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To investigate the efficacy and strength properties of Fe2+-activated persulfate remediation for 1,2-dichlorobenzene-contaminated soil with varying persulfate concentrations, we conducted degradation, microscopic, particle size, liquid-plastic limit, unconfined compressive strength (UCS), and undrained shear tests. The results indicate that adding 15.0% Fe2+-activated persulfate achieves a 92.59% removal rate of 1,2-dichlorobenzene. Furthermore, the reaction produces sodium sulfate, calcium sulfate, and ferric hydroxide. Small amounts of sodium sulfate and calcium sulfate fill the pores between soil particles, leading to a denser soil structure. However, the expansive effect of excessive sodium sulfate crystals weakens the inter-particle cohesion, leading to soil loosening. After remediation, the clay content increases, while the silt and sand content decreases. The liquid limit, the plastic capacity and the plastic index increase, while the plastic limit decreases with the increase of the persulfate dosage. The UCS and the maximum shear stress decrease with the increase of the persulfate dosage. The UCS of the soil treated by 10.0% persulfate is 310.75 kPa, 20.34% higher than the strength of untreated soil. The maximum deviator stress at shear failure is 142.73 kPa.

期刊论文 2024-12-01 DOI: 10.16285/j.rsm.2024.0194 ISSN: 1000-7598

High-temperature thermal desorption is effective for remediating organic-contaminated sites, but its damage to soil functions and high energy consumption raise concerns. In this work, the variation of fertility indicators of two soils with thermal treatment temperature was investigated experimentally. To overcome the difficulties in measuring soil thermophysical properties under sealing and high-temperature conditions, two apparatus matching with the Hot Disk device were established and by which massive data were measured. The results show that, as temperature rises up to 500 degrees C, the combustion and decomposition of organic components and soil minerals gradually enhance, leading to a decrease in most fertility indicators, but an increase in grain size and pH. Available phosphorus and exchangeable potassium decrease with temperature rise first, but increase over 400 degrees C. Soil thermal conductivity and specific heat are positively correlated with temperature and water content. Water diffusion will intensify over 40 similar to 60 degrees C, leading to an intense increase in soil thermal conductivity. The results are expected to provide data basis and theoretical guidance for the comprehensive consideration of remediation effects, land reuse, and energy consumption in practical applications of thermal desorption remediation.

期刊论文 2024-12-01 DOI: 10.1016/j.rineng.2024.103636 ISSN: 2590-1230
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