This paper aims to develop geopolymer concrete (GPC) with flash-calcined soils cured under ambient conditions. Flash calcination is a heat thermal technique used to eliminate pollutants and organic content in excavated soils and allow them to be used in cementitious formulations. To develop GPC, the materials used in the development of the GP precursor binder should be rich in silicon (Si) and Aluminum (Al) that can react with alkaline silicates to yield Si-O-Al bonds that would form cementitious materials. The GP precursor binder is composed of Metakaolin (MK), flash-calcined soils, and granulated blast furnace slag (GBFS). The thermally treated soils are flash-calcined dredged sediments (FCS) and flash-calcined excavated clays (FCC) while potassium silicate is used as the alkaline reagent. This study aims to use the materials above to develop GPC cured under ambient conditions with high strength, good durability, and microstructure properties. Seven formulations are done to evaluate the effect of replacing MK with either FCS or FCC and GBFS on the mechanical compressive strength, water absorption, and freeze-thaw test. The findings reveal that using only metakaolin (MK0) in the formulation yielded the highest compressive strength. These results align with the porosity test outcomes, which show correlations between micropore and macropore percentages. Analysis of the durability freeze-thaw test suggests that as the proportion of macropores increases, formulations incorporating FCS and FCC exhibit improved resistance to extreme temperatures. Conversely, an increase in GBFS content leads to a finer microstructure and reduced resistance. Water absorption testing indicates that formulations with FCS and FCC display favorable sorptivity coefficients compared to MK0, with increased GBFS content enhancing durability. SEM/EDS and calorimetry tests were conducted to investigate the impact of substituting FCS and FCC for MK within the geopolymer matrix.

The efficiency of alkali-activated ground granulated blast furnace slag in stabilizing dredged sediments with high water contents is suboptimal because the activators become diluted. To improve stabilization efficiency, additives such as nano-CaCO3 are proposed. However, some of the proposed additives may not be practical owing to their high costs. This study experimentally investigates the addition of Na2CO3 for the stabilization of dredged sediment with high water contents (i.e., 100%) using Ca(OH)2-activated slag. Experimental results show the optimal content of Na2CO3 to obtain the highest 28-day unconfined compressive strength of stabilized sediments is 0.2% gravimetrically. Below the optimal content, the strength increases with Na2CO3 content. Above the optimal content, a decrease in strength is observed. By examining the reaction products and microstructure of the stabilized dredged sediments, it is observed that the coupling mechanism of cation exchange and calcite precipitation promotes the development of finer capillary pores, leading to a reduction in interpore connectivity and lower structural heterogeneity of the fine capillary pores. Experimental evidence from this study broadens the practical applications of sustainable soil stabilization using additives.

This study investigates the sustainable use of seabed dredged sediments and water treatment sludges as construction materials using combined dewatering and cement stabilization techniques. Dredged sediments and water treatment sludges, typically considered waste, were evaluated for their suitability in construction through a series of dewatering and stabilization processes. Dewatering significantly reduced the initial moisture content, while cement stabilization improved the mechanical properties, including strength and stiffness. The unconfined compressive strength (UCS), shear modulus, and microstructural changes were evaluated using various analytical techniques, including unconfined compression testing, free-free resonance testing, X-ray diffraction (XRD), scanning electron microscopy (SEM), and energy-dispersive X-ray spectroscopy (EDX). The results show a direct correlation between reduced w/c ratios and increased UCS, confirming the potential of treated sludge as a subbase layer for roads and landfill liners. A chemical analysis revealed the formation of calcium silicate hydrate (CSH) and ettringite, which are critical for strength enhancement. This approach not only mitigates the environmental issues associated with sludge disposal but also supports sustainable construction practices by reusing waste materials. This study concludes that cement-stabilized dredged sediments and water treatment sludges provide an environmentally friendly and effective alternative for use in civil engineering projects.