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Silica fume and carbide slag can be used to modify waste mud soil (WMS), which can not only improve the mechanical properties of WMS, but also broaden resource utilization ways of silica fume and carbide slag. For that, in this paper, WMS was modified by adopting 8 % carbide slag and silica fume with different dosages (0, 3 %, 5 %, 7 %, 9 %, and 11 %). Then the small-strain dynamic properties of modified WMS were investigated by using resonance column test, and the microscopic mechanism of modified WMS was analyzed based on Scanning electron microscopy (SEM), Energy dispersive X-ray spectrometer (EDS), Transmission electron microscopy (TEM), X-ray diffraction test (XRD) and Mercury intrusion porosimetry (MIP). It can be found from the resonance column test that the dynamic shear modulus and the damping ratio show an increasing and decreasing trend with the increase of the confining pressure respectively, and both increase with increasing silica fume dosage in the range of 0 to 11 %. A kinetic model applicable to modified WMS was established by introducing the effects of confining pressure and silica fume into the Hardin-Drnevich model. Microscopic testing experiments indicate that there is a reaction between reactive SiO2 in silica fume and Ca(OH)2 in carbide slag, and calcium hydrated silicate (CSH) was generated, which improved the specimen density.

期刊论文 2025-10-01 DOI: 10.1016/j.susmat.2025.e01464 ISSN: 2214-9937

In response to the environmental challenges posed by conventional expansive soil stabilization methods, this study investigates the low-carbon potential of industrial by-products-cement kiln dust (CKD) and calcium carbide slag (CCS)-as sustainable stabilizers. A comprehensive series of laboratory tests, including compaction tests, free swelling rate measurements, unconfined compressive strength (UCS) evaluations, and scanning electron microscopy (SEM) analyses, were conducted on expansive soil samples treated with varying dosages in both single and binary formulations. The results indicate that the binary system significantly outperforms individual stabilizers; for example, a formulation containing 10% CKD and 9% CCS achieved a maximum dry density of 1.64 g/cm3, reduced the free swelling rate to 22.7% at 28 days, and reached a UCS of 371.3 kPa. SEM analysis further revealed that the enhanced performance is due to the synergistic formation of hydration products-namely calcium silicate hydrate (C-S-H) and calcium aluminate hydrate (C-A-H)-which effectively fill interparticle voids and reinforce soil structure. These findings demonstrate that the dual mechanism, combining rapid early-stage hydration from CCS with sustained long-term strength development from CKD, offers a cost-effective and environmentally sustainable alternative to traditional stabilizers for expansive soils.

期刊论文 2025-03-19 DOI: 10.3389/feart.2025.1554812

In this study, carbide slag (CS) and coal gangue (CG) powder were utilized to enhance the properties of the subgrade soil. CS-CG stabilized soil underwent lab experiments to assess its mechanical properties and durability. Tests included unconfined compressive strength (UCS), compressive resilient modulus (CRM), and California bearing ratio (CBR) at stabilizer dosages of 5 %, 10 %, and 15 %. Additional tests, such as dry-wet cycling, salt solution immersion, permeability, leaching, thermogravimetric analysis (TGA), X-ray diffraction (XRD), scanning electron microscope (SEM) and mercury intrusion porosimetry (MIP), were conducted specifically for the 10 % dosage. The mechanical properties and durability were comprehensively analyzed, with a microscopic investigation into pore size. Furthermore, the soil-water characteristic curve (SWCC) of CS-CG stabilized soil is derived through MIP, providing insights into its impact on the material's strength. Results showcased favorable bearing capacity and durability of CS-CG stabilized soil. The optimal mixing dosage is 10%, with the best ratio being CS: CG= 70: 30. After 6 dry-wet cycles, UCS loss rate was 18.6%, comparable to 4% Portland cement (PC) stabilized soil. Dry-wet cycle characteristics surpassed PC and Lime stabilized soils. Immersion in a 5 % NaCl solution for 30 days yielded a UCS of 3.8 MPa at 28-day age, while exposure to 5 % Na2SO4 solution led to an 11.6 % strength decrease compared to NaCl. Permeability coefficient indicated low permeability akin to PC and Lime stabilized soils. Heavy metal content met standards, with minimal increase during cycles. Hydration products mainly comprised C-S-H gel, Ca(OH)2 crystals, and carbonate modification. Analysis suggested capillary and transition pores predominantly, with minimal macropores presence. Dry-wet cycles induced a marginal increase in pore size, with negligible overall impact. SWCC predicted water content (theta s) ranged from 30 % to 32 %, with a slight increase in matrix suction during dry-wet cycles. CS-CG stabilized soil shows favorable mechanical properties, durability, and environmental sustainability, indicating its potential as a substitute for traditional cement and lime treatments in subgrade soil reinforcement.

期刊论文 2024-09-06 DOI: 10.1016/j.conbuildmat.2024.137634 ISSN: 0950-0618

This study addresses the engineering geological disaster resulting from the degradation of mechanical properties of expansive soil due to changes in environmental humidity along the Middle Route of the South-to-North Water Transfer Project. Calcium carbide slag and slag are utilized as curing materials to improve the expansive soil. Comparative tests were conducted on the unconfined compressive strength, split tensile strength, and water stability of untreated and treated expansive soil to analyze the performance differences pre- and post-treatment. The strength enhancement mechanism of the calcium carbide slag-slag cured soil was investigated through the X-ray diffraction (XRD), electron microscope scanning (SEM), thermogravimetric analysis (TGA) test and nuclear magnetic resonance (NMR) test, revealing its microscopic mechanism of action. The results showed a significant increase in the overall strength and water resistance of the calcium carbide slag-slag composite modified cured soil with different slag dosage based on 6% dosage of calcium carbide slag, and a maximum value was reached when the slag dosage was 9%. Over time, the unconfined compressive strength and split tensile strength improved, while the water stability coefficient decreased notably. Hydration of calcium silicate hydrate (C-S-H) and calcium aluminate hydrate (C-A-H) generated by the hydration of calcium carbide slag-slag composite cured soil led to the formation of tightly bonded soil particles, enhancing the soil's pore structure distribution and strength. The evident effectiveness of the composite curing method for calcium carbide slag-slag treated soil suggests promising engineering applications.

期刊论文 2024-08-01 DOI: 10.16285/j.rsm.2023.1172 ISSN: 1000-7598

Shield tunnel muck are usually discarded due to high water content and poor engineering properties, resulting in occupation of land sources and waste of soil sources. Meanwhile, large amounts of industrial waste such as carbide slag (CS) and soda residue (SR) are landfilled with a low reuse rate, which poses a threat to the natural environment. This study aims to improve waste shield tunnel muck using CS and SR and traditional lime, and the improved tunnel muck is expected to be used in subgrade filling to provide a new approach to solve this dilemma. A series of physical, mechanical, subgrade property, and microcosmic tests were conducted on shield tunnel muck improved by CS, SR and lime. The effects of different mixing proportions on the properties of improved tunnel muck were examined. The micro-improvement mechanisms of CS and SR on tunnel muck were explored. Results indicate that the addition of CS or SR can effectively improve the physical and mechanical properties of shield tunnel muck. CS plays a significantly role than SR in improving physical and mechanical properties of tunnel muck. A synergistic enhancement is observed as the combined CS and SR are added, and the optimal mixing proportion of tunnel muck to CS to SR is found to be 100:6:2 with a fixed lime content of 4 %. The alkaline environment created by the synergistic action of CS and SR promotes the dissolution of the active ions in soils, and the generated crystals and gelling products of hydration significant contribute to soil improvement. The tunnel muck improved with appropriate CS or SR content could meet the requirements for light or medium traffic load levels and can be effectively utilized as subgrade filling.

期刊论文 2024-05-17 DOI: 10.1016/j.conbuildmat.2024.136419 ISSN: 0950-0618
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