Microstructure and pore characteristics of soil determine its physical and mechanical properties such as deformation, strength, and permeability. The accurate characterization of soil microstructure is a crucial prerequisite for understanding soil texture and for the effective characterization of soil properties. This study aimed to evaluate the applicability and limitations of various soil micro-test methods, compare the resolution of different micro-test techniques, and present their results. Several different techniques and methods have been used to analyze soil micropore structures. In terms of micro-visualization, scanning electron microscopy (SEM) and computed tomography (CT) are common imaging methods that can present the microstructure of the soil surface and its interior through optical means. In addition, some methods, such as soil-water retention curve (SWRC), mercury intrusion porosimetry (MIP), gas adsorption (GA), and nuclear magnetic resonance (NMR,) indirectly assess the size-related information of soil pores through the pore characteristics of porous media. The targeted joint application may be selected according to varying objectives-MIP is used to obtain the main structure when studying the overall internal pores, supplemented by CT for three-dimensional remodeling; NMR is used when studying local pore damage to reflect the evolution of pore characteristics related to water storage, supplemented by SEM to support observations of surface or morphological structure damage. Finally, the direction for future development is to process the test results and transform the existing technical equipment.

The soil water retention curve (SWRC) strongly influences the hydro-mechanical properties of unsaturated soils. It plays a decisive role in geotechnical and geo-environmental applications in the vadose zone. This paper advances a novel framework to derive the water retention behavior of multimodal deformable soils based on the pore size distribution (PSD) measurements. The multiple effects of suction on the soil pore structure and total volume during SWRC tests are considered. The complete picture of soil microstructure is quantitatively described by the void ratio (for the pore volume) and a newly defined microstructural state parameter (for pore size distribution) from a probabilistic multimodal PSD model. Assuming a reversible microstructure evolution, a unique PSD surface for wetting and drying links the SWRC and PSD curves in the pore radius-suction-probability space. A closed-form water retention expression is obtained, facilitating the model's implementation in particle applications. The model is validated using the water retention data of four different soil types, showing a strong consistency between the measurement and the reproduced curve. The proposed method provides new insights into the pore structure evolution, the water retention behavior and the relationship between them for multimodal deformable soils.

This paper reports the second part of the keynote lecture, whose part I has been already published in this journal, presenting extensive experimental research on the investigation of clay microstructure and its evolution upon loading. Whether the first part focused on the micro to macro behaviour of different reconstituted clays, this part instead concerns the microscale features of the corresponding natural clays, their changes under different loading paths and the ensuing constitutive modelling implications. The experimental investigation is carried out according to the methodology outlined in the part I-paper, hence micro-scale analyses are presented on natural clays subjected to macro-scale mechanical testing, with the purpose to provide experimental evidence of the processes at the micro-scale which underlie the clay response at the macroscale. As for the reconstituted clays in the part I-paper, original results on stiff Pappadai and Lucera clay, this time in their natural state, are compared to literature results on clays of different classes, either soft or stiff. The results presented in this paper, together with those discussed in the part I, allow for a conceptual modelling of the microstructure evolution under compression of natural versus reconstituted multi-mineral clays, providing microstructural insights into the macro-behaviour described by constitutive laws and advising their mathematical formalization in the framework of either continuum mechanics or micro-mechanics.

This keynote lecture discusses the results of a long lasting experimental research, devoted to the investigation of clay microstructure and its evolution upon loading. Micro-scale analyses, involving scanning electron microscopy, image processing, mercury intrusion porosimetry and swelling paths to test the clay bonding, are presented on clays subjected to different loading paths, with the purpose of providing experimental evidence of the processes at the micro-scale which underlie the clay response at the macro-scale. Data from the literature on clays of different classes, either soft or stiff, are compared to original results on two stiff clays, Pappadai and Lucera clay, both in their natural state and after reconstitution in the laboratory. The results presented herein allow building a conceptual model of the evolution of clay microstructure upon different loading paths, providing microstructural insights into the macro-behaviour described by constitutive laws and advising their mathematical formalization in the framework of either continuum mechanics or micro-mechanics. For editorial purposes, the research results are presented in two parts. The first part, presented in this paper, concerns the results for reconstituted clays, whereas a second part, concerning the corresponding natural clays, is discussed in a second companion paper.

The mechanisms of soil failure on a microscopic scale are still not fully understood. Many soil behaviour models characterize a soil failure at the macroscopic level as single, continuous plane. Although on a microscopic scale, failure planes have a complex structure and are considered shear zones. This work aims to contribute to the microscopic analysis of the shear zones in residual soils. It describes the structures observed at the shear zones and correlates the microstructures to the macroscopic behaviour of a gneiss residual soil. The analyses interconnect the microscopic view with the stress-strain behaviour, stress path, and critical state line of the tested soil. The studied shear zone was generated in a laboratory during CAU triaxial tests. Images were obtained using a backscattered electron detector in a scanning electron microscope and subsequently subjected to digital image analysis. The variation in porosity and the degree of alignment of grains and lumps along the shear zones were evaluated. Smaller shear zones that make up a larger shear zone were also found. From the results, it was concluded that there is a strong influence of the strain level and effective confining stresses on the structure and geometry of the shear zones.

In recent years, there has been an increasing interest in investigating the use of non-traditional additives for stabilizing problematic soils. As the demand for eco-friendly alternatives to cement rises, magnesium chloride, a widely used deicer and dust suppressor, has emerged as a potential choice. This study aims to provide a comprehensive understanding of the microstructural changes that occur and affect the macro behavior of treated bentonite (B) and yellow marl (YM). To achieve this, MgCl2 solution was added to the soils at 3, 6, 9, and 12 percent by dry weight of the soil, and samples were cured for 7, 14, and 28 days at 5 degrees C, 25 degrees C, and 35 degrees C. The mechanical properties of the treated soils were then evaluated using the unconfined compression test, direct shear test, and pressure chamber test (SWCC), while microstructural analysis techniques such as X-ray diffraction (XRD), scanning electron microscopy (SEM), energy-dispersive X-ray spectrometry (EDAX), and Fourier transform infrared spectroscopy (FTIR) were employed to examine the mechanism of MgCl2 stabilization. The results indicate that adding MgCl2 and extending the curing period significantly increased both soils' unconfined compressive strength (UCS). However, the UCS value decreased for treated samples cured at temperatures higher than 25 degrees C due to an incomplete cation exchange process and the reduction of apparent cohesion. A part of the gained strength from apparent cohesion and matric suction in the unsaturated samples was lost when the samples reached full saturation during the direct shear test. Changes in the particle size, pore size, and pore void distribution due to the MgCl2 stabilization affected the SWCCs of the treated soils. Microstructural analyses revealed the formation of magnesium hydration products, such as magnesium silicate hydrate (M-S-H) and magnesium aluminate hydrate (M-A-H), which contributed to the strength increase by increasing grain size, filling the pores, binding fine particles within coarse grains, and forming a flocculated structure through recrystallization of MgCl2 and the formation of cementitious gel. Additionally, for B, adding MgCl2 led to soil flocculation through ion exchange, while for YM, the same process occurred due to the greater surface tension of the saline solution encircling the particles.

Temporal variability in the macro-mechanics and microstructure induced by periodic water fluctuations during reservoir operation is widespread but adverse for slip zone soils. Herein, taking the slip zone soils of Huangtupo No. 1 landslide in the Three Gorges Reservoir area as a research case, the consolidation undrained (CU) triaxial tests coupled with wetting-drying cycles are organized to address macroscopic temporal variability of shear strength parameters. Then, quantitative microscopic characterizations are performed based on X-ray diffraction (XRD) and scanning electron microscopy (SEM) combined with mercury compression test (MIT). Eventually, the macro and micro connections are identified via gray rational analysis (GRA) and dynamic time warping (DTW) to be thus mathematized. Moreover, the weakened constitutive model is constructed. The test results show that the temporal variability of macroscopic shear strength parameters can be quantified as negative exponential decay. The wetting-drying cycles prominently contribute to the generation of intra-agglomerate pores (0.9-35 mu m). Besides, the inter-granular pores (0.007-0.9 mu m) and porosity are the connections to bridge microstructural parameters and macroscopic shear strength parameters. Furthermore, empirical equations for macro and micro connections are tentatively derived; the temporal variability of slip zone soils is invited to appropriately model the weakening laws of stress-strain. This study is expected to provide ingenious perspectives and promising references in stability evaluation and even disaster prevention of reservoir landslides.

Antarctic soils are heavily affected by climate change in terms of properties and ecosystem functions. With increasing global temperatures, the frequency of freeze and thaw cycles of Antarctic soils will increase, thus affecting their mechanical behavior, with varying responses in erosion. This study quantitatively evaluated the effect of increasing frequency of freezing-thawing (F-T) cycles on rheological properties of four soils from the maritime Antarctica. Using an amplitude sweep test, the effects of 1, 5 and 9F-T cycles on soil micromechanics were evaluated and compared to a reference soil without F-T. These rheological parameters were determined: (i) the linear viscoelastic strain interval (LVR) (gamma LVR), (ii) the shear stress at the end of the LVR (rLVR), (iii) the maximum shear stress (rmax), (iv) the strain at the yield point (gamma YP), and (v) the storage and loss modulus at the yield point (G'YP). F-T cycles influenced soil rheological properties. Higher F-T frequency either increased or decreased gamma LVR and gamma YP, depending on the soil material. A 35% increase in rLVE occurred after one F-T cycle; however, at the fifth cycle a decrease of approximately 27% occurred, when compared to one cycle treatment, reaching similar values of no F-T. But after nine cycles, rLVE increased again by approximately 29% compared to previous treatment. The resistance and elasticity of the Antarctic soil microstructure showed great variation among the different soils, while soils with different textures behaved similarly for some rheological properties. Rheometry was confirmed as a method with little soil material consumption, however, soil rheology of Antarctic soils requires further studies to disentangle its interactions with soil chemical properties.