Saturn's large and diffuse E ring is populated by microscopic water ice dust particles, which originate from the Enceladus plume. Cassini's Cosmic Dust Analyser sampled these ice grains, revealing three compositional particle types with different concentrations of salts and organics. Here, we present the analysis of CDA mass spectra from several orbital periods of Cassini, covering the region from interior to Enceladus' orbit to outside the orbit of Rhea, to map the distribution of the different particle types throughout the radial extent of the E ring. This will provide a better understanding of the potential impact of space weathering effects on to these particles, as the ice grains experience an increasing exposure age during their radially outward migration. In this context, we report the discovery of a new ice particle type (Type 5), which produces spectra indicative of very high salt concentrations, and which we suggest to evolve from less-salty Enceladean ice grains by space weathering. The radial compositional profile, now encompassing four particle types, reveals distinct radial variations in the E ring. At the orbital distance of Enceladus our results are in good agreement with earlier compositional analyses of E ring ice grains in the moon's vicinity. With increasing radial distance to Saturn however, our analysis suggests a growing degree of space weathering and considerable changes to the spatial distribution of the particle types. We also find that the proportion of Type 5 grains - peaking near Rhea's orbit - probably reflects particle charging processes in the E ring.

We follow Paper I with predictions of how gas leaking through the lunar surface could influence the regolith, as might be observed via optical transient lunar phenomena (TLPs) and related effects. We touch on several processes, but concentrate on low and high flow rate extremes, which are perhaps the most likely. We model explosive outgassing for the smallest gas overpressure at the regolith base that releases the regolith plug above it. This disturbance's timescale and affected area are consistent with observed TLPs; we also discuss other effects. For slow flow, escape through the regolith is prolonged by low diffusivity. Water, found recently in deep magma samples, is unique among candidate volatiles, capable of freezing between the regolith base and surface, especially near the lunar poles. For major outgassing sites, we consider the possible accumulation of water ice. Over geological time, ice accumulation can evolve downward through the regolith. Depending on gases additional to water, regolith diffusivity might be suppressed chemically, blocking seepage and forcing the ice zone to expand to larger areas, up to km(2) scales, again, particularly at high latitudes. We propose an empirical path forward, wherein current and forthcoming technologies provide controlled, sensitive probes of outgassing. The optical transient/outgassing connection, addressed via Earth-based remote sensing, suggests imaging and/or spectroscopy, but aspects of lunar outgassing might be more covert, as indicated above. TLPs betray some outgassing, but does outgassing necessarily produce TLPs? We also suggest more intrusive techniques from radar to in situ probes. Understanding lunar volatiles seems promising in terms of resource exploitation for human exploration of the Moon and beyond, and offers interesting scientific goals in its own right. Many of these approaches should be practiced in a pristine lunar atmosphere, before significant confusing signals likely to be produced upon humans returning to the Moon.