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The increasing production of waste glass fiber reinforced polymer (GFRP) is causing severe environmental pollution, highlighting the need for an effective treatment method. This study explores recycling waste GFRP powder to substitute ground granulated blast furnace slag (GGBS) in synthesizing geopolymers, aiming to rapidly stabilize clayey soil. The impact of GFRP powder replacement, alkali solution concentration, alkaline activator/precursor (A/P) ratio, and binder content on the geomechanical properties and permeability of stabilized soil was thoroughly examined. The findings revealed that replacing GFRP powder from 20 wt% to 40 wt% lowered the unconfined compressive strength (UCS). However, soil stabilized with 30 wt% GFRP powder displayed the highest shear strength. This indicates that the incorporation of an appropriate amount of GFRP powder elevates clay cohesion. Furthermore, an increase in GFRP powder replacement improved permeability coefficient in the early stages, with minimal impact observed after 28 days. Scanning electron microscopy with energy dispersive spectroscopy (SEM-EDS) analysis revealed a microstructural evolution of the stabilized soil, transitioning from a porous to a denser, more homogeneous composition over the curing period, which can be attributed to the formation of cluster gels enveloping the soil particles. Life cycle assessment (LCA) analysis indicated that the GFRP powder/GGBS geopolymer presents an alternative option to traditional Ordinary Portland Cement (OPC) binder, featuring a global warming potential (GWP)/strength ratio reduction of 6 %-40 %. This research offers a practical solution for effectively utilizing GFRP waste in a sustainable manner, with minimal energy consumption and pollution, thereby contributing to the sustainable development of soil stabilization.

期刊论文 2025-07-01 DOI: 10.1016/j.cscm.2025.e04204 ISSN: 2214-5095

The accumulation of waste glass (WG) from construction and demolition waste is detrimental to the environment due to its imperishable nature; therefore, it is crucial to investigate a sustainable way to recycle and reuse the WG. To address this issue, this study examined the mechanical strength, microstructural characteristics, and environmental durability-specifically under wet- dry (WD) and freeze-thaw (FT) cycles-of WG obtained from construction and demolition waste, with a focus on its suitability as a binding material for soil improvement applications. Firstly, sand and WG were mixed, and an alkali solution was injected into the mixture, considering various parameters, including WG particle size, mixing proportions, sodium hydroxide (NaOH) concentration, and curing time. Subsequently, the effect of WG grain sizes on micro- morphology characteristics and mineralogical phases was evaluated before and after the treatment through X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), and ultrasonic pulse velocity (UPV). The results revealed that reducing the WG particle size and increasing the WG/S ratio significantly improved the strength of the WG-treated samples. Additionally, decreasing the NaOH concentration and extending the curing time also positively influenced their strength. The UCS test results indicate that the particle size of WG significantly influenced the strength development of the samples, as the maximum compressive strength increased from 1.42 MPa to 7.82 MPa with the decrease in particle size. Although the maximum UCS values of the samples varied with different WG particle sizes, the values exceed the minimum criterion of 0.80 MPa required for use as a road substructure, as specified in the ASTM D4609 standard. Moreover, as WG grain size decreased, more geopolymer gels formed, continuing to fill the voids and making the overall structure denser, and the changes during geopolymerization were confirmed by XRD, SEM, FTIR, and UPV analysis. The optimum WG/S ratio was found to be 20 %, with strength increasing by approximately 3.88 times higher as the WG/S ratio shifted from 5 % to 20 %. In addition, the optimum NaOH concentration was determined to be 10 M, as higher molarities led to a decrease in strength. Moreover, UPV results indicate that WG-treated sand soils exhibited UPV values 9.4-13 times greater than untreated soils. The WD and FT test results indicate that WG-treated samples experienced more rapid disintegration in the WD cycle than in the FT cycle; however, a decrease in WG particle size resulted in reduced disintegration effects in both WD and FT conditions. In both the FT and WD cycles, the declining trend exhibited a stable tendency around the eighth cycle. Nevertheless, the WD cycling damage considerably intensified disintegration, causing a profound deterioration in the structural integrity of the samples. As a result, repeated WD cycles lead to the formation of microcracks, which progressively weaken soil aggregation and reduce the overall strength of the samples. Consequently, this green and simple soil improvement technique can provide more inspiration for reducing waste and building material costs through efficient use of construction and demolition waste.

期刊论文 2025-07-01 DOI: 10.1016/j.cscm.2025.e04241 ISSN: 2214-5095

Molybdenum ore tailings, iron ore tailings and waste glass powders are important industrial solid wastes, mainly composed of silicate minerals and quartz, which are expected to become alternative resources for inorganic nonmetal industrial materials. In this paper, the ultra-lightweight ceramsite was prepared by the synergistic sintering of molybdenum ore tailings, iron ore tailings and waste glass powders according to their characteristics of silicate minerals. The physical and mechanical properties were investigated when the sintering temperature was between 1100 and 1140 degrees C. The evolution of mineral phases and formation mechanism of pore structure during sintering were studied by XRD, FT-IR, SEM, TG-DSC and HSM. The results showed that in the sintering process, the waste glass powders and the pargasite in iron ore tailings first melted to produce the initial liquid phases. Then the anorthoclase and the quartz in molybdenum ore tailings melted to produce a large amount of liquid phases. These liquid phases covered the gas generated by the oxidation of SiC, thus forming a rich pore structure. At the same time, the [Si2O64-] and Ca2+, Mg2+ in the liquid phases derived from quartz and pargasite melting recrystallized to form diopside, which was conducive to the improvement of mechanical properties of ceramsite. When the raw material ratio of molybdenum ore tailings, iron ore tailings and waste glass powders was 6:2:2 and the sintering temperature was 1120 degrees C, the pore structure of the ceramsite as prepared was uniform and rich and mostly closed. The density was low and the mechanical propertities were excellent. It has a good application prospect in the field of building thermal insulation and sound insulation.

期刊论文 2024-11-22 DOI: 10.1016/j.conbuildmat.2024.138852 ISSN: 0950-0618

The massive accumulation of waste seashells, waste sludge and waste glass not only occupies a large amount of land resources, leading to a shortage of land resources, but also causes serious soil-water-air composite pollution over a long period of time with the role of the surrounding environment, which poses a serious hazard to the ecological environment and public health. In this study, the effect patterns of waste glass powder (WGP) on the workability, mechanical properties, microstructure and carbon emission of seashell powder calcined sludge cement (SCSC) slurries prepared using waste sludge and waste seashells as supplementary cementitious materials in place of part of the cement clinker were investigated. The hydration process and microstructure of the materials were characterized by heat of hydration tests, thermogravimetry (TG-DTG), infrared Fourier transform (FTIR), X-ray diffraction (XRD) and scanning electron microscopy (SEM). The results showed that the addition of WGP improved the fluidity of SCSC slurries and reduced the shear stress of SCSC slurries without changing the flow pattern of SCSC slurries, and all the slurries conformed to the power law model. The compressive strength of SCSC slurries increased by 25.26 % with 5 % WGP addition. The CO2 emissions per cubic meter of SCSC slurries were reduced by 4.43 %, 8.81 %, 13.5 % and 18.23 % for WGP additions of 5 %, 10 %, 15 % and 20 %, respectively. These results can provide a new way for the efficient resource utilization of waste seashells, waste sludge and waste glass, and reduce the CO2 emission during the cement production process, promoting the clean production of cement.

期刊论文 2024-11-01 DOI: 10.1016/j.jobe.2024.110665

The complex interactions between soil and additives such as lignin, glass powder, and rubber tires were investigated using principles of material and soil mechanics. Previous research has mainly focused on individual additives in clay soils. In contrast, this study investigates soil improvement with two different types of waste materials simultaneously. The improvement of soil properties by hybrid waste materials was evaluated using several laboratory tests, including the standard Proctor test, the unconfined compressive strength test, the California Bearing Ratio (CBR) test, and cyclic triaxial tests. The aim of this research is to identify key parameters for the design and construction of road pavements and to demonstrate that improving the subgrade with hybrid waste materials contributes significantly to the sustainability of road construction. The mechanical and physical properties were evaluated in detail to determine the optimal mixtures. The results show that the most effective mixture for the combination of waste glass powder and rubber tires contains 20% glass powder and 3% rubber tires, based on the dry weight of the soil. For the combination of waste glass powder and lignin, the optimum mixture consists of 15% glass powder and 15% lignin, based on the dry weight of the soil. These results provide valuable insights into the sustainable use of waste materials for soil stabilization in road construction projects.

期刊论文 2024-09-01 DOI: 10.3390/app14177532
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