In the reinforcement of micro-cracks and soil, cement grouting often suffers from poor injectability due to particle size limitations. While ultra-fine cement produced through physical grinding can address this issue, it significantly increases cost and energy consumption. Moreover, ultra-fine cement is prone to aging when exposed to moisture and CO2 in the air. To address these issues, this study proposes a new approach for in-situ particle size reduction of cement slurry through the mild corrosion of acetic acid. The refining effect of acetic acid on cement particles was investigated, along with its impact on mechanical properties and hydration products. The results show that acetic acid accelerates cement dissolution, promoting early-stage strength development and microstructure formation. The addition of 1.2 wt% acetic acid reduced the D90 particle size of the slurry by 36.4 %. Acetic acid also enhances the release of Ca2+ from clinker, increasing the precipitation of Ca(OH)2, CaCO3, and calcium silicate hydrate (C-S-H) at early stages, which serves as the primary source of early strength. Additionally, it raises the Ca/Si ratio of the early-formed C-S-H gel. However, excessive acetic acid can inhibit the further development of strength at later stages. The research demonstrates that premixed acetic acid activation is an effective approach for enhancing the performance of cementitious grouting materials, with promising potential to reduce energy consumption associated with physical cement grinding.

To address scour hazards surrounding offshore foundations, a new method employing novel alkali-activated cementitious grout (AACG) has been proposed for improvement of seabed soil. Ground granulated blastfurnace slag (GGBFS) was replaced by fly ash (FA), steel slag (SS) or FA + SS to prepare precursors, the replacement amounts were 10 %, 20 %, 30 % and 40 %. Fresh-state and mechanical properties, minerals and microstructures were investigated. A novel scour simulation test device was developed to simulate engineering conditions of scour and remediation. Flow-soil coupled scour resistance tests were conducted, shear tests and SEM measurements of solidified soil were carried out. The results showed that the optimal ratio of GGBFS:FA:SS was 6:2:2 for AACG. The optimized AACG has better fluidity and lower brittleness, and its 28 d unconfined compressive strength (UCS) achieves 13.5 MPa. For AACG solidified soil, the maximum scour depth was reduced by 33.3 % and the maximum sediment transport amount was decreased by 53.2 %, which were compared to those of cement - sodium silicate (C-S) double slurry. Moreover, the increase degrees of internal friction angle, cohesion and critical shear stress were 700 %, 7.9 % and 786 %, respectively. The scour resistance of AACG solidified soil was superior. The inherent relationship between UCS and critical shear stress was discussed. UCS can be used to rapidly assess the scour resistance of consolidated soil. This study introduced an eco-friendly AACG as an innovative stabilizer for soil reinforcement around offshore structural foundations, offering significant application and environmental values for scour control.

To study scour-resistant applicability, 6-10% mass ratio of polyurethane (PU) was added to sulphoaluminate cement (SAC) and ordinary Portland cement (OPC) grouts to generate OPCPU and SACPU. Sodium silicate (SS) with slurry volume ratio of 1:1-5:1 was added to SAC and OPC grouts to generate OPCSS and SACSS. The water-cement ratio (w/c) of grout was 0.8-1.5. Fresh-state properties and mechanical properties were investigated. Hydrated minerals and microstructures were analyzed, scouring tests were conducted considering key formulations. The results indicated that SACSS and OPCSS have a shorter setting time and higher strength, which makes them suitable as scour resistance materials. At the w/c of 1.0, OPCSS with a volume ratio of 3:1 and SACPU with 6% PU were selected for scour resistance tests. It showed that maximum scour depths and sediment transports were 7.0-12.2 and 1.1-1.2% as those without reinforcing conditions. The critical shear stress on the seabed under reinforcement is similar to 103 times greater than the bed shear stress. This inhibits the occurrence of scouring. The study evaluated the applicability of cementitious reinforcement for scour resistance. This study analyzed material and mechanical properties, hydrated minerals, and microstructures, and conducted scour tests to optimize grouting material ratios for seabed scour protection, providing references for soil reinforcement and grouting protection.