In the effort to mitigate environmental pollution there is a growing global demand for sustainable materials in place of existing synthetic one. In this research work, stacked hybrid laminate composite were produced by combining alkali treated kenaf and bamboo natural fiber mats as reinforcement with a biopolymer polylactic acid as matrix through compression moulding technique. The current work intends to study the outcome of surface modification of natural fibers which modifies their performance characteristics. Here the overall characteristics: mechanical, tribological, thermal and physical properties were investigated for the fabricated sample and the assessments were made between the alkali treated and untreated fiber composites. The alkali treated samples exhibited an enhanced tensile strength of 44.83 %, flexural strength of 108.13 %, compressive strength of 86.21 % and peak degradation temperature compared to the untreated samples. In addition, the tribological characteristics of the treated hybrid composites were studied. The inherent hydrophilic characteristics of natural fiber which leads to water absorption is resisted by the chemical treatment and it is also confirmed by the Fourier Transform Infrared (FTIR) analysis.Morphological analysis of the fractured and worn composites was also conducted to examine the microstructural changes and interface bonding within the developed composites. The biodegradability of the developed composites under soil burial test showed that the untreated composites exhibited higher weight loss percentage compared to the treated samples. The experimental results reveal that the alkali chemical treatment significantly enhances the suitability and compatibility of kenaf and bamboo natural fibers in polymer composites for sustainable construction products like roofing sheets and door panels in rural terrain regions.
The soil moisture active passive (SMAP) satellite mission distributes a product of CO2 flux estimates (SPL4CMDL) derived from a terrestrial carbon flux model, in which SMAP brightness temperatures are assimilated to update soil moisture (SM) and constrain the carbon cyclemodeling. While the SPL4CMDL product has demonstrated promising performance across the continental USA and Australia, a detailed assessment over the arctic and subarctic zones (ASZ) is still missing. In this study, SPL4CMDL net ecosystem exchange (NEE), gross primary production (GPP), and ecosystem respiration (R-E) are evaluated against measurements from 37 eddy covariance towers deployed over the ASZ, spanning from 2015 to 2022. The assessment indicates that the NEE unbiased root-mean-square error falls within the targeted accuracy of 1.6 gC.m(-2).d(-1), as defined for the SPL4CMDL product. However, modeled GPP and R-E are overestimated at the beginning of the growing season over evergreen needleleaf forests and shrublands, while being underestimated over grasslands. Discrepancies are also found in the annual net CO2 budgets. SM appears to have a minimal influence on the GPP and R-E modeling, suggesting that ASZ vegetation is rarely subjected to hydric stress, which contradicts some recent studies. These results highlight the need for further carbon cycle process understanding and model refinements to improve the SPL4CMDL CO2 flux estimatesover the ASZ.
Surface layers of agricultural machinery working bodies are subjected to intensive abrasive wear during operation, which leads to rapid wear of equipment and reduction of its service life. To increase the wear resistance of the working surfaces of tools, the method of induction cladding using 'Sormait-1' materials is widely used. However, after coating, additional heat treatment is required, which improves physical and mechanical properties of the material and increases its durability. When using electrofriction technology (EFT) hardening, the surface of the parts is subjected to melting under the influence of electric arcs, which affects the surface characteristics of the coatings. In this work, two types of surface treatment of L53 steel were investigated: induction cladding using 'Sormait-1' material, as well as a combination of induction cladding and subsequent electrofriction treatment. The coatings were characterized and compared with the substrate in terms of the following parameters: microstructure, phase composition, hardness distribution, and friction-wear characteristics. After induction cladding of the Sormait-1 material, a dendritic structure was formed; however, subsequent electrofriction treatment resulted in a reduction of this dendritic structure, which contributed to an increase in the hardness of the material. The average hardness of the coatings after electrofriction treatment was 786 HV0.1, which is more than three times the hardness of the substrate. Furthermore, the influence of structural characteristics and hardness on abrasive wear resistance was examined in accordance with ASTM G65 international standards. Field tests were conducted on plough shares before and after electrofriction hardening to evaluate their performance. Each ploughshare was scanned with a structured 3D scanner before and after use in the field. From the scan data, the cutting-edge profile was calculated and three key parameters were determined: linear wear, volumetric wear, and mass reduction. According to the results of field tests, it was found that the service life of the blades hardened by electrofriction technology was 12%-14% higher compared to serial blades processed by induction cladding with the use of 'Sormait-1' material. Operational tests of hardened plough shares confirmed the results of laboratory tests and proved the advantages of electrofriction technology for increasing the wear resistance of soil tillage machine working bodies.
Concrete curing is a critical factor influencing its mechanical properties and durability. Traditional curing methods, such as water curing and plastic film curing, have significant limitations, including high water consumption and environmental pollution. This study introduces Microbial Induced Carbonate Precipitation (MICP) as an innovative, environmentally friendly curing method for ready-mixed concrete, addressing the urgent need for sustainable construction practices. The feasibility of MICP surface curing is investigated through comprehensive mechanical and durability tests, coupled with microscopic analyses to understand the underlying mechanisms. The results demonstrate that MICP curing substantially enhances concrete performance. Compared to traditional water curing, the samples cured using MICP have increased compressive strength and splitting tensile strength by up to 31.69% and 24.66%, respectively. Additionally, MICP surface curing significantly reduced capillary water absorption, electric flux, and chloride ion migration coefficient by 12.83%, 15.50%, and 17.36%, respectively. It is found that the optimal concentration of Ca2+ in the MICP solution initially improves concrete performance, which then diminishes at higher concentrations due to bacterial activity inhibition. Spraying the MICP solution at appropriate intervals and increasing the number of treatments further improved concrete properties by ensuring a more extensive and dense deposition of CaCO3. Microscopic analyses, including XRD, TG, and SEM-EDS, revealed that MICP surface curing leads to the formation of vaterite and calcite, which densely cover and fill microscopic cracks and pores, ensuring adequate hydration and simultaneously enhancing the concrete's mechanical and durability properties. This study concludes that MICP surface curing provides superior performance than traditional methods and offers a more sustainable and environmentally friendly curing method.