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In saline soil areas, the concrete piers of concrete bridges experience long-term corrosion, mainly caused by chloride salts due to alternating temperature changes. Waterborne concrete coatings are prone to failure in this aggressive salt environment. Implementing coating protection measures can improve the durability of concrete and enhance the service life of bridges. However, the effectiveness and longevity of coatings need further research. In this paper, three types of waterborne concrete anti-corrosion coatings were applied to analyze the macro and micro surface morphology under wet-dry cycles and long-term immersion conditions. Various indicators such as glossiness, color difference, and adhesion of the coatings were tested during different cyclic periods. The chloride ion distribution characteristics of the buried concrete coatings in saline soil, the macro morphology analysis of chloride ion distribution regions, and the micro morphology changes of the coatings under different corrosion times were also investigated. The results showed that waterborne epoxy coatings (ES), waterborne fluorocarbon coatings (FS), and waterborne acrylic coatings (AS) all gradually failed under long-term salt exposure, with increasing coating porosity, loss of internal fillers, and delamination. The chloride ion content inside the concrete decreased with increasing depth at the same corrosion time, while the chloride ion content at the same depth increased with time. The chloride ion distribution boundary in the cross- of concrete with coating protection was not significant, while the chloride ion distribution boundary in the cross- of untreated concrete gradually contracted towards the concrete core with increasing corrosion time. During the corrosion process in saline soil, the coatings underwent three stages: adherence of small saline soil particles, continuous increase in adhered material area, and multiple layers of uneven coverage by saline soil. The failure process of the coatings still required erosive ions to infiltrate the surface through micropores. The predicted lifespans of FS, ES, and AS coatings, obtained through weighted methods, were 2.45 years, 2.48 years, and 2.74 years, respectively, which were close to the actual lifespans observed in salt environments. The developed formulas effectively reflect the corrosion patterns of different resin-based coatings under salt exposure, providing a basis for accurately assessing the corrosion behavior and protective effectiveness of concrete under actual environmental factors.

期刊论文 2024-10-01 DOI: 10.3390/coatings14101249

Infrastructures built on sulfate saline soil foundations in seasonal frozen regions are highly susceptible to saltfrost heave damage and salt corrosion. To address this issue, a method has been proposed utilizing a ternary blend of industrial solid waste materials - fly ash (FA), silica fume (SF), and brick powder (BP) - in conjunction with Portland cement (PC) for the solidification of sulfate saline soil. The feasibility of this solidification technique has been validated through a series of tests, including unconfined compressive strength tests, freeze-thaw cycle tests, salt leaching tests, and microstructural analysis. The results showed that: The unconfined compressive strength of the solidified saline soil at 56 days increased by up to 61.27 times compared to untreated saline soil. During the freeze-thaw cycles, the volume of salt-frost heave in the solidified saline soil was only 10.75% of that in untreated soil, with a reduction in salt-frost heave force by up to 90.94%. Furthermore, during the salt leaching process, the rate of salt migration in the solidified saline soil could be slowed by up to 4.15 times, while the total amount of salt leached was only 31.34% of that in untreated saline soil. Additionally, through the combined use of X-ray diffraction (XRD), Scanning Electron Microscopy (SEM), and Energy Dispersive X-ray Spectroscopy (EDS), it was discovered that the interactive synergistic effect of the solidifying agents in a SO42- rich environment facilitated the dissolution of Si-O and Al-O micro-lattices on the surface of the solidifying agent particles. This led to the extensive formation of C-(A)-S-H gels and AFt products, resulting in the transformation of the soil structure from dispersed to flocculated. The comprehensive test results indicate that the mechanical properties, frost resistance, and salt corrosion resistance of the solidified saline soil have significantly improved, with an optimal solidifying agent mixture ratio of 3% PC, 5% FA, 5% SF, and 6% BP. These findings can provide a reference for the solidification treatment of sulfate saline soil foundations in seasonal frozen regions.

期刊论文 2024-05-10 DOI: 10.1016/j.conbuildmat.2024.136263 ISSN: 0950-0618
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