Black carbon (BC) is a major short-lived climate pollutant (SLCP) with significant climate and environmentalhealth impacts. This review synthesizes critical advancements in the identification of emerging anthropogenic BC sources, updates to global warming potential (GWP) and global temperature potential (GTP) metrics, technical progress in characterization techniques, improvements in global-regional monitoring networks, emission inventory, and impact assessment methods. Notably, gas flaring, shipping, and urban waste burning have slowly emerged as dominant emission sources, especially in Asia, Eastern Europe, and Arctic regions. The updated GWP over 100 years for BC is estimated at 342 CO2-eq, compared to 658 CO2-eq in IPCC AR5. Recent CMIP6-based Earth System Models (ESMs) have improved attribution of BC's microphysics, identifying a 22 % increase in radiative forcing (RF) over hotspots like East Asia and Sub-Saharan Africa. Despite progress, challenges persist in monitoring network inter-comparability, emission inventory uncertainty, and underrepresentation of BC processes in ESMs. Future efforts could benefit from the integration of satellite data, artificial intelligence (AI)assisted methods, and harmonized protocols to improve BC assessment. Targeted mitigation strategies could avert up to four million premature deaths globally by 2030, albeit at a 17 % additional cost. These findings highlight BC's pivotal roles in near-term climate and sustainability policy.

Canopy reflectance (CR) models describe the transfer and interaction of radiation from the soil background to the canopy layer and play a vital role in the retrieval of biophysical variables. However, few efforts have focused on estimating soil background scattering operators, resulting in uncertainties in CR modelling, especially over sloping terrain. This study developed a canopy reflectance model for simulating CR over sloping terrain, which combines the general spectral vector (GSV) model, the PROSPECT model, and 4SAIL model coupled with topography (GSV-PROSAILT). The canopy reflectance simulated by GSV-PROSAILT was validated against two datasets: discrete anisotropic radiative transfer (DART) simulations and remote sensing observations. A comparison with DART simulations under various conditions revealed that the GSV-PROSAILT model captures terrain-induced CR distortion with high accuracy (red band: coefficient of determination $\lpar {\rm R 2} \rpar = 0.731$(R2)=0.731, root-mean-square error (RMSE) = 0.007; near infrared (NIR) band: $\rm R2 = 0.8319$R2=0.8319, RMSE = 0.0098). The results of remote sensing observation verification revealed that the GSV-PROSAILT model can be successfully used in CR modelling. These validations confirmed the performance of GSV-PROSAILT in soil and canopy reflectance modelling over sloping terrain, indicating that it can provide a potential tool for biophysical variable retrieval over mountainous areas.

The Tibetan Railway has introduced pressures on the fragile grassland ecosystems of the Tibetan Plateau. However, the impact of the railway on the carbon sequestration remains unclear, as existing studies primarily focus on in-situ vegetation observations. In this study, we extracted the start and end of the growing season (SOS, EOS) and maximum daily GPP (GPPmax) along the railway corridor from the satellite-derived Gross Primary Productivity (GPP) data, and quantified the extent and intensity of the railway's disturbance on these indicators. We further employed the Statistical Model of Integrated Phenology and Physiology (SMIPP) to translate these disturbances into annual cumulative GPP (GPPann). Results show that Tibetan Railway significantly influences grassland within 50-meters, causing earlier SOS (0.1086 d m-1), delayed EOS (0.0646 d m-1), and reduced GPPmax (0.0069 gC m-2 d-1 m-1) as the distance to the railway gets closer. The advanced SOS and delayed EOS contributed gains of 28.82 and 104.26 MgC y-1, but reduction in GPPmax accounted for a loss of 2952.79 MgC y-1. Railway-induced phenology-physiology trade-off causes GPPann loss of 2819.71 MgC y-1. This study reveals Tibetan Railway's impact on grassland carbon cycling, offering insights for grassland conservation and sustainable transportation infrastructure projects.

An analytical methodology was developed for the first time in this work enabling the simultaneous enantiomeric separation of the fungicide fenpropidin and its acid metabolite by Capillary Electrophoresis. A dual cyclodextrin system consisting of 4 % (w/v) captisol with 10 mM methyl-beta-cyclodextrin was employed in a 100 mM sodium acetate buffer at pH 4.0. Optimal experimental conditions (temperature 25 degrees C, separation voltage -25 kV, and hydrodynamic injection of 50 mbar x 10 s) allowed the simultaneous separation of the four enantiomers in <10.7 min with resolutions of 3.1 (fenpropidin) and 3.2 (its acid metabolite). Analytical characteristics of the method were evaluated and found adequate for the quantification of both chiral compounds with a linearity range from 0.75 to 70 mg L-1, good accuracy (trueness included 100 % recovery, precision with RSD<6 %), and limits of detection and quantification of 0.25 and 0.75 mg L-1, respectively, for the four enantiomers. No significant differences were found between the concentrations determined and labelled of fenpropidin in a commercial agrochemical formulation. The stability over time (0-42 days) of fenpropidin enantiomers using the commercial agrochemical formulation was evaluated in two sugar beet soils, revealing to be stable at any time in one sample, while in the other a decrease of 45 % was observed after 42 days. Individual and combined toxicity of fenpropidin and its metabolite was determined for the first time for marine organism Vibrio fischeri, demonstrating higher damage caused by parent compound. Synergistics and antagonists' interactions were observed at low and high effects levels of contaminants.

Vegetation greening across the Tibetan Plateau, a critical ecological response to climate warming and land-cover change, affects soil hydrothermal regimes, altering soil moisture (SM) and soil temperature (ST) dynamics. However, its effects on SM-ST coupling remain poorly understood. Using integrated field measurements from a vegetation-soil (V-S) network, reanalysis, and physics-based simulations, we quantify responses of SM, ST, and their coupling to vegetation changes across the Upper Brahmaputra (UB) basin, southern Tibetan Plateau. Results show that strong positive SM-ST correlations occur throughout 0-289 cm soil layers across the basin, consistent with the monsoon-driven co-occurrence of rainy and warm seasons. Spatially, SM-ST coupling strength exhibits pronounced spatial heterogeneity, demonstrating strongest coupling in central basin areas with weaker intensities in eastern and western regions. Overall, vegetation greening consistently induces soil warming and drying: as leaf area index (LAI) increases from 20 % to 180 % of its natural levels, SM (0-160 cm) declines by 15 % to 29 % due to enhanced evapotranspiration and root water uptake. Mean ST simultaneously increases by 1.4 +/- 0.9 degrees C. Crucially, sparsely vegetated regions sustain warming (1.4-2.1 degrees C), while densely vegetated areas transition from initial warming to gradual cooling. These findings advance our understanding of soil hydrothermal dynamics and their broader environmental impacts, improving climate model parameterizations and informing sustainable land management strategies in high-altitude ecosystems.

Abandoned farmlands are increasing due to socio-economic changes and land marginalization, and they require sustainable land management practices. Biocrusts are a common cover on the topsoil of abandoned farmlands and play an important role in improving soil stability and erosion resistance. The critical functions of biocrusts are known to mostly rely on their biofilaments and extracellular polymeric substances (EPS), but how these components act at microscopic scale is still unknown, while rheological methods are able to provide new insights into biocrust microstructural stability at particle scale. Here, bare soil and two representative types of biocrusts (cyanobacterial and moss crusts) developed on sandy (Ustipsamments) and sandy loam (Haplustepts) soils in abandoned farmlands in the northern Chinese Loess Plateau were collected at a sampling depth of 2 cm. Changes in the rheological properties of the biocrusts were analyzed with respect to their biofilament network and EPS contents to provide possible explanations. The rheological results showed that compared with bare soil, storage and loss moduli were decreased by the biocrusts on sandy soil, but they were increased by the biocrusts on sandy loam soil. Other rheological parameters tau max, gamma L, gamma YP, and Iz of biocrusts on both soils were significantly higher than those of bare soil, showing higher viscoelasticity. And the moss crusts had about 10 times higher rheological property values than the cyanobacterial crusts. Analysis from SEM images showed that the moss crusts had higher biofilament network parameters than the cyanobacterial crusts, including nodes, crosslink density, branches, branching ratio and mesh index, and biofilament density, indicating that the biofilament network structure in the moss crusts was more compact and complex in contrast to the cyanobacterial crusts. Additionally, EPS content of the moss crusts was higher than that of the cyanobacterial crusts on both soils. Overall, the crosslink density, biofilament density, and EPS content of the biocrusts were significantly and positively correlated with their gamma YP and Iz. The interaction between crosslink density and biofilament density contributed 73.2 % of gamma YP, and that between crosslink density and EPS content contributed 84.0 % of Iz. Our findings highlight the biocrusts-induced changes of abandoned farmland soil rheological properties in drylands, and the importance of biocrust biofilament network and EPS in maintaining abandoned farmland soil microstructural stability to resist soil water/wind erosion and degradation, providing a new perspective for sustainable management of abandoned farmlands.

Thawing permafrost alters climate not only through carbon emissions but also via energy-water feedback and atmospheric teleconnections. This review focuses on the Tibetan Plateau, where strong freeze-thaw cycles, intense radiation, and complex snow-vegetation interactions constitute non-carbon climate responses. We synthesize recent evidence that links freeze-thaw cycles, ground heat flux dynamics, and soil moisture hysteresis to latent heat feedback, monsoon modulation, and planetary wave anomalies. Across these pathways, both observational and simulation studies reveal consistent signals of feedback amplification and nonlinear threshold behavior. However, most Earth system models underrepresent these processes due to simplifications in freezethaw processes, snow-soil-vegetation coupling, and cross-seasonal memory effects. We conclude by identifying priority processes to better simulate multi-scale cryosphere-climate feedback, especially under continued climate warming in high-altitude regions.

Frozen soil, covering most of the Tibetan Plateau (TP), critically influences land surface and climate simulations. Although some studies have made advancements in simulations, further investigation into the distinct mechanisms underlying relevant parameterization schemes remains essential. This study compares two frozen soil permeability schemes in Noah-MP (NY06: high-permeability; Koren99: low-permeability) to elucidate their distinct hydrological mechanisms. Although significant disparities exist in the simulation of soil water and ice content between the two schemes in permafrost regions, the simulated soil water content in the shallow layer exhibits similarity. Their underlying physical processes behind this similarity differ fundamentally: Koren99 relies on cross-seasonal ice melt recharge, whereas NY06 depends more on current-season precipitation and snowmelt. With greater soil depth, soil water differences progressively propagate downward, amplifying variations in hydraulic conductivity, and soil memory effects become increasingly dominant. Meanwhile, the Koren99 scheme more effectively impedes bottom-up melting water transport than top-down effect. However, the aforementioned disparities are not apparent in seasonally frozen soil. Notable disparities also exist in simulated evapotranspiration and surface runoff over permafrost regions, particularly during the summer months. This research investigates the differences in water transport within frozen soil over the TP, elucidates the distinct hydrological mechanisms underlying different frozen soil permeability schemes, and highlights that similar soil hydrothermal simulations are associated with different physical processes, leading to varying degrees of effectiveness in soil memory. Furthermore, this research elucidates the dual role of soil ice (permeability restriction and water storage) in hydrological processes, providing a theoretical basis for improving frozen soil parameterization.

Freeze-thaw cycles (FTC) influence soil erodibility (K-r) by altering soil properties. In seasonally frozen regions, the coupling mechanisms between FTC and water erosion obscure the roles of FTC in determining soil erosion resistance. This study combined FTC simulation with water erosion tests to investigate the erosion response mechanisms and key drivers for loess with varying textures. The FTC significantly changed the mechanical and physicochemical characteristics of five loess types (P < 0.05), especially reducing shear strength, cohesion, and internal friction angle, with sandy loam exhibiting more severe deterioration than silt loam. Physicochemical indices showed weaker sensitivity to FTC versus mechanical properties, with coefficients of variation below 5 %. Wuzhong sandy loess retained the highest K-r post-FTC, exceeding that of the others by 1.04 similar to 2.25 times, highlighting the dominant role of texture (21.37 % contribution). Under different initial soil moisture contents (SMC), K-r increased initially and then stabilized with successive FTC, with a threshold effect of FTC on K-r at approximately 10 FTC. Under FTC, the K-r variation rate showed a concave trend with SMC, turning point at 12 % SMC, indicating that SMC regulates freeze-thaw damage. Critical shear stress exhibited an inverse response to FTC compared to K-r, displaying lower sensitivity. The established K-r prediction model achieved high accuracy (R-2 = 0.87, NSE = 0.86), though further validation is required beyond the design conditions. Future research should integrate laboratory and field experiments to expand model applicability. This study lays a theoretical foundation for research on soil erosion dynamics in freeze-thaw-affected areas.

A set of direct shear tests on the soil-geotextile interface (SGI) were conducted using a temperature-controlled constant normal stiffness (CNS) direct shear apparatus. This was done in order to evaluate the effects of normal stiffness, initial normal stress, soil water content, and temperature on SGI shear behavior and microdeformation patterns. The observations indicate that all shear stress-shear displacement curves demonstrate strain-hardening characteristics, with SGI cohesion and friction angle increasing at higher normal stiffness and lower temperatures. At freezing conditions, water content significantly affects the interface friction angle, while this effect is minimal at positive temperatures. Normal stress increases with higher water content, lower temperatures, and higher normal stiffness. Shear stress initially rises with normal stress before decreases, with a more pronounced rise under sub-zero conditions. Normal stress shrinkage shows a positive correlation with normal stiffness. Micro-deformation analysis of soil particles at the interface indicates significant strain localization within the shear band, which is less pronounced under sub-zero temperatures compared to positive temperatures. These patterns of normal displacement vary across analysis points within the shear band, with the macroscopic normal displacement reflecting a cumulative effect of these microscopic variations.