We calculated the cross sections of photolysis of OH, LiO, NaO, KO, HCl, LiCl, NaCl, KCl, HF, LiF, NaF, and KF molecules using quantum chemistry methods. The maximal values for photolysis cross sections of alkali metal monoxides are on the order of 10(-18) cm(2). The lifetimes of photolysis for quiet Sun at 1 astronomical unit are estimated as 2.0 x 10(5), 28, 5, 14, 2.1 x 10(5), 225, 42, 52, 2 x 10(6), 35 400, 486, and 30 400 s for OH, LiO, NaO, KO, HCl, LiCl, NaCl, KCl, HF, LiF, NaF, and KF, respectively. We performed a comparison between values of photolysis lifetimes obtained in this work and in previous studies. Based on such a comparison, our estimations of photolysis lifetimes of OH, HCl, and HF have an accuracy of about a factor of 2. We determined typical kinetic energies of main peaks of photolysis-generated metal atoms. Impact-produced LiO, NaO, KO, NaCl, and KCl molecules are destroyed in the lunar and Hermean exospheres almost completely during the first ballistic flight, while other considered molecules are more stable against destruction by photolysis.

Context. The Moon has a tenuous exosphere consisting of atoms that are ejected from the surface by energetic processes, including hypervelocity micrometeoritic impacts, photon-stimulated desorption by UV radiation, and ion sputtering. Aims. We calculate the vapor and neutral Na production rates on the Moon caused by impacts of meteoroids in the radius range of 5-100 mu m. We considered a previously published dynamical model to compute the flux of meteoroids at the heliocentric distance of the Moon. Methods. The orbital evolution of dust particles of different sizes is computed with an N-body numerical code. It includes the effects of Poynting-Robertson drag, solar wind drag, and planetary perturbations. The vapor production rate and the number of neutral atoms released in the exosphere of the Moon are computed with a well-established formulation. Results. The result shows that the neutral Na production rate computed following our model is higher than previous estimates. This difference can be due to the dynamical evolution model that we used to compute the flux and also to the mean velocity, which is 15.3 kms(-1) instead of 12.75 km s(-1) as reported in literature. Conclusions. Until now, the micrometeoritic impacts have been considered a negligible source for the release of neutral sodium atoms into the exosphere compared to other mechanisms, but according to our calculations, the contribution may be 8% of the photo-stimulated desorption at the subsolar point, becoming similar in the dawn and dusk regions and dominant on the night side.