The traditional cement-based stabilization cannot effectively stabilize the marine soft clay under submerged conditions. In order to solve this problem, the enhancement of cement-stabilized marine soft clay was investigated in this study by adding the ionic soil stabilizer (ISS) and polyacrylamide (PAM). For this purpose, varying contents of ISS and PAM (ISS-P) were added into cement-stabilized marine soft clay and subjected to curing under submerged conditions. Atterberg limits tests, direct shear tests, unconfined compression strength (UCS) tests, water-stability tests, scanning electron microscopy analysis, and X-ray diffraction analysis were carried out. The results show that using 1.8% ISS and 0.9% PAM as the optimal ratio, the cohesion, internal friction angle, UCS, and water-stability of the samples increased by 182.7%, 15.4%, 176.5%, and 368.5% compared to the cement-stabilized soft clay after 28 d. The increment in soil cohesion with increasing ISS-P content was more apparent than that in the internal friction angle. The combined action of ion exchange attraction and electrostatic adsorption altered the failure characteristics of the samples, resulting in localized micro-cracking and multiple failure paths. Increasing the content of ISS-P strengthened the skeletal structure of soil, reduced inter-particle spacing, and enhanced the water-stability. Additionally, ISS promotes the hydration of cement and compensates for the inhibitory effect of PAM on early cement hydration. ISS-P can effectively enhance the strength and stability of submerged cement-based stabilized marine soft clay.

The ionic soil stabilizer (ISS) can synergistically enhance the mechanical properties and improve the engineering characteristics of iron tailings soil in conjunction with cementitious materials such as cement. In this paper, the influence of ISS on the cement hydration process and the charge repulsion between iron tailings soil particles was studied. By means of Isothermal calorimetry, X-ray diffraction (XRD), Scanning electron microscope (SEM), and Low-field nuclear magnetic resonance microscopic analysis methods such as (LF-NMR), X-ray photoelectron spectroscopy (XPS), Non-evaporable water content and Zeta potential were used to clarify the mechanism of ISS-enhanced cement stabilization of the mechanical properties of iron tailings soil. The results show that in the cement system, ISS weakens the mechanical properties of cement mortar. When ISS content is 1.67%, the 7 d compressive strength of cement mortar decreases by 59.8% compared with the reference group. This retardation arises due to carboxyl in ISS forming complexes with Ca2+, creating a barrier on cement particle surfaces, hindering the hydration reaction of the cement. In the cement-stabilized iron tailings soil system, ISS has a positive modification effect. At 0.33% ISS, compared with the reference group, the maximum dry density of the samples increased by 6.5%, the 7 d unconfined compressive strength increased by 35.3%, and the porosity decreased from 13.58% to 11.85%. This is because ISS reduces the double electric layer structure on the surface of iron tailings soil particles, reduces the electrostatic repulsion between particles, and increases the compactness of cement-stabilized iron tailings soil. In addition, the contact area between cement particles increases, the reaction energy barrier height decreases, the formation of Ca(COOH)2 reduces, and the retarding effect on hydration weakens. Consequently, ISS exerts a beneficial effect on augmenting the mechanical performance of cement-stabilized iron tailings soil.

This paper utilizes both the ionic soil stabilizer (ISS) and sand to strengthen bentonite, as ISS effectively reduces its expansive properties and sand rapidly improves its strength to reduce cracks. Various experiments are conducted to analyze the changes in physical and mechanical properties of the bentonite strengthened by ISS-sand (ISB). The results show that not only do the sand particles enhance the strength of bentonite, but also the ISS significantly reduces its expansibility. Furthermore, the mass ratio of sand to bentonite has different effects on the unconfined compressive strength (UCS) and the freeze-tolerance of sand-reinforced bentonite (SB) and ISB. These findings suggest that a comprehensive consideration of the sand mixing rate is necessary when implementing ISS reinforcement on natural expansive soil.