This study investigates the effects of incorporating date palm wood powder (DPWP) on the thermal, physical, and mechanical properties of lightweight fired earth bricks made from clay and dune sand. DPWP was added in varying proportions (0 %, 5 %, 8 %, 10 %, 12 %, and 15 % by weight of the soil matrix) to evaluate its influence on brick performance, particularly in terms of thermal insulation. Experimental results revealed that adding DPWP significantly reduced the thermal conductivity of the bricks, achieving a maximum reduction of 56.41 %. However, the inclusion of DPWP negatively impacted the physical and mechanical properties of the samples. Among the tested bricks, those with 8 % and 10 % DPWP achieved a desirable balance, maintaining satisfactory mechanical strength within acceptable standards while achieving thermal conductivity values of 0.333 and 0.279 W/m & sdot;K, representing reductions of 37.29 % and 47.46 %, respectively. To further validate these findings, prototypes of the DPWP-enhanced fired bricks and commercial bricks were constructed and tested under real environmental conditions during both summer and winter seasons, over a continuous 12-h daily period. The DPWP-enhanced prototypes demonstrated superior thermal performance, with temperature differences reaching up to 3 degrees C compared to the commercial bricks. These findings highlight the potential of DPWP as a sustainable additive for improving the thermal insulation properties of fired earth bricks, thereby promoting eco-friendly and energy-efficient building materials for sustainable construction practices.
This paper aims to enhance the effective utilization of construction solid waste renewable brick powder (RBP) and circulating fluidized bed fly ash (CFBFA), addressing the issues of resource consumption and environmental pollution associated with these two types of solid waste. It employs CFBFA to synergistically activate RBP for the preparation of solid waste-based earthwork subgrade backfill. This research examines the impact of RBP and CFBFA content on the performance of earthwork subgrade backfill (ESB), while the microstructure of the paste test block was investigated using XRD, SEM, FTIR, and TG-dTG techniques. The synergistic mechanism of multisolid waste was examined at the micro level, and the appropriate ratio of solid waste-derived lowcarbon ESB was thoroughly assessed. The findings indicate that an increase in the CFBFA content generally enhances the mechanical strength of the paste. At the experimental ratio of RBP: CFBFA: coarse-grained soil = 8: 32: 60, the 28-day unconfined compressive strength (UCS), California Bearing Ratio (CBR) value, rebound modulus value, shear strength value, and compression modulus value of the sample attain their maximums, measuring 5.3 MPa, 41.9 %, 71.9 MPa, 10.5 KPa, and 15.76 MPa, respectively, all exceeding the standard values. The hydration products of cementitious materials based on RBP and CFBFA mostly consist of C-S-H gel, ettringite (AFt), and calcite. The robust honeycomb gel structure, created by the staggered interconnection of C-S-H gel and ettringite, is the primary contributor to mechanical strength. The modified cementitious material, composed of RBP-CFBFA, exhibits effective cementation and solidification properties for heavy metals, achieving leaching concentrations that comply with Class III water standards as outlined in the Chinese standard GB/T 14848-2017.
The wheat powdery mildew (WPM) is one of the most severe crop diseases worldwide, affecting wheat growth and causing yield losses. The WPM was a bottom-up disease that caused the loss of cell integrity, leaf wilting, and canopy structure damage with these symptoms altering the crop's functional traits (CFT) and canopy spectra. The unmanned aerial vehicle (UAV)-based hyperspectral analysis became a mainstream method for WPM detection. However, the CFT changes experienced by infected wheats, the relationship between CFT and canopy spectra, and their role in WPM detection remained unclear, which might blur the understanding for the WPM infection. Therefore, this study aimed to propose a new method that considered the role of CFT for detecting WPM and estimating disease severity. The UAV hyperspectral data used in this study were collected from the Plant Protection Institute's research demonstration base, Xinxiang city, China, covering a broad range of WPM severity (0-85 %) from 2022 to 2024. The potential of eight CFT [leaf structure parameter (N), leaf area index (LAI), chlorophyll a + b content (Cab), carotenoids (Car), Car/Cab, anthocyanins (Ant), canopy chlorophyll content (CCC) and average leaf angle (Deg)] obtained from a hybrid method combining a radiative transfer model and random forest (RF) and fifty-five narrow-band hyperspectral indices (NHI) was explored in WPM detection. Results indicated that N, Cab, Ant, Car, LAI, and CCC showed a decreasing trend with increasing disease severity, while Deg and Car/Cab exhibited the opposite pattern. There were marked differences between healthy samples and the two higher infection levels (moderate and severe infection) for Cab, Car, LAI, Deg, CCC, and Car/Cab. N and Ant only showed significant differences between the healthy samples and the highest infection level (severe infection). As Cab, Car, and Ant decreased, the spectral reflectance in the visible light region increased. The decrease in N and LAI was accompanied by a reduction in reflectance across the entire spectral range and the near-infrared area, which was exactly the opposite of Deg. The introduction of CFT greatly improved the accuracy of the WPM severity estimation model with R2 of 0.92. Features related to photosynthesis, pigment content, and canopy structure played a decisive role in estimating WPM severity. Also, results found that the feature importance showed a remarkable interchange as increasing disease levels. Using features that described canopy structure changes, such as optimized soil adjusted vegetation index, LAI, visible atmospherically resistant indices, and CCC, the mild infection stage of this disease was most easily distinguished from healthy samples. In contrast, most severe impacts of WPM were best characterized by features related to photosynthesis (e.g., photochemical reflectance index 515) and pigment content (e.g., normalized phaeophytinization index). This study help deepen the understanding of symptoms and spectral responses caused by WPM infection.
The integration of industrial and biogenic waste materials in soil stabilization provides an environmentally sustainable alternative to conventional binders. This study evaluates the influence of mussel shell powder (MSP) on both untreated, cemented, and recycled soils, where the recycled soil was initially stabilized with calcium carbide residue, cured for one year, ground into powder, and then re-treated with MSP. Unconfined compression, ultrasonic pulse velocity, and direct shear tests were conducted to assess the strength, compaction, and shear behavior of MSP-stabilized pure, recycled, and cemented soils. The results indicate that MSP addition reduced plasticity and improved soil workability. In recycled soils, 5% MSP provided optimal strength enhancement, while in cemented soils, 20% MSP was required for significant strength gains due to its role in secondary cementation. Freeze-thaw tests demonstrated that MSP-treated soils exhibited up to a 40% reduction in strength loss compared to untreated samples, improving durability in cold climates. The ultrasonic pulse velocity measurements showed strong correlations with unconfined compressive strength, confirming its potential as a nondestructive assessment method for stabilized soils. These findings highlight the potential of MSP as a sustainable stabilizer for improving soil mechanical properties, durability, and resistance to freeze-thaw cycles.
Composite materials with different contents of silicon-modified pineapple leaf fiber (PALF), calcined oyster shell powder (OSP), and poly(butylene succinate) (PBS) were successfully prepared. Moreover, the flexural performance of the composite materials containing calcined oxazoline (OSP) was obviously enhanced. The addition of silicon-modified PALF contributed to the improvement of the material's thermal stability and affected its water absorption performance. Significant degradation differences were observed in PALF composite materials modified with glycidoxypropyl trimethoxysilane (Glymo) and PBS when adding calcined OSP. Formulations containing calcined OSP and epoxy-type silicon-modified PALF showed better adhesion to the PBS substrate, thereby exhibiting good flexural performance. The flexural strength of the formulation increased by 47% compared to pure PBS. This research accentuates the differences between epoxy-type silicon-modified PALF and PBS when integrated with calcined OSP. Biodegradation experiments demonstrated a notable 38.32% degradation after 105 days of the soil burial period. Furthermore, the study investigated the potential for manufacturing products, including tableware, storage boxes, and bowls, using injection molding techniques.
This study investigated the improvement in a type of sand using a geopolymer made of recycled glass powder (RGP) as the base material and sodium hydroxide (NaOH) as the alkaline activator. Using maximum uniaxial compressive strength (UCS), the impact of alkaline activator concentration and the RGP content were investigated to determine the optimum mix design. Groundwater level increments were simulated through a laboratory procedure to study the effect of curing age and capillary action on the behavior of stabilized soil. The UCS of samples at different ages (14, 28, 45, and 60 days) and different degrees of saturation (Sr=0%, 20%, 50%, 80%, and 100%) were determined and their stress-strain diagrams were drawn. Using the stress-strain relationships, UCS, modulus of elasticity (Es), shear modulus (G), and resilient modulus (Mr) of the stabilized soil were estimated. The results showed that fully saturated stabilized samples did not disintegrate and exhibited a considerable UCS of up to 1.88 MPa at the age of 60 days. The greatest observed reduction in the UCS through saturation was between Sr=0 to 20%. To further investigate and validate the mechanical results, chemical and microstructural studies including X-ray fluorescence (XRF), scanning electron microscopy (SEM), energy dispersive X-ray analysis (EDX), X-ray diffraction analysis (XRD), and Fourier transform infrared spectroscopy (FTIR) were carried out. The results showed that during the curing period, the silicon/aluminum (Si/Al) ratio increased from 2.98 in untreated soil to 4 in stabilized samples, indicating active geopolymerization, which enhanced UCS and reduced the potential for disintegration. Additionally, the crystal size decreased from 53 to 24 nm for the 45-day stabilized samples when the degree of saturation changed from 0% to 100%. This finding suggests that if RGP-based geopolymer-stabilized soil contacts water after fully drying, geopolymerization reactions will resume that involve the dissolution of both crystalline and amorphous phases.
Herin, a biodegradable bioplastic composite packaging film was prepared by utilizing bamboo powder partially in replace of plastic. Bamboo powder lignocellulose and polybutylene adipate terephthalate (PBAT) resin granules were mixed together with certain percentage to form bamboo-plastic complex, and then through hotpressed to obtain the bamboo/PBAT bioplastic composite films. The effect of bamboo powder content on overall properties of the composite film was systematically investigated. Results showed that the addition of bamboo powder could greatly improve the mechanical properties of composite films, especially the tensile strength and elastic modulus increased by 18.90 %, 251.58 %, respectively. Besides, the bioplastic composite film exhibited superior water resistance including the high water contact angle value of 108.13 degrees, low water absorption rate (2.38 %), and water absorption thickness expansion rate (1.08 %) with 10.0 % bamboo powder content. Notably, the enhanced bonding between bamboo powder and PBAT contributed to the excellent gas barrier performance (1.48 x 10- 2 cm3 & sdot;m/(m2 & sdot;24 h & sdot;0.1 MPa)). With the increase of bamboo powder addition, the melt flow rate of the composite was increased, indicating the improved processing performance. More importantly, the bamboo/PBAT bioplastic composite film showed good packaging preservation ability for strawberry and excellent biodegradability in soil, presenting feasible and green alternatives to biodegradable plastic food packaging material.
Improving the fracture toughness of agricultural soil-engaging components can mitigate the detrimental effects of hard particles in the soil while maintaining the wear resistance of the components, thereby improving the service performance. The wear resistance of the parts can be improved by surface treatment, but the surface toughness after treatment still needs to be further improved. In this study, WC10Co4Cr@YSZ (Yttria Stabilized Zirconia) core-shell structured composite powder was synthesized by modifying commercial WC10Co4Cr powder using the sol-gel method, and WC10Co4Cr coatings were prepared using the powders before and after modification. The microstructure of the powder and coatings were characterized. The mechanical properties and wear resistance of the coatings were evaluated through microhardness, nanoindentation, and friction testing. The hardness of the YSZ-modified composite coating was comparable to that of the unmodified coating, yet it exhibited lower porosity and twice the fracture toughness. Wear test results indicated that the coating's wear loss was greatly reduced compared with the substrate. In addition, the wear rate of the YSZ-modified coating was 71.11 % lower than the unmodified coating, demonstrating its exceptional wear resistance. The findings show that incorporation of YSZ into the coating system further enhanced wear resistance. The strengthening mechanisms resulting from the YSZ inclusion include the pinning effect, which controls the size and distribution of the WC grains, the shell structure that prevents overheating, and the improved fracture toughness of the coating. This work provides a new way to extend the service time of agricultural soil-engaging components.
Microbial-induced calcite precipitation (MICP) is an eco-friendly soil stabilization technology widely applied to the solidification of aeolian sand. To further enhance the effectiveness of MICP in cementing aeolian sand, this study introduced wheat straw powder (WSP) as a reinforcing material and conducted experimental research on WSP-enhanced microbial cemented aeolian sand. By combining macroscopic physical and mechanical tests with discrete element method (DEM) simulations, this study systematically investigated the mechanisms by which WSP enhances microbial cementation and the mesoscopic failure characteristics of the material. The results indicated that adding WSP significantly increased the calcium carbonate content, resulting in uniform calcite deposition and encapsulation of sand particles. This enhancement increased the compressive strength and deformation resistance of the cemented sand columns, with a notable increase in strain at failure. DEM simulations further revealed that as the calcium carbonate content increased, macroscopic cracks within the sand columns evolved from single to multiple pathways, eventually penetrating the entire sand column along the loading direction. The internal bonding failure process could be divided into compaction, expansion, and rapid growth stages. Additionally, the uniformity of particle bonding in WSP-reinforced sand columns significantly impacted their macroscopic mechanical behavior, with uneven interparticle bonding likely inducing microcrack accumulation, leading to severe fracture patterns. These findings provide valuable insights for optimizing microbial cementation techniques for aeolian sand.
In aggressive environments, including acidic environments, low and high-plasticity clays play an important role in transmitting and spreading dangerous pollution. Stabilisation of these types of soils can improve their characteristics. In this research, different ratios of two precursors with a low calcium percentage, for example, waste statiti-ceramic sphere powder (WS-CSP) and a high calcium percentage (e.g. ground granulated blast furnace slag [GGBFS], were employed to investigate the properties of soils with different plasticity indices [PIs]). Low and high-plasticity-stabilised and stabilised with 5 wt% Portland cement specimens were prepared and exposed to an acidic solution with a pH of 2.5 in intervals of 1, 3, 6 and 9 months. The long-term durability of specimens was evaluated using the uniaxial compressive strength test (UCS) and bending strength test (BS). Additionally, the microstructures of these specimens under various time intervals were analyzed using scanning electron microscopy and Fourier-transform infrared. According to the results, in an acidic environment, the reduction in UCS, BS, toughness and secant modulus of elasticity (E50) for low-plasticity-stabilised specimens and containing 100% WS-CSP was lower than that of other specimens. The Taguchi method and ANOVA were used to investigate the effect of each control factor on the UCS and BS.