at 8% dosage. More importantly, results from the sustainability index (ISus) computations showed that FA-LS (ISus = 12.88) and FA-GGBS (ISus = 29.72) geopolymer treatment methods of EPK clay subgrade soils are more sustainable alternatives compared to the traditional lime (ISus = 48.07) treatment method.

Harrow tines experience large deflections due to varying soil conditions, leading to fatigue failure through cyclic loads. Selecting the appropriate coil diameter, pitch, and number of coils is crucial for designing harrow tines that can withstand these deflections. The aim of this research is to develop new harrow tine designs that offer improved sustainability compared to conventional harrow tines used in the Canadian prairies. Nine double helical torsion spring harrow tine designs were developed, differing in coil diameters, pitch, and number of turns, while keeping the wire diameter constant. A comparative analysis was conducted, considering fatigue life, failure criteria, and stress distribution patterns assessed through Finite Element Modeling (FEM). Additively manufactured 38% scaled harrow tine prototypes underwent load-bearing tests using identical load sets of 20, 50, 100, and 200 grams. The 2T3D2P, 1T4D2.5P, and 2T4D2.5P models emerged as reliable harrow tine designs with higher fatigue life of 14,115, 14,438, and 27,618 cycles compared to the frequently used conventional harrow tine's 7533.87 cycles. Coil diameter has a preferential influence on achieving higher fatigue life, overshadowing the effects of pitch and the number of coils. Furthermore, models with larger coil diameters displayed greater flexibility against the defined weight loads, as observed in the load-bearing tests.

PurposeWeighting in LCA is important as it supports decision-making by prioritising and determining which impact categories are more important. However, the lack of weighting factors in developing countries forces LCA practitioners to adopt weighting values developed for other countries, leading to a less transparent decision-making process. One transparent and easily reproducible distance-to-target (DtT) weighting method that can be applied in Nigeria is the Swiss-developed ecological scarcity method. This method is based on the ratio of the current environmental situation of a country, region or product to the desired policy targets. The purpose of this study was to apply the ESM to develop weighting factors and eco-factors for Nigeria.MethodsThe normalization and current flows data for emissions and resource use in 2010 (base year) were collected from official data sources, and the critical flows were extracted from corresponding policy targets of the Government of Nigeria in 2030 (target year). The ESM was then applied to the aggregated data to derive Nigeria-specific weighting factors and eco-factors as the quantitative indicators for the emissions and resources.Results and discussionWeighting and eco-factors for emissions and resources were developed for 25 environmental issues in Nigeria. NOx, total petroleum hydrocarbon and land use weigh heavily. Except for carcinogenic substances in the air, emissions to water resulted in high eco-factors: TPH, phenol, total nitrogen, nitrate, ammonia and heavy metals (human and ecotoxicity). Policymakers in Nigeria need to set quantitative emission reduction targets for substances and such as carcinogenic substances in the air, oil spills and metal mineral resources.ConclusionsThe ESM was used to develop Nigeria's eco-factors as quantitative indicators for emissions or resource use using the normalization and current flows in 2010 obtained from government data sources as base year data. The critical flows were extracted from the policy targets of the government of Nigeria, with 2030 as the target year. The eco-factors can support environmental sustainability decision-making in Nigeria. Future methodological development should apply updated policy targets and more data to calculate eco-factors for missing substances such as waste (radioactive and non-radioactive), heavy metal emissions to air and soil, emissions to groundwater, photochemical ozone creation substances and phosphorous in surface water and soil.

Global economic growth leads to massive plastic waste increase, posing severe environmental challenges worldwide. Addressing it demands innovative solutions like repurposing plastics for construction. Extensive engineering and environmental assessments can accelerate their adoption. This study explores the potential incorporation of plastic waste (in flake and pellet forms) into a cement-treated fine-grained soil through a comprehensive geotechnical experimental testing program and Life Cycle Assessment (LCA) study to assess their environmental sustainability. Experimental investigations were conducted on four distinct plastic types, namely polypropylene (PP), high-density polyethylene (HDPE), polylactic acid (PLA), and polyethylene terephthalate (PET), with varying weight percent inclusions of 2 %, 4 %, and 6 %. Results revealed a decreasing trend in maximum dry densities and strength (both unconfined compressive strength (UCS) and split tensile strength (STS)) with increasing plastic content. Sorptivity of soil generally increased with plastic inclusions, yet in the case of PET, for plastic content > 4 %, a notable drop in the rate of increase was observed. California bearing ratio (CBR) test results indicated a reduction in the CBR values by up to 18.33 % for 6 % plastic inclusions. LCA study findings favoured plastic flakes over pellets as a more sustainable material choice, exhibiting a lower environmental impact across all assessed indicators. This research findings offer insights into the potential utilization of plastic waste and promote sustainable geomaterial choices in road pavement construction.

Non-point source pollution resulting from agricultural fertilization may enter neighboring water bodies, negatively impacting the environmental water quality. Therefore, this study aims to evaluate the efficiency of innovative fertilization strategies for agricultural non-point source pollution control and explore their benefit for carbon negativity. The results show that organic fertilizers are more likely to be washed out by rainfall or irrigation due to their higher soluble component content. The treatments using bamboo biochar, microbial agents, or both significantly reduced the nitrogen concentrations in infiltration and surface runoff. The washedaway phosphate demonstrated a different trend because adding microbial agents, including phosphorussolubilizing bacteria, converted fixed inorganic phosphorus in the soil into water-soluble phosphorus. In addition, the scouring and leaching in rainfall events mainly cause the farmland's nutrient loss after fertilizer application. The nutrient uptake by crops was increased by 15-30 %, and nutrient mass in infiltration and runoff waters was reduced by 5-10 %. By combining fertilizer reduction and innovative fertilization strategies, the crop yield remained similar to that with a full amount of fertilizer application. Over-dose application in fertilizer may not necessarily promote crop growth but may cause crop damage and fertilizer loss. The carbon negativity benefit of using innovative fertilization strategies was explored, and adding both microbial agents and bamboo biochar in half organic fertilization demonstrated the highest reduction (80.75 %) in carbon emission through synergistic interactions in the soil matrix. The innovative fertilization strategies employed in this study can (1) effectively reduce non-point source pollution from agricultural activities without impairing crops' overall growth and yield and (2) induce the synergistic effects in reducing nutrient loss, enhancing soil carbon sequestration, and mitigating greenhouse gas emissions.

Human activities involving combustion and agricultural practices, among others, lead to the release of acidifying compounds such as nitrogen oxides (NOx), sulfur oxides (SOx), and ammonia (NH3). These substances are the main drivers of human-induced terrestrial acidification, a geochemical process resulting mainly in the decline of soil pH, causing ecosystem damage and biodiversity loss. A relevant tool to quantify impacts of human activities is Life Cycle Assessment where characterization factors are used to estimate the potential environmental impacts per unit of emission. These are derived from models of environmental processes occurring along the stressor's impact pathway, connecting an emission to its potential environmental damage. Here, new ecosystem quality characterization factors for terrestrial acidification were developed, assessing the potential global loss of vascular plant species. The final values combine four elements: existing fate factors, updated soil response factors, recently revised effect factors, and the Global Extinction Probability. The latter allows to convert the local decline in species richness into a global species loss. The regionalized marginal characterization factors provided represent the aggregated global biodiversity impact in all the world's ecoregions due to an acidifying emission (of NOx, NHx, or SOx) from a specific country. The values cover five orders of magnitude (from 10- 16 to 10-11 PDFglobal.yr.kgemitted- 1 ), and the comparison to currently implemented values has helped both validate the calculation pathway and confirm the need for updated factors. Following current harmonization recommendations, terrestrial acidification impacts can now be compared to those from other stressors estimated in global Potential Disappeared Fraction of species.