Geopolymer-based cementitious materials known for their robust durability and lower environmental impact make them an ideal choice for sustainable construction. The main focus of this study is to understand the influence of chemical admixtures which plays a pivotal role in improving the properties of geopolymer mortar (GM). This research integrates various chemical admixtures, including calcium chloride, sodium sulphate, sodium hexametaphosphate, and MasterGlenium SKY 8233 (SKY) which falls under the category of either accelerators, retarders, or superplasticisers. Assessments were conducted on the fresh and hardened states of flyashbased GM mixes with varying proportion of river sand (RS), laterite soil (LS) and copper slag (CS), encompassing flowability, setting times, compressive strength, durability study in aggressive environmental conditions and microstructural analyses after 56 days of ambient curing. Findings reveal that calcium chloride and sodium sulphate efficiently decrease the initial and final setting times of the geopolymer paste, highlighting their roles as accelerators, with calcium chloride showing greater efficacy than sodium sulphate. On the other hand, sodium hexametaphosphate serves as a retarder, substantially extending the initial setting time of the geopolymer paste. Introducing the modified polycarboxylic ether (PCE) based superplasticiser SKY into the mortar matrix caused the initial setting time to be extended and resulted in a slight drop in compressive strength compared to the other mixes. Durability tests confirmed the superior resistance of GM mixes to harsh environments like acid, sulphate, and marine water exposure. These findings highlight the potential for tailoring geopolymer blends to achieve desired properties under ambient curing conditions using chemical admixtures.

The development of new urban areas necessitates building on increasingly scarce land, often overlaid on weak soil layers. Furthermore, climate change has exacerbated the extent of global arid lands, making it imperative to find sustainable soil stabilization and erosion mitigation methods. Thus, scientists have strived to find a plant-based biopolymer that favors several agricultural waste sources and provides high strength and durability for sustainable soil stabilization. This contribution is one of the first studies assessing the feasibility of using inulin to stabilize soil and mitigate erosion. Inulin has several agricultural waste sources, making it a sustainable alternative to traditional additives. Soil samples susceptible to wind erosion were collected from a dust-prone area in southwest Iran and treated with inulin at 0%, 0.5%, 1%, and 2% by weight. Their mechanical strength was evaluated using unconfined compressive strength tests and a penetrometer. In addition, wind tunnel tests (at 16 m/s) were performed to investigate inulin's wind erosion mitigation potential. The durability of treated samples was evaluated after ten wetting-drying cycles to assess the effect of environmental stressors. The results indicated a 40-fold increase in the unconfined compressive strength (up to 8 MPa) of the samples treated with 2% inulin and only 0.22% weight loss after ten wetting-drying cycles. SEM images revealed the formation of biopolymer-induced particle-to-particle bonds. Moreover, Raman spectroscopy indicated molecular (hydrogen) bonding of the biopolymer hydrogel-soil particles facilitated by the hydroxyl groups of inulin. The deterioration in stiffness and strength of treated samples was less noticeable after 3rd dry-wet cycle, indicating the durability of the samples. The durability of samples against wet-dry cycles was attributed to molecular bonding of soil-biopolymer hydrogel, as revealed by FTIR analysis.