Mercury ion (Hg2+) is one of the most toxic pollutants that can exist throughout the environment and be diffused into water, soil, air, and eventually the food chain. Even a very low level of Hg2+ diffused in living organisms can hurt their DNA and cause the permanent damage of the central nervous system and a variety of consequential disorders. Hence, the development of a sensitive and specific method for the detection of Hg2+ at trace ranges is extremely important as well as challenging. Fluorometric detection assays based on graphene quantum dots (GQDs) and carbon quantum dots (CQDs) offer considerable potential for the determination and monitoring of heavy metals due to their fascinating properties. Although the quantum yield of GQDs and CQDs is sufficient for their use as fluorescent probes, doping with heteroatoms can significantly improve their optical properties and selectivity toward specific analytes. This review explores the primary advances of CQDs and GQDs in their great electronic, optical, and physical properties, their synthetic methods, and their use in Hg2+ fluorimetry detection.

The pollution of heavy metals such as Cu2+ is still serious and the discharge of sewage of Cu2+ will cause damage to soil environment and human health. Herein, a biomass-based solid-state fluorescence detection platform (CPUCDs) was developed as fluorescent sensor for detection Cu2+ via fluorescence and colorimetric dual-model methods in real time. CPU-CDs was composed of xylan-derived CDs (U-CDs) and cotton cellulose paper, which exhibiting good reusability, non-toxicity, excellent fluorescence characteristics and high biocompatibility. Further, CPU-CDs displayed high effectiveness and sensitivity for Cu2+ with the detection limit as low as 0.14 mu M, which was well below U.S. EPA safety levels (20 mu M). Practical application indicated that CPU-CDs could achieve precision response of Cu2+ change in real environment water samples with good recovery range of 90 %- 119 %. This strategy demonstrated a promising biomass solid-state fluorescence sensor for Cu2+ detection for water treatment research, which is of great significance in dealing with water pollution caused by heavy metal ions.