This research investigated the production of biodegradable plastic films made from a blend of carrageenan and corn starch biopolymers. The procedure included producing bioplastic resin pellets using a single screw extrusion at a 110 degrees C temperature, followed by hot compression at a temperature of 160 degrees C to form a biodegradable plastic film. The project aimed to develop a continuous biodegradable plastic production method, particularly made from carrageenan, which is more adaptable for commercial-scale production. The carrageenan/corn starch films were prepared with various compositions, ranging from formulations dominated by carrageenan (56:14% w/w) to those dominated by corn starch (14:56% w/w), with the addition of a constant amount of glycerol (30% w/w) as a plasticizer. After the films were obtained, each of the samples was evaluated for their physico-mechanical properties, chemical structure, water sensitivity, and soil biodegradability. In general, an increase in corn starch content within the film matrix led to an enhancement of the overall properties of the resulting film. The film with the highest corn starch content exhibited tensile strength and elongation at break values that were 49% and 163% higher, respectively, compared to the film with the lowest corn starch content. Additionally, these samples demonstrated improved thermal stability, with a 12% increase in the thermal decomposition temperature, and enhanced barrier properties, as evidenced by a 6% reduction in water vapor permeability and a 72% decrease in water uptake. This is mainly due to the inherent molecular structure of corn starch, particularly due to its long straight-glucose chains. On the other hand, carrageenan increased the biodegradability rate of the films. These findings demonstrate the potential of carrageenan/corn starch blends as promising candidates for future packaging materials.

Most biopolymers used as additives for the improvement of expansive subgrade soils are ecofriendly but highly uneconomical and unsustainable. Even the traditional additives such as cement, lime, and fly ash that are used widely for most soil improvement schemes are highly notorious for their carbon footprint. This necessitated the motivation in the present study to utilize an economical, ecofriendly and highly sustainable biopolymer, known as pregelatinized corn starch (PGCS), to improve the strength properties of an expansive subgrade soil. The PGCS was admixed with quarry dust (QD), an industrial waste additive, before blending with the expansive subgrade soil in different mix ratios generated with a 32 full factorial design experiment. The California bearing ratio (CBR) samples were subjected to 7 day curing while that of the unconfined compressive strength (UCS) were subjected to 1, 7, and 28 day curing. Shortly after the improvement of the expansive subgrade soil, the PGCS and QD were used as predictors in the development of two regression models for the two strength parameters (CBR and UCS) of the expansive subgrade soil considered in the study. Next, multiobjective salp swarm optimization algorithm (MOSSA), a bioinspired algorithm, was employed to optimize the additives in order to obtain optimal values of the strength properties of the expansive subgrade soil blended with the additives. The developed models were set as fitness functions in the slightly modified MOSSA technique. Thereafter, nondominated solutions were determined after the implementation of the optimization analysis. The results obtained from laboratory experiments and the optimization process showed that there was significant improvement in the UCS and CBR of the expansive subgrade soil. Optimal improvement in the UCS (1,326.241 kN/m2) and CBR (36.8%) were observed when an optimum mix ratio of the additives, 0.3117% PGCS and 10% QD, was blended with the expansive subgrade soil.

The present study aimed to assess the potential of a bio-inspired algorithm, multi-objective grey wolf optimization algorithm (MOGWO), to optimize the strength properties (California bearing ratio (CBR) and unconfined compressive strength (UCS)) of an expansive subgrade soil. This optimization process involves the use of two additives, namely a bio-polymer, pregelatinized corn starch (PGCS), and a nanoparticle agro waste, rice husk ash (RHA), blended with the soil in different mix ratios determined by a 32 factorial experimental design. The CBR samples were cured for 7 days, while the UCS samples were cured for 1, 7, and 28 days. To optimize the expansive subgrade soil strength, regression models were developed using PGCS and RHA as predictors for CBR and UCS, serving as fitness functions in the slightly modified MOGWO optimization technique. Next, the optimization analysis produced non-dominated solutions. The results obtained from the laboratory experiments and optimization analysis revealed that there was significant improvement in the UCS and CBR of the soil. These improvements can be attributed to the pozzolanic reaction between the soil-RHA matrix, the formation of intercalated and exfoliated nanocomposites, and the hydrophilic interaction of PGCS. By applying the slightly modified MOGWO technique, the study achieved optimal enhancements in UCS (710.3 kN/m2) and CBR (24.2%) when the expansive subgrade soil was mixed with 0.2637% PGCS and 12.2413% RHA. The results demonstrate the potential of the MOGWO technique in improving the properties of expansive subgrade soil.

The escalating environmental crisis posed by single-use plastics underscores the urgent need for sustainable alternatives. This study provides an approach to introduce biodegradable polymer blends by blending synthetic polyvinyl alcohol (PVA) with natural polymers-corn starch (CS) and hydroxypropyl methylcellulose (HPMC)-to address this challenge. Through a comprehensive analysis, including of the structure, mechanical strength, water solubility, biodegradability, and thermal properties, we investigated the enhanced performance of PVA-CS and PVA-HPMC blends over conventional polymers. Scanning electron microscopy (SEM) findings of pure PVA and its blends were studied, and we found a complete homogeneity between the PVA and both types of natural polymers in the case of a high concentration of PVA, whereas at lower concentration of PVA, some granules of CS and HMPC appear in the SEM. Blending corn starch (CS) with PVA significantly boosts its biodegradability in soil environments, since adding starch of 50 w/w duplicates the rate of PVA biodegradation. Incorporating hydroxypropyl methylcellulose (HPMC) with PVA not only improves water solubility but also enhances biodegradation rates, as the addition of HPMC increases the biodegradation of pure PVA from 10 to 100% and raises the water solubility from 80 to 100%, highlighting the significant acceleration of the biodegradation process and water solubility caused by HPMC addition, making these blends suitable for a wide range of applications, from packaging and agricultural films to biomedical engineering. The thermal properties of pure PVA and its blends with natural were studied using diffraction scanning calorimetry (DSC). It is found that the glass transition temperature (Tg) increases after adding natural polymers to PVA, referring to an improvement in the molecular weight and intermolecular interactions between blend molecules. Moreover, the amorphous structure of natural polymers makes the melting temperature (TM) lessen after adding natural polymer, so the blends require lower temperature to remelt and be recycled again. For the mechanical properties, both types of natural polymer decrease the tensile strength and elongation at break, which overall weakens the mechanical properties of PVA. Our findings offer a promising pathway for the development of environmentally friendly polymers that do not compromise on performance, marking a significant step forward in polymer science's contribution to sustainability. This work presents detailed experimental and theoretical insights into novel polymerization methods and the utilization of biological strategies for advanced material design.