This study aims to systematically investigate the influence mechanism of particle size and surface roughness on the shear mechanical behavior of spherical particle materials. Rough glass beads with different particle sizes (2 mm, 3 mm, 4 mm) were prepared using sandblasting technique. Together with smooth glass beads, they were used as test raw materials for indoor triaxial consolidated-drained (CD) tests. Based on the quantitative characterization of particle surface roughness, the differences in the shear mechanical properties of spherical particle materials, including stress-strain curves, strength parameters, critical state characteristics, and stick-slip behavior, etc., were discussed from the aspects of the particle size effect (R), the surface roughness index (Ra), and the normalized roughness effect (Ra/R). The main research results show that: increasing the surface roughness of particles can improve various shear mechanical parameters to a certain extent. This includes effectively increasing the peak deviatoric stress, expanding the range of the strength envelope, and raising the deviatoric stress corresponding to the specimen in the critical failure state. It can significantly increase the peak friction angle phi by approximately 10 %-40 % and the critical state line slope (CSL slope) by about 5 %-23 %. Moreover, the increase becomes more pronounced as the particle size decreases. Meanwhile, as the normalized roughness effect (Ra/R) increases, the friction coefficient becomes larger, which greatly weakens the stick-slip behavior between particles.

Our recent investigations have discovered inward diffusion (in-gassing) of moderately volatile elements (MVEs; e.g., Na, K and Cu) from volcanic gas into volcanic beads/droplets. In this work, we examine the distribution of sulfur in lunar orange glass beads. Our analyses reveal that sulfur exhibits a non-uniform distribution across the beads, forming U or W shaped profiles typical of in-gassing. A model developed to assess sulfur contributions from different sources (original magmatic sulfur versus atmospheric in-gassed sulfur) in the orange beads indicates that atmospheric sulfur in-gassed during eruption contributes approximately 9-24 % to the total sulfur content of an orange bead, averaging around 16 %. This in-gassed sulfur is derived from the eruption plume, where atmospheric sulfur could undergo photochemical reactions induced by UV light, leading to mass independent fractionation and a distinct sulfur isotope signature. Interestingly, a recent study discovered a small mass independent isotope fractionation of sulfur in lunar orange glass beads in drive tube 74002/1 and a lack of such mass independent isotope fractionation in black glass beads in the same lunar sample. This finding contrasts with sulfur in lunar basalts, which typically exhibit mass dependent fractionation. With our work, the observed mass independent fractionation signal in sulfur isotopes of orange beads can be attributed to the in-gassing of photolytic sulfur in the optically thin part of the eruption plume where UV light can penetrate. Using the sulfur isotope data of lunar orange beads, we estimate that the 033S value of atmospheric sulfur is approximately -0.18 %o. Our study provides new insights into the complex dynamics of volatile elements in lunar volcanic processes, highlighting the role of in-gassing in shaping sulfur isotope signatures in volcanic glass beads.

Spherical glass beads weaken the influences of particle morphology, surface properties, and microscopic fabric on shear strength, which is significant for revealing the relationship between macroscopic particle friction mechanisms and the particle size distribution of sand. This paper explores the shear mechanical properties of glass beads with different particle size ratios under different confining pressures. It obtains the particle size ratio and fractal dimension D through an optimal mechanical response. Simultaneously, we explore the range of the fractal dimension D under well-graded conditions. The test results show that the strain-softening degree of R-s is more obvious under a highly effective confining pressure, and the strain-softening degree of R-s can reach 0.669 when the average particle size (d) over bar is 0.5 mm. The changes in the normalized modulus ratio E-u/E-u50 indicate that the particle ratio and arrangement are the fundamental reasons for the different macroscopic shear behaviors of particles. The range of the peak effective internal friction angle phi is 23 degrees similar to 35 degrees, and it first increases and then decreases with the increase in the effective confining pressure. As the average particle size increases, the peak stress ratio M-FL and the peak effective internal friction angle phi first increase and then decrease, and both can be expressed using the Gaussian function. The range of the fractal dimension D for well-graded particles is 1.873 to 2.612, and the corresponding average particle size (d) over bar ranges from 0.433 to 0.598. Under the optimal mechanical properties of glass beads, the particle size ratio of 0.25 mm to 0.75 mm is 23:27, and the fractal dimension D is 2.368. The study results provide a reference for exploring friction mechanics mechanisms and the optimal particle size distributions of isotropic sand.

The origin, evolution, and cycling of volatiles on the Moon are established by processes such as the giant moon forming impact, degassing of the lunar magma ocean, degassing during surface eruptions, and lunar surface gardening events. These processes typically induce mass-dependent stable isotope fractionations. Mass-independent fractionation of stable isotopes has yet to be demonstrated during events that release large volumes of gas on the moon and establish transient lunar atmospheres. We present quadruple sulfur isotope compositions of orange and black glass beads from drive tube 74002/1. The sulfur isotope and concentration data collected on the orange and black glasses confirm a role for magmatic sulfur loss during eruption. The Delta S-33 value of the orange glasses is homogenous (Delta S-33 = -0.029 parts per thousand +/- 0.004 parts per thousand, 2SE) and different from the isotopic composition of lunar basalts (Delta S-33 = 0.002 parts per thousand +/- 0.004 parts per thousand, 2SE). We link the negative Delta S-33 composition of the orange glasses to an anomalous sulfur source in the lunar mantle. The nature of this anomalous sulfur source remains unknown and is either linked to (a) an impactor that delivered anomalous sulfur after late accretion, (b) sulfur that was photochemically processed early during lunar evolution and was transported to the lunar mantle, or (c) a primitive sulfur component that survived mantle mixing. The examined black glass preserves a mass-dependent Delta S-33 composition (-0.008 parts per thousand +/- 0.006 parts per thousand, 2SE). The orange and black glasses are considered genetically related, but the discrepancy in Delta S-33 composition among the two samples calls their relationship into question.

The Moon is not volcanically active at present, therefore, we rely on data from lunar samples, remote sensing, and numerical modeling to understand past lunar volcanism. The role of different volatile species in propelling lunar magma ascent and eruption remains unclear. We adapt a terrestrial magma ascent model for lunar magma ascent, considering different compositions of picritic magmas and various abundances of H-2, H2O, and CO (measured and estimated) for these magmas. We also conduct a sensitivity analysis to investigate the relationship between selected input parameters (pre-eruptive pressure, temperature, conduit radius, and volatile content) and given outputs (exit gas volume fraction, velocity, pressure, and mass eruption rate). We find that, for the model simulations containing H2O and CO, CO was more significant than H2O in driving lunar magma ascent, for the range of volatile contents considered here. For the simulations containing H-2 and CO, H-2 had a similar or slightly greater control than CO on magma ascent dynamics. Our results showed that initial H-2 and CO content has a strong control on exit velocity and pressure, two factors that strongly influence the formation of an eruption plume, pyroclast ejection, and overall deposit morphology. Our results highlight the importance of (a) quantifying and determining the origin of CO, and (b) understanding the abundance of different H-species present within the lunar mantle. Quantifying the role of volatiles in driving lunar volcanism provides an important link between the interior volatile content of the Moon and the formation of volcanic deposits on the lunar surface.