Friction characteristics are critical mechanical properties of clay, playing a pivotal role in the structural stability of cohesive soils. In this study, molecular dynamics simulations were employed to investigate the shear behavior of undrained montmorillonite (MMT) nanopores with varying surface charges and interlayer cations (Na+, K+, Ca2+), subjected to different normal loads and sliding velocities. Consistent with previous findings, our results confirm that shear stress increases with normal load. However, the normal load-shear stress curves reveal two distinct linear regions, indicating segmented friction behavior. Remarkably, the friction coefficient declines sharply beyond a critical pressure point, ranging from 5 to 7.5 GPa, while cohesion follows an inverse trend. The elevated friction coefficient at lower pressures is attributed to the enhanced formation of hydrogen bonds and concomitant changes in density distribution. Furthermore, shear strength was observed to increase with sliding velocities, normal loads, and surface charges, with Na-MMT exhibiting superior shear strength compared to KMMT and Ca-MMT. Interestingly, the friction coefficient shows a slight decrease with increasing surface charge, while ion type exerts a minimal effect. In contrast, cohesion is predominantly influenced by surface charge and remains largely unaffected by ion type, except under extreme pressures and velocities.

Energy piles, which serve the dual functions of load-bearing and geothermal energy exchange, are often modeled with surrounding soil assumed to be either fully saturated or completely dry in existing design and computational methods. These simplifications neglect soil saturation variability, leading to reduced predictive accuracy of the thermomechanical response of energy piles. This study proposes a novel theoretical framework for predicting the thermo-hydro-mechanical (THM) behavior of energy piles in partially saturated soils. The framework incorporates the effects of temperature and hydraulic conditions on the mechanical properties of partially saturated soils and pile-soil interface. A modified cyclic generalized nonlinear softening model and a cyclic hyperbolic model were developed to describe the interface shear stress-displacement relationship at the pile shaft and base, respectively. Governing equations for the load-settlement behavior of energy piles in partially saturated soils were derived using the load transfer method (LTM) and solved numerically using the matrix displacement method. The proposed approach was validated against experimental data from both field and centrifuge tests, demonstrating strong predictive performance. Specifically, the average relative error (ARE) was less than 15% for saturated soils and below 23% for unsaturated soils when evaporation effects were considered. Finally, parametric analyses were conducted to assess the effects of flow rate, groundwater table position, and softening parameters on the THM behavior of energy piles. This framework can offer a valuable tool for predicting THM behavior of energy piles in partially saturated soils, supporting their broader application as a sustainable foundation solution in geotechnical engineering.

This study conducted load-bearing capacity tests to quantitatively analyze the impact of permafrost degradation on the vertical load-bearing capacity of railway bridge pile foundations. Meanwhile, a prediction model vertical load-bearing capacity for pile foundations considering permafrost degradation was developed and validated through these tests. The findings indicate that the permafrost degradation significantly influences both the failure patterns of the pile foundation and the surrounding soil. With the aggravation of permafrost degradation, damage to the pile foundation and the surrounding soil becomes more pronounced. Furthermore, permafrost degradation aggravates, both the vertical ultimate bearing capacity and maximum side friction resistance of pile foundations exhibit a significant downward trend. Under unfrozen soil conditions, the vertical ultimate bearing capacity of pile foundations is reduced to 20.1 % compared to when the permafrost thickness 160 cm, while the maximum side friction resistance drops to 13.2 %. However, permafrost degradation has minimal impact on the maximum end bearing capacity of pile foundations. Nevertheless, as permafrost degradation aggravates, the proportion of the maximum end bearing capacity attributed to pile foundations increases. Moreover, the rebound rate of pile foundations decreases with decreasing permafrost thickness. Finally, the results confirm that the proposed prediction model can demonstrates a satisfactory level of accuracy in forecasting the impact of permafrost degradation on the vertical load-bearing capacity of pile foundations.

The coupled thermo-hydro-mechanical response caused by fire temperature transfer to surrounding rock/soil has a significant impact on tunnel safety. This study developed a numerical simulation model to evaluate the effects of fire on tunnel structures across different geological conditions. The heat transfer behavior varied with the mechanical properties and permeability of the geotechnics, concentrating within 1.0 m outside the tunnel lining and lasted for 10 days. Significant differences in pore water pressure changes were observed, with less permeable geologies experiencing greater pressure increases. Tunnel deformation was more pronounced in weaker geotechnics, though some tunnels in stronger geologies showed partial recovery post-fire. During the fire, thermal expansion created a bending moment, while a negative bending moment occurred after the fire due to tunnel damage and geotechnical coupling. The entire process led to irreversible changes in the bending moment. The depth of tunnel burial showed varying sensitivity to fire across different geological settings. This study provides important references for fire protection design and post-fire rehabilitation of tunnels under diverse geological conditions.

The stress state and density of soil have been considered as the key factors to determine the liquefaction resistance. However, the results of seismic liquefaction case histories, laboratory tests and centrifuge model tests show that the fabric characteristics also influence liquefaction resistance, even more significantly than the contributions of stress state and density. In this study, anisotropic specimens with different consolidation histories were prepared using the 3D Discrete Element Method (DEM) to investigate the influence of fabric characteristics on the mechanical behavior of granular materials and the underlying mechanisms. The simulations revealed that under monotonic shear conditions, horizontally anisotropic specimens exhibited strain hardening and dilatancy characteristics, as well as higher peak strength. Under cyclic shear condition, the normalized liquefaction resistance of the specimens showed a strong linear relationship with the degree of anisotropy, independent of confining pressures and density. Microscopic results indicate that the fabric arrangement aligned with the loading direction leads to the evolution of the mechanical coordination number and average contact force in a manner favorable to resisting loads, which is the underlying mechanism influencing macroscopic mechanical properties. Additionally, the evolution patterns of contact normal magnitude and angle in anisotropic granular materials under cyclic loading conditions were also analyzed. The results of this study provided a new perspective on the macroscopic mechanical properties and the evolution of the microstructure of granular soils under anisotropic conditions.

Self-boring pressuremeter (SBPM) tests are widely used in situ investigations, due to their distinct advantage to measure the shear stress-strain-strength properties of the surrounding soil with minimum disturbance. The measured pressuremeter curve can be interpreted using analytical solutions based on the long cylindrical cavity expansion/contraction theory with relatively simple constitutive models, to derive useful soil properties (e.g., undrained shear strength of clay, shear modulus, and friction angle of sand). However, the real soil behavior is more complex than the assumed constitutive relations, and the derived parameters may differ from those obtained using more reliable lab tests. In addition, SBPM tests can be affected by other well-known factors (e.g., installation disturbance, limited length/diameter ratio, and strain rate) that are not considered in the analytical solutions. In this paper, SBPM tests are evaluated using finite-element analysis and the MIT-S1 model, a unified constitutive model for soils, to consider complex soil behavior more realistically. SBPM tests in Boston Blue Clay and Toyoura sands are simulated in axial symmetric and plain strain conditions, and the computed results are interpreted following the suggested procedures by analytical solutions. The derived parameters are compared with those from the stress-strain relations to evaluate the reliability of SBMP tests for practical application.

With the advantages of low construction costs and rapid installation, suction caissons are widely used as foundations in offshore engineering. This paper investigates the behavior of suction caisson foundations located in sandy soil under horizontal cyclic loads. The upgraded simple anisotropic sand constitutive model with memory surface (SANISAND-MS model) is employed to accurately capture the sand's cyclic behavior. To calibrate the parameters of the upgraded SANISAND-MS model, a series of triaxial drained monotonic and cyclic tests was performed. The effects of load idealization and loading sequence on the cyclic behavior of sand are studied based on the element test results, and the effects of load idealization on the cyclic response of suction caissons are studied from a finite-element simulation perspective. The triaxial test results indicate that load idealization slightly affects strain accumulation in both loose and dense sand. Based on simulation results, it is found that the loading sequence of load packages with varying amplitudes has a minor effect on the rotation accumulation of the suction caisson. The current load idealization method used in the engineering design practice of suction caissons is acceptable under drained conditions.

High-strength mortar (HSM) gradually has wide applications due to its exceptional strength, micro-expansion properties, and excellent fluidity. Behavior deterioration of structures in saline soil areas is primarily attributed to freeze-thaw cycles and sulfate attack. In this study, the coupling effect of freeze-thaw cycles and sulfate attack on the appearance, mass loss, and relative dynamic elastic modulus of HSM was investigated during erosion. Then, compressive experiments were conducted to assess the mechanical properties of HSM subjected to both freeze-thaw cycles and sulfate attack. The influences of coupling freeze-thaw cycles and sulfate attack on the compressive properties of HSM were quantified through regression analysis of experimental results. Empirical models for compressive stress-strain curves and damage constitutive behavior of HSM were developed, taking the coupled adverse effect into account. The results indicate that the coupled effect of freeze-thaw cycles and sulfate attack causes performance deterioration of HSM. The empirical models reproduce the compressive behaviors of HSM subjected to freeze-thaw cycles and sulfate attack.

A novel iron-based phosphate cement (IPC), derived from iron-rich smelting slag (ISS), was developed as a sustainable and efficient binder for the stabilization/solidification of trivalent chromium (Cr3+). The mechanical properties, hydration behavior, microstructure, leaching toxicity, chromium chemical forms, and environmental safety of chromium-stabilized iron phosphate cement (CIPC) were thoroughly evaluated. The results showed that, with a mass ratio of ISS to ammonium dihydrogen phosphate (ADP) of 2.0, and even with the addition of 20 % chromium nitrate nonahydrate (CN), the compressive strength of CIPC reached 4.2 MPa after curing for 28 d. Furthermore, chromium leaching was well below 1 mg/L, significantly lower than the GB 5085.3-2007 standard limit of 15 mg/L, demonstrating the effective encapsulation of Cr3+ due to IPC's high early strength. In the IPC system, Cr3+ was primarily stabilized by forming CrPO4 and CrxFe1-x(OH)3 co-precipitates, which were further solidified through the physical encapsulation of IPC hydration products, such as (NH4)2Fe(PO3OH)2 center dot 4H2O, (NH4) (Mg,Ca)PO4 center dot H2O, and FePO4. This process resulted in a solidification efficiency of up to 99 %. BCR analysis confirmed that more than 98 % of the chromium in the CIPC remained in a stable residual form. Finally, the ecological risk index (PERT) was found to be 23.52, far below the safety threshold of 150, indicating the solidified material's long-term environmental safety. This study provides an innovative approach for the reutilization of ISS while effectively stabilizing/solidifying chromium.

Atrazine (ATR) is a widely utilized herbicide that has been demonstrated to exert a multitude of deleterious effects on the environment, particularly with regard to water and soil contamination. Moreover, its disruption of endocrine function and implications for antibiotic resistance underscore the urgent need to prioritize alternative solutions for both ecosystems and human health. Therefore, the objective of this study was to investigate a range of neurotoxic effects associated with atrazine-induced damage in the prefrontal lobe of mice. The results of this study indicate that treatment with ATR in C57BL/6 J mice resulted in cognitive-related behavioral deficits, including anxiety and depression, as well as motor impairments. In vivo analyses demonstrated that ATR exposure resulted in a reduction in neuronal synapse density at the microstructural level, while also compromising prefrontal morphological integrity, nociceptor count, and overall neuronal health within the brain. These findings collectively suggest that synaptic deficits are implicated in ATR-induced behavioral abnormalities observed in these mice. Furthermore, our findings revealed that ATR exposure resulted in elevated TDP-43 expression levels that were ectopically localized within the cytoplasm. This alteration led to impaired functionality of mRNP granules and contributed to the development of abnormal synaptic defects. Conversely, TDP43 has the potential to localize ectopically to mitochondria, where it activates the mitochondrial unfolded protein response (UPRmt), which ultimately results in mitochondrial dysfunction. These findings collectively indicate a strong correlation between TDP-43 dysregulation and the progression of neurodegenerative diseases. Further investigation into the potential neurotoxicity of atrazine may foster heightened awareness, leading to more stringent regulatory measures, research into safer alternatives, and the adoption of sustainable practices, which are essential for safeguarding environmental integrity alongside human health.