The infiltration and degradation of domestic contaminants have a substantial influence on the mechanical properties of soil. Sucrose is one of the oligosaccharide contaminants with high content and is prone to degradation in domestic-source contaminants. In this study, a series of tests were conducted to investigate the changes in the mechanical properties of clayey soil during the sucrose degradation process. First, in different concentrations of sucrose-contaminated soil, the organic matter content during the sucrose degradation process was measured to analyze its degradation characteristics. During the degradation process, the unconfined compressive strength and compression coefficient of the soil were measured to analyze the changes in its mechanical properties. Finally, the changes in the permeability coefficient and microstructure of the soil were analyzed in depth. The findings indicated that the degradation of sucrose and the associated alterations in the mechanical properties of contaminated soil were concentration-dependent. The effect mechanism involved the formation of organic-clay flocs during the early stages of degradation and the alkaline oxides' dissolution in the later stages. These findings contribute to a deeper understanding of the impact of domestic-source pollution on soil and provide references for the reinforcement of contaminated soil.
Ambient seismic noise and microseismicity analyses are increasingly applied for the monitoring of landslides and natural hazards. These methodologies can offer a valuable monitoring tool also for glacial and periglacial bodies, to understand the internal processes driven by external modifications in air temperature and rainfall/snowfall regimes and to forecast possible melting-related hazards in the light of climate change adaptation. We applied the methods to an almost continuous year of data recorded by a network of four passive seismic stations deployed in the frontal portion of the Gran Sometta rock glacier (Aosta Valley, NW Italian Alps). The spectral analysis of ambient seismic noise revealed frequency peaks related to stratigraphic resonances inside the rock glacier. Although the resonance frequency related to the bedrock interface was constant over time, a second higher resonance frequency was identified as the effect of variations in the active layer thickness driven by external air temperature modifications at the daily and seasonal scales. Ambient seismic noise cross-correlation highlighted coherent shear wave velocity modifications inside the periglacial body. The microseismicity dataset extracted from the continuous ambient noise recordings was analyzed and clustered to further investigate the ongoing internal processes and gain insight into their source mechanism and location. The first cluster of events was found to be likely related to the basal movements of the rock glacier and to falls and slides of the debris material. The second cluster was possibly related to shallow ice and rock fracturing processes. The validation of the seismic results through simple models of the rock glacier physical and mechanical layering, the internal thermal regime and the surface displacements allowed for a comprehensive understanding of the rock glacier's reaction to the external conditions.
This study formulated biodegradable, edible films with sodium alginate and varying concentrations and a combination of seed oils (watermelon seed oil, sesame seed oil) and rosehip extract. In the present study, rosehip, sesame, and watermelon seed oils, which incorporated many bioactive compounds and are known to have antioxidant properties, were incorporated into edible films to improve the film properties due to the controlled release of the active substance and thus increase the storage time. The potential to form alginate-based edible films by incorporating this extract and seed oils into alginate-based films has not been thoroughly investigated. Fourier transform infrared (FT-IR) spectroscopy, scanning electron microscopy (SEM), and mechanical, physical, thermal, and antioxidant properties characterized the edible film samples. The biodegradability by soil was also performed. Blending rosehip extract and its combination with seed oils significantly improved the films' antioxidant properties while reducing moisture content. In the study, the highest total phenolic content was recorded in the rosehip + sesame oil film (R2) sample (0.418 +/- 0.015 mg GAE/g) and the lowest total phenolic content was recorded in the control sample (0.208 +/- 0.014 mg GAE/g). Additionally, the highest % moisture value was recorded in the control sample (68.060 +/- 0.530%), and the lowest % moisture value was recorded in the rosehip + sesame oil film (R2) sample (61.223 +/- 0.881%). Watermelon seed oil blended film samples showed more homogeneity and had smooth surfaces compared to control samples. Alginate-based films incorporated with seed oils and rosehip extract may have caused color differences and whiteness index due to phenolic and bioactive compounds in their content. Soil degradation properties showed that the films were biodegradable. The elongation at break value of alginate-based films combined with rosehip extract and seed oils showed a significant increase compared to the control films. According to the results, alginate-based films combined with rosehip extract (films compounded with rosehip extract only and films compounded with rosehip and selected seed oils) improved film properties compared to control films. In addition, the incorporation of rosehip extract into the films improved the film properties compared to the films obtained using only seed oil. Based on the findings of this study, the use of rosehip extract, sesame, and watermelon seed oil in the development of composite biodegradable, edible films of sodium alginate could be used as a suitable alternative for edible food packaging.
Ensuring the stability of the surrounding rock mass is of great importance during the construction of a large underground powerhouse. The presence of unfavorable structural planes within the rock mass, such as faults, can lead to substantial deformation and subsequent collapse. A series of in situ experiments and discrete element numerical simulations have been conducted to gain insight into the progressive failure behavior and deformation response of rocks in relation to controlled collapse scenarios involving gently inclined faults. First, the unloading damage evolution process of the surrounding rock mass is characterized by microscopic analysis using microseismic (MS) data. Second, the moment tensor inversion method is used to elucidate the temporal distribution of MS event fracture types in the surrounding rock mass. During the development stage of the collapse, numerous tensile fracture events occur, while a few shear fractures corresponding to structural plane dislocation precede their occurrence. The use of the digital panoramic borehole camera, acoustic wave test, and numerical simulation revealed that gently inclined faults and deep cracks at a certain depth from the cavern periphery are the primary factors contributing to rock collapse. These results provide a valuable case study that can help anticipate and mitigate fault-slip collapse incidents while providing practical insights for underground cave excavation. (c) 2025 Institute of Rock and Soil Mechanics, Chinese Academy of Sciences. Published by Elsevier B.V. This is an open access article under the CC BY license (http://creativecommons.org/licenses/by/4.0/).
This study focuses on the development of polyvinyl alcohol-chitosan-tragacanth gum composite films enriched with rosehip extract and seed oil for the packaging of active foods. The films were tested for their antioxidant activity, transparency, biodegradability, water vapor permeability and effectiveness in preserving sweet cherries under seasonal high temperature conditions. The addition of tragacanth, rosehip extract and rosehip seed oil significantly influenced the mechanical properties by increasing elongation at break and tensile strength. Films enriched with rosehip seed oil effectively reduced weight loss and preserved the sensory properties of the cherries, while films based on rosehip extract exhibited superior antioxidant properties with increased free radical scavenging activity. Biodegradability tests showed that all films degraded under soil conditions, with the rate of degradation depending on the concentration of tragacanth gum. The water vapor permeability results showed that the addition of rosehip extract and seed oil significantly reduced the water vapor permeability and improved the barrier properties of the films. Preservation tests showed that these films minimized titratable acidity, oxidative stress and moisture loss, effectively extending the shelf life of sweet cherries under highly stressful conditions. These results highlight the potential of rosehip-enriched biopolymer films as a sustainable and environmentally friendly packaging alternative to extend the shelf life of perishable fruits.
The present work investigated the macrostructural and microstructural changes in the behavior of two different soil samples collected from Rayaka (Su-1Clay) and Dodka (Su-2Clay) in Vadodara, Gujarat, India, under multi-staged oedometer tests. The microstructural analysis was performed to understand the pore morphology and particle rearrangement for different stress cycles and durations. For interlinking the macroscopic and microscopic data, porosity and void ratio were compared for both levels, and results showed an average deviation of 6%. From the mineralogical data, illite group minerals were predominant in both the samples and similar macroscopic behavior was observed during the multi-staged tests. The pore count was found to be higher during the initial stages of consolidation, as there was no stress involved. The microscopic results for Su-2Clay indicated that the loading patterns, load duration and plane of observations (i.e., parallel or perpendicular to loading) do not influence the circularity of pores and shape ratio. It was observed that the particle rearrangement was influenced by their loading value and duration, plane of observations and loading patterns. As a result, the behavior of most of the particles changed from anisotropic to isotropic as the stress value and time increased.
The fabrication of biodegradable and recyclable bio-based plastic by complexing carboxymethyl cellulose (CMC) and cationic polymeric ionic liquid (PILCl) assisted with KNO3 is offered to utilize plastics sustainably and mitigate serious threats to the environment. The CMC/PIL plastic film, formed via electrostatic interactions, exhibits exceptional mechanical properties that surpass those of most conventional plastics. It demonstrates a tensile strength of approximately 200 MPa and a Young's modulus of around 5.5GPa. Even after recycling and regeneration, they essentially retain the original mechanical characteristics with a tensile strength of about 190 MPa. These CMC/PIL plastic films can be processed into three-dimensional (3D) shapes assisted with water and their fundamental qualities maintain after numerous shaping. Besides, they possess excellent biodegradability and can finish biodegrading in a few hours with cellulase and within a few days when exposed to soil. This innovation provides a fresh and practical way to produce degradable plastics.
The widespread reliance on single-use plastics (SUPs) has fostered a global throwaway culture, especially in the food packaging industry, where convenience and low cost have driven their adoption, posing serious environmental threats, particularly to marine ecosystems and biodiversity. Edible and ecofriendly packaging made from millet, specifically sorghum (Sorghum bicolor (L.) Moench), is a promising solution to mitigate SUP consumption and promote sustainability. This study explores the development of edible sorghum bowls, enhanced through roasting and incorporating 3 g of hibiscus and rose flower powders. The standardized sorghum bowl was analyzed for nutritional value; optical, technological, functional, and mechanical properties; and shelf life, and the results were discussed. The bowls, 18.5 g of average weight, dimensions of 10.2 cm, and a thickness of 3 mm, were baked in a unique bowl-shaped mold at 80 degrees C for 7 min. Enhancing the bowls with flower powder improved their optical properties and nutrient content. The addition of flower powder also increased phytochemical levels, according to qualitative analysis, while roasting sorghum reduced tannin and phytic acid content. The IC50 values revealed that hibiscus (47.74 mg/mL) and rose (39.87 mg/mL) enrichment boosted antioxidant activity. Sensory evaluations favored roasted bowls across all attributes, while Fourier transform infrared spectroscopy (FTIR) and thermogravimetric analyzer (TGA) analyses confirmed significant structural changes. The enhanced bowls exhibited greater hardness and hold hot or cold snacks for 90 min without compromising structural integrity. Additionally, these bowls demonstrated an extended shelf life, low microbial count (1 x 101CFU/g), reduced toxicity (3%-10% mortality in brine shrimp assays), and complete biodegradation within 15 days in wet soil. These findings indicate that sorghum-based edible bowls present a nutritious, viable, less toxic alternative to SUPs, appealing to a broad demographic, especially in the food and tourism sector, and contributing to environmental conservation by reducing plastic waste and suitable for wide consumption.
Pulp and paper mill sludge is composed of cellulosic waste and clay and is rich in microorganisms that can benefit horticulture. However, its application in horticulture has received less research attention. Field and greenhouse studies were carried out to determine if sludge from a case study industry can replace the typical cellulosic additive utilized in hydroseeding, and the ideal application rate of a sludge-soil-seed mixture. The treatments were 0-100% sludge and soil by mass with a consistent mass of embedded seeds of Kentucky Bluegrass (Poa pratensis), Creeping Red Fescue (Festuca rubra), Perennial (Lolium perenne) and Annual Ryegrass (Lolium multiflorum). Seeding with a top layer of soil and 5 to 75% sludge gave the best outcome using a cellulosic additive after 3 weeks of growth. Mixtures containing 5-25% sludge resulted in the quickest seed germination rate. The cellulosic additive has the capacity to retain a higher volume of water but requires 15 times more material by volume. An increase in sludge increased water retention by 20%. Overall, the cellulosic additive in hydroseeding applications can be replaced by sludge without plant detriment. However, further testing is needed to determine long-term effects. [GRAPHICS] .
The present study investigated the evolution of the time-dependent behavior of remolded samples of Indian black cotton soil for different loading-unloading-reloading cycles in oedometer conditions. The microstructural analysis was carried out to evaluate the parameters such as particle rearrangement and pore size reduction that are responsible for creep at different time periods. It was observed that micropores existed in large numbers, and the number of pores decreased rapidly with an increase in pore size. The number of pores was found to decrease by 20-30% and 85-90% at the intermediate and final stages of the creep test, respectively. Additionally, it was noted that although small pores and mesopores were less in number, they were significant in pore area calculations. The reduction in pore areas for the intermediate and final stages was found to be in the range of 40-50% and 40-60%, respectively, as there were large proportions of micropores that compressed without influencing the overall pore area. The percentage of vertically aligned particles reduced from 21 to 15% at the end of the test. This observation is attributed to the particle rearrangement and reduction in pore sizes that occurred during the test.