Peloid is a natural product developed during the maturation process between a clay material and water and is used in health and wellness centres due to its mineralogical, physiochemical and biological properties. However, the potential therapeutic value of clays in Portugal has not been fully investigated. Therefore, the main objective of this research is to identify the effects of two mineralized waters: thermo-mineral water (sulphurous and hydroxylated water abundant in chloride ions, sodium and calcium) and seawater, on three residual soils from Alentejo, from a morphological, mineralogical and chemical perspective. The peloids morphology is more homogeneous than the residual soils, and the particle size decreases during the maturation process. Thermo-mineral water enriched the peloids in smectite (58-76 %), while seawater newly formed Na-minerals (decreasing smectite contents to 39-54 %). Smectite is essentially montmorillonite, although there is nontronite and beidelite. The residual soils and peloids have a silicilastic composition (32.23-52.85 %), between 14.22 and 20.53 % of Al2O3, and besides smectite, the mineralogical composition is composed of salts (only in seawater peloids), feldspars, iron oxides, carbonates, and quartz. Morphology and mineralogy enhance the influence of waters in peloids properties and suggest that this samples have potential therapeutic value. Furthermore, physicalchemical, rheological, thermal and biological analysis are needed to support these findings.

Contact Lens (CLs) are often disposed of via toilet or sinks, ending up in the wastewater treatment plants(WWTPs). Millions of CLs enter WWTPs worldwide each year in macro and micro sizes. Despite WWTPs'ability to remove solids, CLs can persist and potentially contaminate watercourses and soils. This study evaluates whether different CLs degrade in WWTP aeration tanks. Six daily CLs (Nelfilcon A,Delefilcon A, Nesofilcon A, Stenfilcon A, Narafilcon A, Somofilcon A) and four monthly CLs (Lotrafilcon B,Comfilcon A, Senofilcon A, and Samfilcon A) were immersed in aeration tanks for twelve weeks. Theirphysical and chemical properties, including water content (WC), refractive index (RI), chemical prop-erties (Fourier Transform Infrared Spectroscopy), and mechanical properties were assessed. Results show that all CLs maintained their physical appearance after 12 weeks. Neither Nelfilcon A norNarafilcon A exhibited significant changes in WC and RI, (p>0.05, Tukey test), while other daily lensesshowed variations in at least one parameter. Among monthly CLs, only Senofilcon A showed significant differences in both WC (p0.05 Tukey test). However, Somofilcon A displayed significant changes in stress at break (p<0.0001,Tukey test), and Elongation at Break (p<0.05, Tukey test). No changes were found in the chemicalstructure of any CLs suggesting that twelve weeks in WWTP aeration tanks is insufficient for CLsdegradation. Thesefindings highlight CLs as a potential emerging pollutant, emphasizing their persis-tence in sludge or migration into watercourses and soils (c) 2025 The Authors. Publishing services by Elsevier B.V. on behalf of KeAi Communications Co. Ltd. Thisis an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).

Thermochemical processing of biowaste generates renewable carbon-rich materials with potential agronomic uses, contributing to waste valorization. This study evaluates the application of hydrochar obtained from hydrothermal carbonization of food waste, those obtained by different post-treatments (washing, aging, and thermal treatment), as well as biochar obtained by pyrolysis as soil amendments. For this purpose, the effect of char addition (1-10 wt% d.b.) on a marginal agricultural soil on germination and growth of Solanum lycopersicum (tomato) plants was assessed. All the hydrochars exhibited a chemical composition suitable for agronomic use, characterized by high nutrient content, abundant organic matter, and low concentration of phytotoxic metals. In contrast, biochar exceeded the permissible limits for Cr, Cu, and Ni concentrations rendering it unsuitable for application to agronomic crops. The high temperature of thermal post-treatment and pyrolysis favored mineral and heavy metal concentration while washing significantly reduced nutrient content (N, S, P, K, Mg) along with the electrical conductivity. The addition of biochar or both washed and thermally post-treated hydrochar negatively affected tomato growth. Reduced chlorophyll content was associated with the decreased expression of genes encoding enzymes involved in antioxidant metabolism. This led to photosynthetic membrane damage, as evidenced by chlorophyll fluorescence-related parameters. Conversely, the addition of aged (<= 5 wt %) and fresh (1-10 wt%) hydrochars increased both germination and plant growth compared to unamended soil, indicating that hydrochar from food waste does not require additional post-treatments to be used as a soil amendment.

Loose sandy soil layers are prone to liquefaction under strong earthquakes, causing damage to civil engineering structures inside or upon the liquefied ground. According to the present Japanese design guideline on liquefaction countermeasures for river levees, the entire depth of the liquefiable subsoil below river embankments should be improved. However, this approach is not economical against deep liquefiable subsoil. To rationalize the design approach, this contribution investigated the performance of a floating-type cement treatment method, in which only the shallower part of the liquefiable subsoil is reinforced. A series of centrifuge shaking table model tests was conducted under a 50g environment. The depth of improvement (cement treatment) was varied systematically, and the effect of the sloping ground was examined. The experimental results revealed that the settlements of river embankments can be reduced linearly by increasing the depth of improvement. Moreover, the acceleration of embankments can be reduced drastically by the vibration-isolation effect between the cement-treated soil and the liquefiable soil. These effects contribute to the safe retention of the embankment shape even when the liquefied sloping ground causes lateral flows. Towards practical implementation, discussions on the effect of permeability on cement-treated soil were expanded. Furthermore, the stress acting on cement-treated soil during shaking was measured using an acrylic block to explain the occurrence of cracks in the soil. (c) 2025 Japanese Geotechnical Society. Published by Elsevier B.V. This is an open access article under the CC BY-NC-ND license (http:// creativecommons.org/licenses/by-nc-nd/4.0/).

This study addresses the cracking issue of airport foundations in marine and coastal regions by proposing an unsaturated reinforcement method based on Microbially Induced Calcium Carbonate Precipitation (MICP) combined with coconut fibers. Composite sand columns incorporating coconut fiber and bioslurry were prepared, and the effects of fiber length and content on the mechanical properties of MICP-treated sand columns were investigated. Experimental results revealed that the addition of short fibers (1-5 mm) significantly improved the unconfined compressive strength and ductility of the MICP-treated sand columns. As the bioslurry content decreases in the sand columns, the enhancement effect of short fibers on the unconfined compressive strength becomes more pronounced, with fiber addition improving compressive strength by up to 98 %. However, the inclusion of medium fibers (5-10 mm) and long fibers (10-15 mm) negatively affected the mechanical properties of the sand columns. Microstructural analysis further confirmed the synergistic reinforcement effect of short fibers and calcium carbonate precipitation. Short fibers acted as bridges, forming additional contact points between sand particles, which facilitated calcium carbonate precipitation at critical contact points, thereby enhancing the overall stability and strength of the sand columns. This characteristic was more pronounced under unsaturated conditions. This study provides a feasible technical solution for the effective reinforcement of airport foundations and demonstrates potential in unsaturated reinforcement and improving the ductility of sandy soil foundations.

The fundamental cause of frost heave and salt expansion of saline soil is the water condensation and salt crystallization during the freezing process. Therefore, controlling the water and salt content is crucial to inhibit the expansion behaviors of saline soil. Recently, electroosmosis has been demonstrated to accelerate soil dewatering by driving hydrated cations. However, its efficiency in mitigating the salt-induced freezing damages of saline soil requires further improvement. In this study, a series of comparative experiments were conducted to investigate the synergistic effects of electroosmosis and calcium chloride (CaCl2) on inhibiting the deformation of sodium sulfate saline soil. The results demonstrated that electroosmosis combined with CaCl2 dramatically increased the cumulative drainage volume by improving soil conductivity. Under the external electric field, excess Na+ and SO42- ions migrated towards the cathode and anode, respectively, with a portion being removed from the soil via electroosmotic flow. These processes collectively contributed to a significant reduction in the crystallization-induced deformation of saline soil. Additionally, abundant Ca2+ ions migrated to cathode under the electric force and reacted with OH- ions or soluble silicate to form cementing substances, significantly improving the mechanical strength and freeze-thaw resistance of the soil. Among all electrochemical treatment groups, the soil sample treated with 10 % CaCl2 exhibited optimal performance, with a 71 % increase in drainage volume, a 180 similar to 443 % enhancement in shear strength, and a 65.1 % reduction in freezing deformation. However, excessive addition of CaCl2 resulted in the degradation of soil strength, microstructure, and freeze-thaw resistance.

This study investigates the effect of 3-aminopropyltriethoxysilane (APTES) concentration on the surface modification of rice husk (RH) for developing polybutylene adipate-co-terephthalate (PBAT) composites with varying filler loadings (30-50 wt%). Silane-treated RH was incorporated into PBAT via melt blending to enhance mechanical and thermal properties. The novelty lies in systematically correlating APTES concentration with RH loading, offering insights into their synergistic impact on composite microstructure and overall performance. Our approach provides a comprehensive understanding of how controlled silane treatment improved interfacial adhesion, mechanical strength, thermal stability, and maintained biodegradability. Characterization was performed using Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), X-ray diffraction (XRD), tensile testing, thermogravimetric analysis (TGA), water absorption, and soil burial tests. SEM revealed a more homogeneous morphology with fewer voids. The 70PBAT/30Silane RH-2% composite achieved the best mechanical performance, outperforming 4% and 6% silane-treated composites, with tensile strength improvements of 7% and 10%, and Young's modulus increases of 12% and 4%, respectively. Tensile properties indicated that for a filler loading of 30 wt%, a 2% silane concentration is sufficient, while a maximum of 6% is required for 40 wt%, and a minimum of 4% is necessary for 50 wt% filler loading. TGA showed enhanced thermal stability with higher filler content, while soil burial tests confirmed 90% mass loss after 6 months, indicating excellent biodegradability. These results highlight the potential of silane-treated PBAT/RH composites for sustainable molded products such as trays.

A common physical technique assessed for improving expansive clays is by the addition of natural fibres to the soil. A good understanding of the impact of stabilisation using fibres on the clay soil's constituents, microfabric, and pore structure is, however, required. Mixtures of clay and fibre, regardless of type or extent, can never change the natural composition of the clay. Even the smallest part must still consist of spaces with clay with the original physical properties and mineralogy. This suggests that, although the mixture may show beneficial physical changes over the initial clay soil, its spatial attributes in terms of mineralogical characteristics, remain unchanged. This paper discusses some of the fundamentals that are not always adequately considered or addressed in expansive clay research, aiming to improve the focus of current and future research investigations. These include the process, mechanics, and implications of chemical and physical soil treatment as well as the concept of moisture equilibration.

Strongyloides stercoralis (S. stercoralis) is a soil-transmitted nematode that is endemic to tropical and subtropical regions. S. stercoralis has the ability to cause autoinfection, potentially leading to a chronic disease that can last for decades or result in severe hyperinfection especially in individuals who are taking corticosteroids or other immunosuppressive medications. Here, we report the case of a patient presenting a two-week history of symptoms including cough, fatigue, weight loss, pruritus, and rash. Due to a significant increase in the percentage of eosinophils, the patient was referred to the hematology clinic. The patient underwent a comprehensive evaluation that included an autoimmune panel, genetic testing, and imaging methods. The results of these investigations were found to be normal. The upper gastrointestinal system endoscopy revealed eosinophilic duodenitis and corticosteroid treatment was initiated. The commencement of corticosteroid therapy resulted in a worsening of the patient's symptoms. In the repeated endoscopy of the upper gastrointestinal tract, the presence of S. stercoralis larvae was observed between the crypts. Subsequently, stool tests for S. stercoralis diagnosis were also found to be positive. The patient was at risk of developing a hyperinfection syndrome. Corticosteroids are commonly used to reduce inflammation and manage symptoms associated with eosinophilic disorders. The immunosuppressive effects of corticosteroids are known to precipitate S. stercoralis hyperinfection syndrome, which can result in significant morbidity and mortality. This case highlights the importance of maintaining a high index of suspicion for S. stercoralis in patients undergoing immunosuppressive therapy, particularly when presenting with unexplained eosinophilia.

Recycled aggregates (RA) from construction and demolition waste have many shortcomings such as high porosity and low strength due to adhered mortar and defects inside. If the defects (micropores and microcracks) of RA were repaired, the quality of RA could be improved greatly and its application could be further enlarged. Our previous study has proposed a new modification method, enzyme-induced carbonate precipitation (EICP), to repair the internal defects of RA. In this study, the efforts were focused on the optimization of the EICP treatment. It was found that the two-step immersion method, consisting of preimmersing in CO(NH2)2-Ca(NO3)2 solution for 24 h, then adding urease solution at once with single treatment duration of 5 days and cycling two treatments, was the optimal treatment. Compared with the untreated RA, the water absorption and crush value of treated recycled concrete aggregates (T-CA) were decreased by 7.01% and 9.91%, respectively, and 21.59% and 14.40% for treated recycled mixed aggregates (T-MA), respectively. By use of the optimized EICP-treated RA, the compressive strength of concrete increased by 6.05% (T-CA concrete) and 9.23% (T-MA concrete), and the water absorption of concrete decrease by 11.46% (T-CA concrete) and 18.62% (T-MA concrete). This indicates that the optimized EICP treatment could reduce the porosity and improve the strength of aggregates, thus enhancing the mechanical properties and impermeability of recycled concrete.