Transforming waste materials into valuable commodities is a promising strategy to alleviate challenges associated with managing solid waste, benefiting both the environment and human well-being. This study is focused towards harnessing the potential of waste eggshell microparticles (ESMP) (0.10, 0.15, 0.20 g/150 mL) as reinforcing biofiller and orange peel essential oil (OPEO) (14 %, 25 % and 36 %, w/w) as bioactive agent with pectin (2.80, 2.85, 2.90, and 3.00 g/150 mL) to fabricate five different biocomposite films using particle dispersion and solvent casting technique. The addition of ESMP and OPEO progressively increased film thickness and led to variations in transparency. Micromorphological analysis and vibrational spectroscopy indicated hydrophobicity and compactness, as showed by the loss of free O- H bonds, sharpening of aliphatic C- H and stretching of C = C, C- O and C- O- C bonds with increasing filler content. Noticeable improvements in thermal stability and tensile strength were observed, while the flexibility was minimized. The films displayed remarkable barrier properties against hydrological stress, as evidenced by a reduction in water activity, moisture content, water uptake capacity, and solubility. The antioxidant activity against DPPH radicals suggested efficient release of bioactive compounds. Antibacterial assessment revealed inhibitory effect on Staphylococcus aureus and Bacillus cereus. During soil burial, notable weight loss along with shrinkage confirmed the film biodegradability. In conclusion, the pectin-ESMP-OPEO biocomposite films show potential characteristics as food packaging materials, warranting further performance testing on food samples.

Plastic production and waste are a growing menace that affects the soil, the marine environment, and the air in a cumulative manner. The demand for mineral and bioplastics from renewable and biodegradable materials has therefore increased in all relevant sectors. The use of currently available degradable plastics is, however, limited by their poor mechanical properties and high production costs. In addition, many of today's plastics undergo uncontrolled biodegradation processes that involve harsh or expensive conditions and which may last from months to years. Here, the advantages of using multi-arm polymers for the production of sustainable mineral plastics are presented. A 4-arm poly(acrylic acid) is synthesized via atom transfer radical polymerization and is reacted with divalent calcium ions to obtain semi-liquid hydrogel or degradable plastic when dried. The mechanical properties of the different phases are evaluated and compared with linear poly(acrylic acid) of the same molecular weight. The multi-arm approach yielded improved mechanical characteristics, including self-healing and biodegradation without compromising other typical hydrogel characteristics. This concept of synthesizing multi-arm polymers with improved characteristics from building blocks of traditionally linear structures may be applicable to other mineral and bioplastic materials including acrylates, polysaccharides, and DNA.

Skin-like bioelectronics offer a transformative technological frontier, catering to continuous and real-time yet highly imperceptible and socially discreet digital healthcare. The key technological breakthrough enabling these innovations stems from advancements in novel material synthesis, with unparalleled possibilities such as conformability, miniature footprint, and elasticity. However, existing solutions still lack desirable properties like self-adhesivity, breathability, biodegradability, transparency, and fail to offer a streamlined and scalable fabrication process. By addressing these challenges, inkjet-patterned protein-based skin-like silk bioelectronics (Silk-BioE) are presented, that integrate all the desirable material features that have been individually present in existing devices but never combined into a single embodiment. The all-in-one solution possesses excellent self-adhesiveness (300 N m-1) without synthetic adhesives, high breathability (1263 g h-1 m-2) as well as swift biodegradability in soil within a mere 2 days. In addition, with an elastic modulus of approximate to 5 kPa and a stretchability surpassing 600%, the soft electronics seamlessly replicate the mechanics of epidermis and form a conformal skin/electrode interface even on hairy regions of the body under severe perspiration. Therefore, coupled with a flexible readout circuitry, Silk-BioE can non-invasively monitor biosignals (i.e., ECG, EEG, EOG) in real-time for up to 12 h with benchmarking results against Ag/AgCl electrodes.

Poor strength of soils under dynamic loading conditions can trigger catastrophic failures during earthquakes, which are manifested in the form of landslides, lateral spreading of sloped ground and ground failure. Collapse of structures founded on such soils leads to loss of life and damage to infrastructure. Such conditions can be tackled through mechanical, physical, chemical, hydraulic or thermal treatment of the soils. Many of the conventional ground improvement methods like grouting or deep soil mixing involve addition or injection of cement or lime into the soil. Recent strides in developing bio-based sustainable ground improvement methods showed great promise in providing effective improvement under diverse loading scenarios. Though several bio-based ground improvement methods are being researched, the long-term and large-scale applications of many of these methods need further investigations. This paper presents a critical assessment of existing biobased-sustainable approaches geared toward enhancing the strength of soils to withstand dynamic loads.

The improper disposal of plastics is a growing concern due to increasing global environmental problems such as the rise of CO2 emissions, diminishing petroleum sources, and pollution, which necessitates the research and development of biodegradable materials as an alternative to conventional packaging materials. The purpose of this research was to analyse the properties of biodegradable polymer blends of thermoplastic potato starch (TPS) and polylactide, (PLA) without and with the addition of citric acid (CA) as a potential compatibilizer and plasticizer. The prepared blends were subjected to a comprehensive physicochemical characterization, which included: FTIR-ATR spectroscopy, morphological analysis by scanning electron microscopy (SEM), determination of thermal and mechanical properties by differential scanning calorimetry (DSC), water vapour permeability (WVP), as well as biodegradation testing in soil. The obtained results indicate an improvement in adhesion between the TPS and PLA phases due to the addition of citric acid, better homogeneity of the structure, and greater compatibility of the polymer blends, leading to better thermal, mechanical and barrier properties of the studied biodegradable TPS/PLA polymer blends. After conducting the comprehensive research outlined in this paper, it has been determined that the addition of 5 wt.% of citric acid serves as an effective compatibilizer and plasticizer. This supplementation achieves an optimal equilibrium across thermal, mechanical, morphological, and barrier properties, while also promoting material sustainability through biodegradation. In conclusion, it can be stated that the use of thermoplastic starch in TPS/PLA blends accelerates the biodegradation of PLA as a slowly biodegradable polymer. While the addition of citric acid offers significant advantages for TPS/PLA blends, further research is needed to optimize the formulation and processing parameters to achieve the desired balance between mechanical strength, thermal and barrier properties and biodegradability.