This research explores the stabilization of clay soil through the application of geopolymer binder derived from silicomanganese slag (SiMnS) and activated by sodium hydroxide (NaOH). This research aims to evaluate the effects of key parameters, including the percentage of slag, the activator-to-stabilizer ratio, and curing conditions (time and temperature), on the mechanical properties of the stabilized soil. Unconfined compressive strength (UCS) tests were conducted to assess improvements in soil strength, while scanning electron microscopy (SEM) was employed to analyze the microstructural changes and stabilization mechanisms. The results demonstrated that clay soil stabilized with SiMnS-based geopolymers exhibited significant strength enhancement. Specifically, the sample stabilized with 20% SiMnS and an activator-to-slag ratio of 1.6, cured at room temperature for 90 days, achieved a UCS of 27.03 kg & frasl;cm2. The uniaxial strength was found to be positively correlated with the SiMnS content, activator ratio, curing time, and temperature. Additionally, the strain at failure remained below 1.5% for all samples, indicating a marked improvement in soil stiffness. SEM analysis revealed that geopolymerization led to the formation of a dense matrix, enhancing soil particle bonding and overall durability. These results emphasize the potential of SiMnS-based geopolymers as a sustainable and effective soil stabilizer for geotechnical applications.

Due to the detrimental ecological impacts and the exorbitant expenses associated with the cement industry, researchers have sought to find natural, sustainable, low-carbon alternatives to Portland cement for weak soil stabilization. This research used geopolymer based on metakaolin (MK), a natural pozzolanic material with different activator concentrations (NaOH and Na2SiO3), to stabilize loose poorly graded sand soils. The research investigated the effect of different amounts of addition MK (5, 10, and 15 %) on the soil's mechanical properties. Furthermore, the effect of parameters such as the type and concentration of the alkaline solution and curing time (1, 3, and 7 days) on the unconfined compressive strength, failure strain, Young's modulus, California bearing ratio, and direct shear test were evaluated. This research also aims to measure the sub- grade reaction modulus (Ks) by developing and manufacturing a laboratory testing apparatus and steel mold to simulate the natural conditions of sandy subgrade soil obtained from performing nonrepetitive static plate load tests. Additionally, scanning electron microscopy images (SEM) and X-ray diffraction analysis (XRD) were also used to study the microstructural changes and the chemical composition of the stabilized soil samples. The results indicate that the soil samples that were stabilized with MK 10 % and NaOH had notably higher compressive strength (2936 kPa), indicating a denser and less porous structure (improved stiffness stabilized soil) in comparison to the soil samples stabilized with MK 10 % and Na2SiO3 which was (447 kPa). Ultimately, Microstructural analysis showed that, due to the addition of 10 % MK, stabilized soils have a denser and more homogeneous structure.

The increasing production of waste glass fiber reinforced polymer (GFRP) is causing severe environmental pollution, highlighting the need for an effective treatment method. This study explores recycling waste GFRP powder to substitute ground granulated blast furnace slag (GGBS) in synthesizing geopolymers, aiming to rapidly stabilize clayey soil. The impact of GFRP powder replacement, alkali solution concentration, alkaline activator/precursor (A/P) ratio, and binder content on the geomechanical properties and permeability of stabilized soil was thoroughly examined. The findings revealed that replacing GFRP powder from 20 wt% to 40 wt% lowered the unconfined compressive strength (UCS). However, soil stabilized with 30 wt% GFRP powder displayed the highest shear strength. This indicates that the incorporation of an appropriate amount of GFRP powder elevates clay cohesion. Furthermore, an increase in GFRP powder replacement improved permeability coefficient in the early stages, with minimal impact observed after 28 days. Scanning electron microscopy with energy dispersive spectroscopy (SEM-EDS) analysis revealed a microstructural evolution of the stabilized soil, transitioning from a porous to a denser, more homogeneous composition over the curing period, which can be attributed to the formation of cluster gels enveloping the soil particles. Life cycle assessment (LCA) analysis indicated that the GFRP powder/GGBS geopolymer presents an alternative option to traditional Ordinary Portland Cement (OPC) binder, featuring a global warming potential (GWP)/strength ratio reduction of 6 %-40 %. This research offers a practical solution for effectively utilizing GFRP waste in a sustainable manner, with minimal energy consumption and pollution, thereby contributing to the sustainable development of soil stabilization.

Eco-friendly materials have gained significant attention for soil stabilization and reinforcement in road construction and geo-environmental infrastructure, as traditional additives pose notable environmental concerns. In this study, three concentrations of Chitosan Biopolymer (CBP) (1.5 %, 3 %, and 4.5 %) as a bio-stabilizer, three proportions of Rice Husk Biochar (RHB) (0.5 %, 1 %, and 1.5 %) as a waste-derived filler, and three dosages of Hemp Fiber (HF) (0.2 %, 0.4 %, and 0.6 %) as reinforcement were used to treat sand-kaolinite mixtures (SKM). The samples were cured for 1, 7, 14, 21, and 28 days and subjected to varying numbers of freeze-thaw (F-T) cycles. A diverse range macro-scale laboratory tests, encompassing compaction, unconfined compressive strength (UCS), indirect tensile strength (ITS), F-T durability, ultrasonic pulse velocity (UPV), and thermal conductivity (TC), were performed on the treated samples. In addition, microstructural analyses using X-ray diffraction (XRD), scanning electron microscopy (SEM), and Fourier-transform infrared spectroscopy (FTIR) were conducted to correlate mechanical behavior with micro- scale properties. The optimal dosages of CBP and RHB were first determined through UCS tests, with 3 % CBP and 1 % RHB proving the most effective. These dosages were then used to analyze their impact on other mechanical properties. Results showed that the compressive and tensile strengths of the bio-stabilized soil at the optimum contents of additives increased by 2410.7 kPa and 201.2 %, respectively, compared to the control samples. Incorporating HF into the SKM-CBP-RHB mixtures significantly enhanced their F-T durability after 10 consecutive cycles, reducing strength deterioration and performance degradation compared to the untreated soil. The optimum composition (3 % CBP, 1 % RHB, and 0.4 % HF) led to a 6.1-fold increase in ITS and a minor 2 % reduction in performance after 10 F-T cycles. Moreover, HF incorporation improved the failure strain and reduced the brittleness of the stabilized soil. UPV and TC tests revealed that incorporating HF at levels up to 0.4 %, combined with the optimum CBP-RHB mixture, enhanced soil stiffness by 963.7 MPa and reduced thermal conductivity by 0.76 W & sdot;m-1 & sdot;K-1. The microstructural analysis confirmed these findings, showing enhanced interlocking between SKM and fibers via hydrogel formation. Overall, the study demonstrates that the CBP-RHB-HF composite markedly enhances soil strength and durability, making these additives highly suitable for applications like landfills, embankments, and slopes.

This study developed all-solid-waste-based curing agents using industrial solid wastes-ground granulated blastfurnace slag (GGBS), carbide slag (CS), and sulfate solid wastes (electrolytic manganese residue (EMR), desulfurized-gypsum (DG), and phosphogypsum (PG))-to stabilize engineering sediment waste (ESW). Based on the simplex centroid design, three ternary curing agents (GGBS-EMR-CS (GEC), GGBS-DG-CS (GDC), and GGBSPG-CS (GPC)) were prepared. The optimal ratios for GEC, GDC, and GPC are 60:12:28, 70:27:3, and 70:21:9, respectively. Compared to ordinary Portland cement (OPC), the unconfined compressive strength (UCS) of ESW stabilized with these curing agents increased by 78 %, 178 %, and 98 %, respectively. Sulfate components synergistically activates GGBS and CS, promoting needle-like ettringite (AFt) formation, which fills pores and enhances strength. Meanwhile, COQ emissions and costs were reduced up to 99 % and 73 %, respectively. This study developed all-solid-waste-based curing agents with excellent mechanical performance, low costs, and near net-zero emissions, which provided a sustainable solution for ESW stabilization.

This study presents a new experimental procedure for evaluating the durability of stabilized soils subjected to multiple wetting and drying (W-D) cycles. An integrated experimental program combining dynamic shear rheometer (DSR) testing with W-D cycles was designed and implemented to assess moisture-induced performance degradation in natural sand stabilized with two types of rapid-setting cementitious stabilizers. Small cylindrical specimens (10.5 mm in diameter and 35.0 mm in height) of stabilized sand mixes were compacted, cured, and subjected to up to seven W-D cycles. Each W-D cycle was meticulously controlled to gauge its impact on the material's durability. The mechanical properties of the stabilized samples were evaluated at different stages of the W-D cycles using the strain-sweep DSR testing based on a methodology developed from preliminary work. The proposed test method focuses on the shear properties of the material, measuring its mechanical response under the torsional loading of a cylindrical sample and providing dynamic mechanical properties and fatigue-resistance characteristics of the stabilized soils under cyclic loading. Test results demonstrate water-induced deterioration of stiffness and reduced resistance to cyclic loading with good testing repeatability, efficiency, and material-specific sensitivity. By combining dynamic mechanical characterization with durability assessment, the new testing method provides a high potential as a simple, scientific, and efficient method for assessing, engineering, and developing stabilized soils, which will enable more resilient transportation infrastructure systems.

This study explores the mechanical properties and synergistic mechanisms of silty sand modified with guar gum (GG) and polypropylene fiber (PP fiber) through a series of unconfined compressive strength (UCS) tests, direct shear tests, and direct tensile tests. The test results reveal that the unconfined compressive strength (UCS) of silty sand can be dramatically improved by incorporating GG, boosting its strength by up to 23 times compared to the natural soil. Adding PP fiber further enhances the UCS and effectively mitigates brittle failure. GG dominates the increase in shear strength by enhancing cohesion, while the PP fiber optimises the shear stability by increasing the internal friction angle. The shear strength of the GG-PP fiber-enhanced soil can be boosted by 235% compared to natural soil. The synergistic effect of GG and PP fibers enables the tensile strength of the improved silty sand to reach 122.75 kPa, representing a 34.15% increase compared to soil with only GG incorporated. However, if the fiber content is too high (> 0.5%), the tensile strength will decrease due to increased porosity. The study found that GG enhances the cohesion between soil particles through hydrated gel, and the PP fiber inhibits crack propagation and improves ductility through the bridging effect. The two form a bonding-bridging synergistic system, which significantly optimises the mechanical properties of the soil. This combined improvement scheme has both high strength and high ductility and can replace traditional inorganic cementitious materials, providing new ideas and methods for the application of silty sand in roadbed engineering, slope reinforcement, and other fields.

This study evaluated the stabilization of dam sediment using a blended binder of eucalyptus wood ash (EWA) and cement for cost-effective and environmentally safe pavement material development. The sediment is classified as a sandy lean clay. EWA, a pozzolanic byproduct, was used as a partial cement replacement to enhance the material's geotechnical properties and reduce environmental impact. The optimized mixture showed a 12-fold increase in unconfined compressive strength (1.4 MPa) and a California bearing ratio of 70%, meeting Thailand Department of Highways' specifications for subbase and base layers. The microstructural analysis confirmed the formation of calcium silicate hydrates, improving durability and reducing weight loss by 30% under wetting-drying cycles. Leachate tests showed that heavy metal concentrations remained within regulatory limits. EWA also reduced costs by 2.6 times compared to conventional stabilization methods, highlighting its potential for pavement applications.

This study investigated the improvement in a type of sand using a geopolymer made of recycled glass powder (RGP) as the base material and sodium hydroxide (NaOH) as the alkaline activator. Using maximum uniaxial compressive strength (UCS), the impact of alkaline activator concentration and the RGP content were investigated to determine the optimum mix design. Groundwater level increments were simulated through a laboratory procedure to study the effect of curing age and capillary action on the behavior of stabilized soil. The UCS of samples at different ages (14, 28, 45, and 60 days) and different degrees of saturation (Sr=0%, 20%, 50%, 80%, and 100%) were determined and their stress-strain diagrams were drawn. Using the stress-strain relationships, UCS, modulus of elasticity (Es), shear modulus (G), and resilient modulus (Mr) of the stabilized soil were estimated. The results showed that fully saturated stabilized samples did not disintegrate and exhibited a considerable UCS of up to 1.88 MPa at the age of 60 days. The greatest observed reduction in the UCS through saturation was between Sr=0 to 20%. To further investigate and validate the mechanical results, chemical and microstructural studies including X-ray fluorescence (XRF), scanning electron microscopy (SEM), energy dispersive X-ray analysis (EDX), X-ray diffraction analysis (XRD), and Fourier transform infrared spectroscopy (FTIR) were carried out. The results showed that during the curing period, the silicon/aluminum (Si/Al) ratio increased from 2.98 in untreated soil to 4 in stabilized samples, indicating active geopolymerization, which enhanced UCS and reduced the potential for disintegration. Additionally, the crystal size decreased from 53 to 24 nm for the 45-day stabilized samples when the degree of saturation changed from 0% to 100%. This finding suggests that if RGP-based geopolymer-stabilized soil contacts water after fully drying, geopolymerization reactions will resume that involve the dissolution of both crystalline and amorphous phases.

The effectiveness of zeolitic tuff (ZT) based geopolymer stabilization as a sustainable alternative to conventional cement stabilization for expansive soils is investigated in this study. Mechanical and geotechnical properties of geopolymer stabilized soil are evaluated in terms of ZT content, sodium silicate to sodium hydroxide (NS:NH) ratio and curing time. Soil improvement was assessed by laboratory tests, unconfined compressive strength (UCS), plasticity, compaction, and free swell tests. The test results show that the geopolymer stabilization increases the UCS significantly, as the NS:NH=2:1 mixture attains the maximum UCS of about 5.0 MPa in 28 days of curing, representing a 40 % increase over 12 % cement-stabilized soil. Furthermore, geopolymer-stabilized soils show a higher swelling reduction with free swell percentages as low as 0.25 %, a 42 % improvement compared to cement. The environmental assessment shows a 19 % lower CO2 emission per MPa of strength for geopolymer stabilization compared to cement-based stabilization, making it an eco-friendly choice. Pavement performance analysis using the Mechanistic-Empirical Pavement Design Guide (MEPDG) indicates that geopolymer-stabilized subbase layers improve structural integrity while reducing overall pavement rutting and fatigue cracking. Scanning Electron Microscopy (SEM) results validate the creation of a dense geopolymer matrix structure that enhances the strength and stability characteristics of soil materials. The study concludes that geopolymer stabilization using ZT with optimized NS:NH ratios delivers effective, high-performing, environmentally sustainable alternatives to traditional cement.