Canopy reflectance (CR) models describe the transfer and interaction of radiation from the soil background to the canopy layer and play a vital role in the retrieval of biophysical variables. However, few efforts have focused on estimating soil background scattering operators, resulting in uncertainties in CR modelling, especially over sloping terrain. This study developed a canopy reflectance model for simulating CR over sloping terrain, which combines the general spectral vector (GSV) model, the PROSPECT model, and 4SAIL model coupled with topography (GSV-PROSAILT). The canopy reflectance simulated by GSV-PROSAILT was validated against two datasets: discrete anisotropic radiative transfer (DART) simulations and remote sensing observations. A comparison with DART simulations under various conditions revealed that the GSV-PROSAILT model captures terrain-induced CR distortion with high accuracy (red band: coefficient of determination $\lpar {\rm R 2} \rpar = 0.731$(R2)=0.731, root-mean-square error (RMSE) = 0.007; near infrared (NIR) band: $\rm R2 = 0.8319$R2=0.8319, RMSE = 0.0098). The results of remote sensing observation verification revealed that the GSV-PROSAILT model can be successfully used in CR modelling. These validations confirmed the performance of GSV-PROSAILT in soil and canopy reflectance modelling over sloping terrain, indicating that it can provide a potential tool for biophysical variable retrieval over mountainous areas.

An analytical methodology was developed for the first time in this work enabling the simultaneous enantiomeric separation of the fungicide fenpropidin and its acid metabolite by Capillary Electrophoresis. A dual cyclodextrin system consisting of 4 % (w/v) captisol with 10 mM methyl-beta-cyclodextrin was employed in a 100 mM sodium acetate buffer at pH 4.0. Optimal experimental conditions (temperature 25 degrees C, separation voltage -25 kV, and hydrodynamic injection of 50 mbar x 10 s) allowed the simultaneous separation of the four enantiomers in <10.7 min with resolutions of 3.1 (fenpropidin) and 3.2 (its acid metabolite). Analytical characteristics of the method were evaluated and found adequate for the quantification of both chiral compounds with a linearity range from 0.75 to 70 mg L-1, good accuracy (trueness included 100 % recovery, precision with RSD<6 %), and limits of detection and quantification of 0.25 and 0.75 mg L-1, respectively, for the four enantiomers. No significant differences were found between the concentrations determined and labelled of fenpropidin in a commercial agrochemical formulation. The stability over time (0-42 days) of fenpropidin enantiomers using the commercial agrochemical formulation was evaluated in two sugar beet soils, revealing to be stable at any time in one sample, while in the other a decrease of 45 % was observed after 42 days. Individual and combined toxicity of fenpropidin and its metabolite was determined for the first time for marine organism Vibrio fischeri, demonstrating higher damage caused by parent compound. Synergistics and antagonists' interactions were observed at low and high effects levels of contaminants.

Abandoned farmlands are increasing due to socio-economic changes and land marginalization, and they require sustainable land management practices. Biocrusts are a common cover on the topsoil of abandoned farmlands and play an important role in improving soil stability and erosion resistance. The critical functions of biocrusts are known to mostly rely on their biofilaments and extracellular polymeric substances (EPS), but how these components act at microscopic scale is still unknown, while rheological methods are able to provide new insights into biocrust microstructural stability at particle scale. Here, bare soil and two representative types of biocrusts (cyanobacterial and moss crusts) developed on sandy (Ustipsamments) and sandy loam (Haplustepts) soils in abandoned farmlands in the northern Chinese Loess Plateau were collected at a sampling depth of 2 cm. Changes in the rheological properties of the biocrusts were analyzed with respect to their biofilament network and EPS contents to provide possible explanations. The rheological results showed that compared with bare soil, storage and loss moduli were decreased by the biocrusts on sandy soil, but they were increased by the biocrusts on sandy loam soil. Other rheological parameters tau max, gamma L, gamma YP, and Iz of biocrusts on both soils were significantly higher than those of bare soil, showing higher viscoelasticity. And the moss crusts had about 10 times higher rheological property values than the cyanobacterial crusts. Analysis from SEM images showed that the moss crusts had higher biofilament network parameters than the cyanobacterial crusts, including nodes, crosslink density, branches, branching ratio and mesh index, and biofilament density, indicating that the biofilament network structure in the moss crusts was more compact and complex in contrast to the cyanobacterial crusts. Additionally, EPS content of the moss crusts was higher than that of the cyanobacterial crusts on both soils. Overall, the crosslink density, biofilament density, and EPS content of the biocrusts were significantly and positively correlated with their gamma YP and Iz. The interaction between crosslink density and biofilament density contributed 73.2 % of gamma YP, and that between crosslink density and EPS content contributed 84.0 % of Iz. Our findings highlight the biocrusts-induced changes of abandoned farmland soil rheological properties in drylands, and the importance of biocrust biofilament network and EPS in maintaining abandoned farmland soil microstructural stability to resist soil water/wind erosion and degradation, providing a new perspective for sustainable management of abandoned farmlands.

Frozen soil, covering most of the Tibetan Plateau (TP), critically influences land surface and climate simulations. Although some studies have made advancements in simulations, further investigation into the distinct mechanisms underlying relevant parameterization schemes remains essential. This study compares two frozen soil permeability schemes in Noah-MP (NY06: high-permeability; Koren99: low-permeability) to elucidate their distinct hydrological mechanisms. Although significant disparities exist in the simulation of soil water and ice content between the two schemes in permafrost regions, the simulated soil water content in the shallow layer exhibits similarity. Their underlying physical processes behind this similarity differ fundamentally: Koren99 relies on cross-seasonal ice melt recharge, whereas NY06 depends more on current-season precipitation and snowmelt. With greater soil depth, soil water differences progressively propagate downward, amplifying variations in hydraulic conductivity, and soil memory effects become increasingly dominant. Meanwhile, the Koren99 scheme more effectively impedes bottom-up melting water transport than top-down effect. However, the aforementioned disparities are not apparent in seasonally frozen soil. Notable disparities also exist in simulated evapotranspiration and surface runoff over permafrost regions, particularly during the summer months. This research investigates the differences in water transport within frozen soil over the TP, elucidates the distinct hydrological mechanisms underlying different frozen soil permeability schemes, and highlights that similar soil hydrothermal simulations are associated with different physical processes, leading to varying degrees of effectiveness in soil memory. Furthermore, this research elucidates the dual role of soil ice (permeability restriction and water storage) in hydrological processes, providing a theoretical basis for improving frozen soil parameterization.

Freeze-thaw cycles (FTC) influence soil erodibility (K-r) by altering soil properties. In seasonally frozen regions, the coupling mechanisms between FTC and water erosion obscure the roles of FTC in determining soil erosion resistance. This study combined FTC simulation with water erosion tests to investigate the erosion response mechanisms and key drivers for loess with varying textures. The FTC significantly changed the mechanical and physicochemical characteristics of five loess types (P < 0.05), especially reducing shear strength, cohesion, and internal friction angle, with sandy loam exhibiting more severe deterioration than silt loam. Physicochemical indices showed weaker sensitivity to FTC versus mechanical properties, with coefficients of variation below 5 %. Wuzhong sandy loess retained the highest K-r post-FTC, exceeding that of the others by 1.04 similar to 2.25 times, highlighting the dominant role of texture (21.37 % contribution). Under different initial soil moisture contents (SMC), K-r increased initially and then stabilized with successive FTC, with a threshold effect of FTC on K-r at approximately 10 FTC. Under FTC, the K-r variation rate showed a concave trend with SMC, turning point at 12 % SMC, indicating that SMC regulates freeze-thaw damage. Critical shear stress exhibited an inverse response to FTC compared to K-r, displaying lower sensitivity. The established K-r prediction model achieved high accuracy (R-2 = 0.87, NSE = 0.86), though further validation is required beyond the design conditions. Future research should integrate laboratory and field experiments to expand model applicability. This study lays a theoretical foundation for research on soil erosion dynamics in freeze-thaw-affected areas.

A set of direct shear tests on the soil-geotextile interface (SGI) were conducted using a temperature-controlled constant normal stiffness (CNS) direct shear apparatus. This was done in order to evaluate the effects of normal stiffness, initial normal stress, soil water content, and temperature on SGI shear behavior and microdeformation patterns. The observations indicate that all shear stress-shear displacement curves demonstrate strain-hardening characteristics, with SGI cohesion and friction angle increasing at higher normal stiffness and lower temperatures. At freezing conditions, water content significantly affects the interface friction angle, while this effect is minimal at positive temperatures. Normal stress increases with higher water content, lower temperatures, and higher normal stiffness. Shear stress initially rises with normal stress before decreases, with a more pronounced rise under sub-zero conditions. Normal stress shrinkage shows a positive correlation with normal stiffness. Micro-deformation analysis of soil particles at the interface indicates significant strain localization within the shear band, which is less pronounced under sub-zero temperatures compared to positive temperatures. These patterns of normal displacement vary across analysis points within the shear band, with the macroscopic normal displacement reflecting a cumulative effect of these microscopic variations.

Liquefaction resistance and post-liquefaction shear deformation are key aspects of the liquefaction behavior for granular soil. In this study, 3D discrete element method (DEM) is used to conduct undrained cyclic triaxial numerical tests on specimens with diverse initial fabrics and loading history to associate liquefaction resistance and post-liquefaction shear deformation with the fabric of granular material. The influence of several fabric features on liquefaction resistance is first analyzed, including the void ratio, particle orientation fabric anisotropy, contact normal fabric anisotropy, coordination number, and redundancy index. The results indicate that although the void ratio and anisotropy strongly influence liquefaction resistance, the initial coordination number or redundancy index can uniquely determine liquefaction resistance. Regarding post-liquefaction shear deformation, the above quantities do not dictate the shear strain induced after initial liquefaction. Instead, the mean neighboring particle distance (MNPD), a fabric measure previously introduced in 2D and extended to 3D in this study, is the governing factor for post-liquefaction shear. Most importantly, a unique relationship between the initial MNPD and ultimate saturated post-liquefaction shear strain is identified, providing a measurable state parameter for predicting the post-liquefaction shear of sand.

The influence of seismic history on the liquefaction resistance of saturated sand is a complex process that remains incompletely understood. Large earthquakes often consist of foreshocks, mainshocks, and aftershocks with varying magnitudes and irregular time intervals. In this context, sandy soils undergo two interdependent processes: (i) partial excess pore water pressure (EPWP) generation during foreshocks or moderate mainshocks, where seismic loadings elevate EPWP without causing full liquefaction and (ii) incomplete EPWP dissipation between seismic events due to restricted drainage. These processes leave behind persistent residual EPWP, reducing the liquefaction resistance during subsequent shaking. A series of cyclic triaxial tests simulating these mechanisms revealed that liquefaction resistance increases when the EPWP ratio r(u) < 0.6-0.8 (peaking at r(u) similar to 0.4) but decreases sharply at higher r(u). Crucially, EPWP generation during seismic loading plays a dominant role in resistance evolution compared to reconsolidation effects. Threshold lines (TLs) mapping r(u), the reconsolidation ratio (RR), and peak resistance interval (the range of r(u) where the peak liquefaction resistance is located) indicates that resistance decreases above TLs and increases below them, with higher cyclic stress ratios (CSR) weakening these effects. These findings provide a unified framework for assessing liquefaction risks under realistic multi-stage seismic scenarios.

This study explores the effectiveness of soft viscoelastic biopolymer inclusions in mitigating cyclic liquefaction in loosely packed sands. This examination employs cyclic direct simple shear testing (CDSS) on loose sand treated with gelatin while varying the gelatin concentration and the cyclic stress ratio (CSR). The test results reveal that the inclusion of soft, viscoelastic gelatin significantly reduces shear strain and excess pore pressure during cyclic shear. Liquefaction potential, defined as the number of cycles to liquefaction (NL) at an excess pore pressure ratio (ru = Delta u/sigma ' vo) of 0.7, is substantially improved in gelatin-treated sands compared to gelatin-free sands. This improvement in liquefaction resistance is more pronounced as the inclusion stiffness increases. Furthermore, the viscoelastic pore-filling inclusion helps maintain skeletal stiffness during cyclic shearing, resulting in a higher shear modulus in gelatin-treated sand in both small and large-strain regimes. At a grain scale, pore-filling viscoelastic biopolymers provide structural support to the skeletal frame of a loosely packed sand. This pore filler mitigates volume contraction and helps maintain the effective stress of the soil structure, thereby reducing liquefaction potential under cyclic shearing. These findings underscore the potential of viscoelastic biopolymers as bio-grout agents to reduce liquefaction risk in loose sands.

Rice bakanae disease is a soil-borne disease mainly caused by Fusarium fujikuroi, which seriously damages the yield and quality of rice. Phenamacril targets Myosin-5, thereby inhibiting its ATPase activity to exert an antifungal effect, demonstrating significant bioactivity against Fusarium species. However, the resistance of Fusarium fujikuroi field populations to phenamacril in Jiangsu Province in recent years remains unclear. In this study, a total of 223 Fusarium fujikuroi isolates were collected in Jiangsu Province from 2022 to 2023, with the resistance frequency increase from 25.88 % to 49.28 %. Additionally, a novel mutation type (S420I) in FfMyosin-5 was identified and confirmed by genetic transformation. The compound fitness index (CFI) revealed that the fitness of FfMyosin5(S420I) point mutants (1 x 10(5) < CFI <= 2 x 10(5)) was significantly lower than sensitive strain (CFI = 10.26 x 10(5)) in terms of mycelial growth rate, conidia production and conidia germination. In summary, the S420I mutation in FfMyosin-5 induces resistance to phenamacril while also decreased the fitness of Fusarium fujikuroi.