The increasing production of waste glass fiber reinforced polymer (GFRP) is causing severe environmental pollution, highlighting the need for an effective treatment method. This study explores recycling waste GFRP powder to substitute ground granulated blast furnace slag (GGBS) in synthesizing geopolymers, aiming to rapidly stabilize clayey soil. The impact of GFRP powder replacement, alkali solution concentration, alkaline activator/precursor (A/P) ratio, and binder content on the geomechanical properties and permeability of stabilized soil was thoroughly examined. The findings revealed that replacing GFRP powder from 20 wt% to 40 wt% lowered the unconfined compressive strength (UCS). However, soil stabilized with 30 wt% GFRP powder displayed the highest shear strength. This indicates that the incorporation of an appropriate amount of GFRP powder elevates clay cohesion. Furthermore, an increase in GFRP powder replacement improved permeability coefficient in the early stages, with minimal impact observed after 28 days. Scanning electron microscopy with energy dispersive spectroscopy (SEM-EDS) analysis revealed a microstructural evolution of the stabilized soil, transitioning from a porous to a denser, more homogeneous composition over the curing period, which can be attributed to the formation of cluster gels enveloping the soil particles. Life cycle assessment (LCA) analysis indicated that the GFRP powder/GGBS geopolymer presents an alternative option to traditional Ordinary Portland Cement (OPC) binder, featuring a global warming potential (GWP)/strength ratio reduction of 6 %-40 %. This research offers a practical solution for effectively utilizing GFRP waste in a sustainable manner, with minimal energy consumption and pollution, thereby contributing to the sustainable development of soil stabilization.
The accumulation of waste glass (WG) from construction and demolition waste is detrimental to the environment due to its imperishable nature; therefore, it is crucial to investigate a sustainable way to recycle and reuse the WG. To address this issue, this study examined the mechanical strength, microstructural characteristics, and environmental durability-specifically under wet- dry (WD) and freeze-thaw (FT) cycles-of WG obtained from construction and demolition waste, with a focus on its suitability as a binding material for soil improvement applications. Firstly, sand and WG were mixed, and an alkali solution was injected into the mixture, considering various parameters, including WG particle size, mixing proportions, sodium hydroxide (NaOH) concentration, and curing time. Subsequently, the effect of WG grain sizes on micro- morphology characteristics and mineralogical phases was evaluated before and after the treatment through X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), and ultrasonic pulse velocity (UPV). The results revealed that reducing the WG particle size and increasing the WG/S ratio significantly improved the strength of the WG-treated samples. Additionally, decreasing the NaOH concentration and extending the curing time also positively influenced their strength. The UCS test results indicate that the particle size of WG significantly influenced the strength development of the samples, as the maximum compressive strength increased from 1.42 MPa to 7.82 MPa with the decrease in particle size. Although the maximum UCS values of the samples varied with different WG particle sizes, the values exceed the minimum criterion of 0.80 MPa required for use as a road substructure, as specified in the ASTM D4609 standard. Moreover, as WG grain size decreased, more geopolymer gels formed, continuing to fill the voids and making the overall structure denser, and the changes during geopolymerization were confirmed by XRD, SEM, FTIR, and UPV analysis. The optimum WG/S ratio was found to be 20 %, with strength increasing by approximately 3.88 times higher as the WG/S ratio shifted from 5 % to 20 %. In addition, the optimum NaOH concentration was determined to be 10 M, as higher molarities led to a decrease in strength. Moreover, UPV results indicate that WG-treated sand soils exhibited UPV values 9.4-13 times greater than untreated soils. The WD and FT test results indicate that WG-treated samples experienced more rapid disintegration in the WD cycle than in the FT cycle; however, a decrease in WG particle size resulted in reduced disintegration effects in both WD and FT conditions. In both the FT and WD cycles, the declining trend exhibited a stable tendency around the eighth cycle. Nevertheless, the WD cycling damage considerably intensified disintegration, causing a profound deterioration in the structural integrity of the samples. As a result, repeated WD cycles lead to the formation of microcracks, which progressively weaken soil aggregation and reduce the overall strength of the samples. Consequently, this green and simple soil improvement technique can provide more inspiration for reducing waste and building material costs through efficient use of construction and demolition waste.
As lunar exploration advances, the development of durable and sustainable lunar surface architecture is increasingly critical, with a particular focus on material selection and manufacturing processes. However, current technologies and designs have yet to deliver an optimal solution. This study presented an innovative designs pattern for laser-sintered lunar soil bricks, namely a sintered glass outer layer and a core composed of lunar soil particles. For structural reinforcement purposes, a combined system of columns and slabs was implemented to improve the overall strength characteristics. This approach leverages the low thermal conductivity of lunar regolith particles in conjunction with the thermal stability, radiation resistance, and mechanical strength characteristics of glass. In this case, our simulations of heat conduction demonstrated a marked improvement in the thermal insulation properties of the new lunar soil bricks. The low thermal conductivity of lunar regolith effectively serves as an insulating layer, while the column, plate and glass outer layer, with their higher thermal conductivity, enable rapid thermal response across the entire structure and enhance spatial heat transfer uniformity. We further investigated the influence of structural variations on heat transfer mechanisms, revealing that the thickness of the glass layer exclusively modulates the heat transfer rate without altering its spatial distribution. Additionally, comparative analysis of all designed samples demonstrated that the novel sample displays superior thermal insulation properties, reduces average energy consumption by three quarters, and maintains adequate mechanical strength, alongside the proposal of a suitable assembly and construction methodology. Consequently, we believe that glassy composites exhibit substantial potential for space construction. These findings offer valuable insights and recommendations for material design in lunar surface construction.
Sulfate saline soil is considered as an inferior subgrade construction material that is highly susceptible to damage from salt heaving and dissolution. Polyurethane/water glass (PU/WG) is an efficient grouting material widely used in underground engineering; however, its application in saline soil reinforcement has not yet been reported. In this study, PU/WG was used to solidify sulfate-saline soils. The influence of the dry density, curing agent ratio, and salt content on the strength was evaluated. The mechanical properties of the solidified soil were determined by conducting uniaxial compression strength tests, and crack development was detected using acoustic emission technology. The reinforcing mechanism was revealed by scanning electron microscopy tests and mercury intrusion porosimetry. The results indicated that the peak stress, peak strain, and ultimate strain increased with increasing dry density and PU/WG content, whereas they decreased with increasing salt content. The relationship between the peak stress, density, and PU/WG can be described using linear functions. The relationship between the peak stress and salt content can be described by a second-order polynomial function. The larger the dry density and the higher the PU/WG content, the steeper the stress-strain curves and the lower the ductility. Further, the higher the salt content, the higher the ductility. Soil with a higher dry density, more PU/WG, and less salt content exhibited higher brittleness. Thus, PU/WG can fill in the original disorganized and large pores, thereby increasing the complexity of the internal pore structure via organic-inorganic gel reactions.
Accurate determination of potassium ion (K+) concentration in fingertip blood, soil pore water, pipette solution, and sweat is crucial for performing biological analysis, evaluating soil nutrients levels, ensuring experimental precision, and monitoring electrolyte balance. However, current electrochemical K+ sensors often require large sample volumes and oversized reference electrodes, which limits their applicability for the aforementioned small-volume samples. In this paper, a K+ sensor integrated with a glass capillary and a spiral reference electrode was proposed for detecting K+ concentrations in small-volume samples. A K+-selective membrane (K+-ISM)/ reduced graphene oxide-coated acupuncture needle (working electrode) was spirally wrapped with a chitosangraphene/AgCl-modified Ag wire (reference electrode). This assembly was then inserted into a glass capillary, forming an anisotropic diffusion region of an annular cylindrical gap with width 410 mu m and height 20 mm. It was found that the capillary action of the glass capillary results in a raised liquid level of the sample inside it compared to that in the container, which promotes efficient contact between the small-volume sample and the K+ sensor. Besides, the formed anisotropic diffusion region limits the K+ diffusion from the bulk solution to the K+ISM, which leads to a larger potentiometric response of the K+-ISM. The glass capillary-assembled K+ sensor displays high performance, including a sensitivity 58.3 mV/dec, a linear range 10_ 5-10_ 1 M, and a detection limit 1.26 x 10_6 M. Moreover, it reliably determines K+ concentrations in artificial sweat of microliter volume. These results facilitate accurate detection of K+ concentration in fingertip blood, soil pore water, and pipette solution.
This study investigated the improvement in a type of sand using a geopolymer made of recycled glass powder (RGP) as the base material and sodium hydroxide (NaOH) as the alkaline activator. Using maximum uniaxial compressive strength (UCS), the impact of alkaline activator concentration and the RGP content were investigated to determine the optimum mix design. Groundwater level increments were simulated through a laboratory procedure to study the effect of curing age and capillary action on the behavior of stabilized soil. The UCS of samples at different ages (14, 28, 45, and 60 days) and different degrees of saturation (Sr=0%, 20%, 50%, 80%, and 100%) were determined and their stress-strain diagrams were drawn. Using the stress-strain relationships, UCS, modulus of elasticity (Es), shear modulus (G), and resilient modulus (Mr) of the stabilized soil were estimated. The results showed that fully saturated stabilized samples did not disintegrate and exhibited a considerable UCS of up to 1.88 MPa at the age of 60 days. The greatest observed reduction in the UCS through saturation was between Sr=0 to 20%. To further investigate and validate the mechanical results, chemical and microstructural studies including X-ray fluorescence (XRF), scanning electron microscopy (SEM), energy dispersive X-ray analysis (EDX), X-ray diffraction analysis (XRD), and Fourier transform infrared spectroscopy (FTIR) were carried out. The results showed that during the curing period, the silicon/aluminum (Si/Al) ratio increased from 2.98 in untreated soil to 4 in stabilized samples, indicating active geopolymerization, which enhanced UCS and reduced the potential for disintegration. Additionally, the crystal size decreased from 53 to 24 nm for the 45-day stabilized samples when the degree of saturation changed from 0% to 100%. This finding suggests that if RGP-based geopolymer-stabilized soil contacts water after fully drying, geopolymerization reactions will resume that involve the dissolution of both crystalline and amorphous phases.
This study explores a novel stabilization technique combining Persian gum (PG), an eco-friendly biopolymer, and glass fiber (GF) to enhance the strength and durability of fine-grained soils under freeze-thaw (F-T) cycles. Specimens were prepared at maximum dry density (MDD) with varying PG and GF contents, cured for 0, 7, or 14 days, and subjected to 0, 5, 7, or 10 F-T cycles. Tests included Standard Proctor compaction, Scanning Electron Microscopy (SEM), Unconfined Compressive Strength (UCS), and Direct Shear (DS). Results demonstrated that GF significantly improved durability, ductility, and strength by enhancing interparticle interaction and friction angle. The results indicated that at an optimum GF content of 1%, UCS and E-5(0) increased by up to 35%. Also, after 10 F-T cycles, UCS decreased by 46% for untreated soil and 36% for treated soil. PG enhanced cohesion through interparticle bonding, which was curing-time-dependent. Specimens with 2.5% PG (optimum content) showed a 133% UCS increase after 14 days of curing but a 9% reduction after 5 F-T cycles, with 70% of total UCS loss occurring in the first 5 cycles. The tests indicated that formation of large and stable soil-PG-GF matrix with improved rigidity, strength, and F-T resistance. The results demonstrated that the suggested soil stabilization method, which utilizes low-cost, eco-friendly materials, was effective.
This study aims to systematically investigate the influence mechanism of particle size and surface roughness on the shear mechanical behavior of spherical particle materials. Rough glass beads with different particle sizes (2 mm, 3 mm, 4 mm) were prepared using sandblasting technique. Together with smooth glass beads, they were used as test raw materials for indoor triaxial consolidated-drained (CD) tests. Based on the quantitative characterization of particle surface roughness, the differences in the shear mechanical properties of spherical particle materials, including stress-strain curves, strength parameters, critical state characteristics, and stick-slip behavior, etc., were discussed from the aspects of the particle size effect (R), the surface roughness index (Ra), and the normalized roughness effect (Ra/R). The main research results show that: increasing the surface roughness of particles can improve various shear mechanical parameters to a certain extent. This includes effectively increasing the peak deviatoric stress, expanding the range of the strength envelope, and raising the deviatoric stress corresponding to the specimen in the critical failure state. It can significantly increase the peak friction angle phi by approximately 10 %-40 % and the critical state line slope (CSL slope) by about 5 %-23 %. Moreover, the increase becomes more pronounced as the particle size decreases. Meanwhile, as the normalized roughness effect (Ra/R) increases, the friction coefficient becomes larger, which greatly weakens the stick-slip behavior between particles.
Salicornia europaea L. is a euhalophyte increasingly cultivated as a high-value green vegetable. In July 2021, root and crown rot occurred on 6-month-old S. europaea plants grown in peat-filled pots under a greenhouse, affecting 25% of plants. The causal agent was identified as Fusarium pseudograminearum O'Donnell & T. Aoki using morphological and molecular analyses. An experiment to assess the pathogenicity of this fungus to S. europaea was conducted with 96 seedlings in hydroponic culture. Half of these plants were inoculated with a conidial suspension of F. pseudograminearum. At 24 days post inoculation (dpi), half of the plants were transferred into a new hydroponic system, while the other plants were transplanted into pots. At 80 dpi, all inoculated plants grown in pots had shoot browning and desiccation symptoms, while these symptoms developed more slowly in 70% of the hydroponically grown inoculated plants. A qualitative symptom severity assessment scale showed that disease severity was greater (63%) in pot-grown plants than in hydroponically grown plants (46%). Fusarium pseudograminearum was consistently reisolated from diseased plants in both cultivation systems (62% from pots and 83% from hydroponics) fulfilling Koch's postulates. Production of deoxynivalenol (DON) and zearalenone (ZEA) was investigated in vitro and in planta. Traces of DON (0.029 +/- 0.012 mg kg(-1)) were found in severely damaged plants grown in hydroponics. In the in vitro test, F. pseudograminearum isolates from wheat crops in Spain (isolate ColPat-351) and Italy (isolate PVS Fu-7) were also assessed, and all tested isolates produced considerable amounts of ZEA. Fusarium pseudograminearum isolates obtained from S. europaea produced more DON (6.81 +/- 0.24 mg kg(-1), on average) than the Italian isolate PVS Fu-7 (0.37 +/- 0.06 mg kg(-1)), while DON production by the Spanish isolate ColPat-351 was less than the limit of detection (< 0.25 mg kg(-1)). This is the first report of root and crown rot caused by F. pseudograminearum on S. europaea.
Restoration of coastal dunes following tropical storm events often requires renourishment of sand substrate dredged from offshore sources, although dredging has well-described negative ecological impacts and high economic costs. As a potential solution, recycled glass sand (cullet) made from crushed glass bottles has been proposed as a potential replacement for dredging. However, glass sand substrates may have limited ability to provide support to coastal plant communities due to the absence of native soil microbial communities. To explore the potential use of glass sand as a substrate for dune plants in the Northern Gulf of Mexico, we compared the growth of Sea oats (Uniola paniculata), Beach morning-glory (Ipomoea imperati), and Railroad vine (I. pes-caprae) in glass sand to growth in live beach sand. To determine if inoculation of glass sand with native soil microbial communities improved survival, growth, and biomass production, we also tested plant growth in glass sand with native microbial amendments. Overall, we found no difference in the survival of the three dune species across three soil treatments and weak differences in plant growth and biomass production across our soil substrates. Our results suggest that glass sand substrates may be a viable option for coastal dune restoration, with limited differences between live beach sand, glass sand, and glass sand inoculated with native soil microbes. Restoration and replenishment of coastal dunes using glass sand as a substrate following tropical storms or sea-level rise may allow coastal managers to reduce the economic and ecological damage associated with offshore sediment dredging.