Land reclamation from the sea is increasingly common in coastal areas in China as its urban population continues to grow and the construction of subways in these areas becomes an effective way to alleviate transportation problems. Earth pressure balance shield (EPBS) tunneling in reclaimed lands often faces the problem of seawater erosion which can significantly affect the effectiveness of soil conditioning. To investigate the impacts, in this work, the stratum adaptability of EPBS foaming agents in seawater environments was evaluated based on a series of laboratory tests. The Atterberg limits and vane shear tests were carried out to understand the evolution characteristics of mechanical properties of clay-rich soils soaked in seawater and then conditioned with foams. The results revealed that, for the same foaming agents, the liquid limit and plastic limit of soils soaked in seawater were lower than those in deionized water due to the thinning of bound water films adsorbed on the surface of soil particles. Similarly, soils soaked in seawater had lower shear strength. In addition, the results indicated that the foam volume (FV) produced by foaming agents using seawater as the solvent was slightly higher than that when using the deionized water due to the higher hydration capacity of inorganic salt cations in seawater compared with organic substances. It was also shown that seawater had negative effects on the half-life time (T1/2) and the dynamic viscosity (eta) of foaming agents due to the neutralization reaction between anions in the foaming agents and Na+ present in seawater. The test results also confirmed that 0.5 % of the tackifier (CMC) can alleviate the issue of thin foam films caused by seawater intrusion and improve the dynamic viscosity of foaming agents more effectively, leading to superior resistance to seawater intrusion in EPBS tunnel constructions.
Microbially induced carbonate precipitation (MICP) is an eco-friendly technique for weak soil reinforcement. In this study, Sporosacina pasteurii was used to strengthen silty sand after multigradient domestication in an artificial seawater environment. The efficiency of MICP was investigated by carrying out a series of macroscopic and microscopic tests on biocemented silty sand specimens. It was found that the salt ions in seawater impacted bacterial activity. The best activity of the bacterial solution in the seawater environment was achieved after five-gradient domestication, which was approximately 8% lower than that in the deionized water environment. The significant effects of domesticated bacteria on silty sand reinforcement were demonstrated by the content of precipitated carbonate and the unconfined compressive strength (UCS) of the treated specimens. The seawater positively impacted the MICP procedure due to the roles of calcium and magnesium ions, indicated by the X-ray diffraction spectra. The scanning electron microscopy (SEM) results showed that carbonate precipitations distributed primarily on the surfaces and near the contact points of the soil particles, contributing to the soil strength. The cementation solution concentration and injection rate significantly influenced the content and distribution of carbonate precipitations and UCS of the biocemented silty sand, and the values corresponding to good reinforcement efficiency were 1.0 mol/L and 1.0 mL/min, respectively. The results of consolidated undrained triaxial tests showed that the mechanical properties of treated specimens were influenced by biocementation cycles. It was found that the stress-strain behavior of biocemented samples changed from strain hardening to strain softening when the number of reinforcement cycles increased. The peak strength of silty sand was increased by 1.9-3 times after 5 times MICP treatment. The effect of biocementation cycles on the shear strength parameters could be represented by relating the effective friction angle and effective cohesion of biocemented silty sand to the carbonate content.
Nano-SiO2, a highly acclaimed nanomaterial for enhancing cemented soil, has shown remarkable improvements in the physical properties and microstructure of cemented soil. The organic matter content in soil plays a crucial role in determining the engineering quality of cemented soil, regardless of whether it is in a freshwater or seawater environment. Therefore, when employing Nano-SiO2 as an amendment for cemented soil, it is crucial to consider the influence of different soil types and environmental conditions on the effectiveness of the enhancement. This study presents a scientific approach for enhancing the consolidation of cemented soil by incorporating Nano-SiO2 as an additive in both freshwater and seawater environments. To ensure consistency with practical construction practices, the experiments were divided into freshwater preparation and curing groups, as well as seawater preparation and curing groups. In soils with distinct characteristics, we utilized five different gradient levels of Nano-SiO(2 )additives and subjected the cemented soil specimens to a 60-day immersion curing process. Subsequently, unconfined compressive strength (UCS) tests were performed on samples that had reached the specified curing age to investigate the alterations in the mechanical properties of cemented soil caused by Nano-SiO2. The internal microstructure and chemical composition of the cemented soil were analyzed utilizing scanning electron microscopy (SEM) and X-ray diffraction (XRD), respectively. The UCS and deformation modulus of cement soil composed of silty clay A and silty clay D with low organic matter content in fresh water environment increased by 109%, 24.7% and 117%, 43% respectively after adding 3.2% Nano-SiO2; In freshwater environments, the cemented soil composed of high-organic-matter content mucky silty clay B, muddy soil C, and dredged silt E experienced respective increases of 16% and - 27%, 2% and 42%, 6% and - 6% in UCS and deformation modulus after adding 3.2% Nano-SiO2; The UCS and deformation modulus of cemented soil with high organic matter content in seawater and freshwater environment increased by 3% and 6% ( Soil B), 12% and 67% ( Soil C), 23% and 27% ( Soil E), respectively, after adding 3.2% Nano-SiO2; The increase of UCS and deformation modulus of cement soil by adding Nano-SiO(2 )is negatively correlated with the content of organic matter. in the case of cemented soil with high organic matter content in a seawater environment, the specific type of soil not only impacts UCS and deformation modulus of the soil but also influences the effectiveness of enhancement. Due to the organic matter, the rate of hydration reaction in cemented soil is reduced, resulting in a decrease in the formation of pozzolanic reaction products with SiO2. As a result, the improvement in Nano-SiO(2 )effectiveness is diminished.