This study investigates the microhardness and geometric degradation mechanisms of interfacial transition zones (ITZs) in recycled aggregate concrete (RAC) exposed to saline soil attack, focusing on the influence of supplementary cementitious materials (SCMs). Ten RAC mixtures incorporating fly ash (FA), granulated blast furnace slag (GBFS), silica fume (SF), and metakaolin (MK) at 10 %, 15 %, and 20 % replacement ratios were subjected to 180 dry-wet cycles in a 7.5 %MgSO4-7.5 %Na2SO4-5 %NaCl solution. Key results reveal that ITZ's microhardness and geometric degradation decreases with exposure depth but intensifies with prolonged dry-wet cycles. The FAGBFS synergistically enhances ITZ microhardness while minimizing geometric deterioration, with ITZ's width and porosity reduced to 67.6-69.0 mu m and 25.83 %, respectively. In contrast, FA-SF and FA-MK exacerbate microhardness degradation, increasing porosity and amplifying microcrack coalescence. FA-GBFS mitigates the diffusion-leaching of aggressive/original ions and suppresses the formation of corrosion products, thereby inhibiting the initiation and propagation of microcracks. In contrast, FA-SF and FA-MK promote the formation of ettringite/gypsum and crystallization bloedite/glauberite, which facilitates the formation of trunk-limb-twig cracks.
Alkali-activated concrete (AAC) is a focal point in green building material research due to its low carbon footprint and superior performance. This study seeks to enhance the impact resistance of recycled aggregate concrete (RAC) by elucidating the synergistic mechanisms of alkali activation, nano-modification, and fiber reinforcement. To this end, four mix designs, incorporating NaOH and NaOH-Na2SiO3 systems with 2 % nano-SiO2(NS), were developed and assessed through setting time, compressive strength, drop hammer impact tests, and XRD/ SEM analyses. The NaOH-Na2SiO3 system exhibited a 23.5 % increase in compressive strength over NaOH, achieving 28.41 MPa, while NS refined pore structures, elevating strength to 32.2 MPa; XRD/SEM analyses confirmed mechanisms of pore refinement and interfacial enhancement. In the optimized system, the NT12-C5 formulation, incorporating polypropylene fiber (PPF) and recycled carbon fiber (RCF), exhibited superior impact resistance, with NS enhancing interfacial bonding between carbon fiber and the matrix, resulting in a 47.8 % increase in initial crack impact energy. The Weibull model validated the reliability of impact performance. Furthermore, life cycle assessment revealed that Soil Solidification Rock Recycled aggregate concrete (SSRRAC) substantially reduced carbon emissions compared to ordinary Portland cement (OPC), while maintaining competitive economic costs. This study's innovations include: (1) synergistic optimization of low-carbon AAC performance using NaOH-Na2SiO3 and NS; (2) optimized PPF/RCF formulations promoting the reuse of waste carbon fiber; and (3) application of the Weibull model to overcome conventional statistical constraints. Collectively, these findings establish a theoretical and practical foundation for the global development of sustainable building materials.
Solidified soil (SS) is widely applied for resource utilization of excavated soil (ES), however the waste solidified soil (WSS) may pose environmental hazards in future because of its high pH (>10). WSS is unsuitable for landfill but can be raw materials for preparing recycled solidified soil (RSS) with better mechanical properties than SS. This investigation used OPC and alkali-activated slag (AAS) as binders to solidify ES and WSS and prepare RSS. The mechanical properties of RSS were experimentally verified to be better than SS, increased by over 76 %. The mechanism is that the clay particles in WSS have been solidified to form sand-like particles or adhere to natural sand, resulting in increasing content of sand-sized particles, and the residual clay particles undergo cation exchange under the high pH and Ca2 + content, resulting in a decrease in zeta potential, reducing diffusion layer thickness. As a result, the flowability of RSS increases under the same liquid to solid ratio. The residual unreacted binder particles and high pH in WSS are beneficial for the early and final compressive strength increase of RSS, which allows preparing RSS with lower cost and carbon emission. Finally, the utilization of WSS has significant environmental benefits.
The treatment of excavated soil using the dry sieving method to produce recycled sand is an effective approach for resource utilization. Currently, the hot-air drying process used in this method exhibits high energy consumption. To address this issue, this study proposes a microwave drying technology to dry the excavated soil. Comparative experiments on microwave (1-6 kW) and hot-air (105-205 degrees C) drying of the excavated soil were conducted. The drying behavior and specific energy consumption of the excavated soil were investigated. The Weibull-Fick combined method was recommended for the segmental determination of the effective moisture diffusion coefficient, and the question of whether microwave drying adversely affects sand particles in the excavated soil was answered. The results revealed the following: Compared with hot-air drying, microwave drying demonstrated shorter drying time (3.5-38 min vs 75-1200 min), lower specific energy consumption (6.2-11.5 MJ/kg vs 22.3-55.4 MJ/kg), and a higher range of effective moisture diffusion coefficient (10-8-10-7 m2/s vs 10-9-10-8 m2/s). With increasing microwave power (3-6 kW), the time required for complete drying of the sample was reduced by up to 56 %. Under microwave drying, relaxing the termination moisture content criterion from 0 to 0.01 resulted in a 17 %-32 % reduction in specific energy consumption, accompanied by a 24 %-36 % decrease in drying time. Microwave drying did not damage sand particles within the excavated soil.
This paper aims to enhance the effective utilization of construction solid waste renewable brick powder (RBP) and circulating fluidized bed fly ash (CFBFA), addressing the issues of resource consumption and environmental pollution associated with these two types of solid waste. It employs CFBFA to synergistically activate RBP for the preparation of solid waste-based earthwork subgrade backfill. This research examines the impact of RBP and CFBFA content on the performance of earthwork subgrade backfill (ESB), while the microstructure of the paste test block was investigated using XRD, SEM, FTIR, and TG-dTG techniques. The synergistic mechanism of multisolid waste was examined at the micro level, and the appropriate ratio of solid waste-derived lowcarbon ESB was thoroughly assessed. The findings indicate that an increase in the CFBFA content generally enhances the mechanical strength of the paste. At the experimental ratio of RBP: CFBFA: coarse-grained soil = 8: 32: 60, the 28-day unconfined compressive strength (UCS), California Bearing Ratio (CBR) value, rebound modulus value, shear strength value, and compression modulus value of the sample attain their maximums, measuring 5.3 MPa, 41.9 %, 71.9 MPa, 10.5 KPa, and 15.76 MPa, respectively, all exceeding the standard values. The hydration products of cementitious materials based on RBP and CFBFA mostly consist of C-S-H gel, ettringite (AFt), and calcite. The robust honeycomb gel structure, created by the staggered interconnection of C-S-H gel and ettringite, is the primary contributor to mechanical strength. The modified cementitious material, composed of RBP-CFBFA, exhibits effective cementation and solidification properties for heavy metals, achieving leaching concentrations that comply with Class III water standards as outlined in the Chinese standard GB/T 14848-2017.
Soft clay soils inherently exhibit low mechanical strength, imposing significant challenges for various engineering applications. The present research explores various techniques and stabilizers to enhance soft clay's suitability for construction purposes. This study evaluates the mechanism of stabilizing kaolin using recycled macro-synthetic fibers (RMSF) for the first time. Samples were prepared with 5 % LKD, with 25 % replaced by VA, and varying RMSF amounts of 0, 0.5 %, 1 %, and 1.5 % in lengths ranging from 4 to 6 mm. The specimens were cured for 7, 28, and 56 days and exposed to 0, 1, 4, and 10 freeze-thaw (F-T) cycles. Laboratory investigations were conducted through standard compaction, Unconfined Compressive Strength (UCS), Indirect Tensile Strength (ITS), Scanning Electron Microscope (SEM), California Bearing Ratio (CBR), X-ray diffraction (XRD), and Fourier Transform Infrared Spectroscopy (FTIR) tests on the samples at various stages of stabilizer addition, both before and after F-T cycles. The optimal mixture was 5 % LKD, with 25 % VA replacement and 1 % RMSF, which led to a considerable 11-fold enhancement in ITS and a 14-fold improvement in UCS compared to the untreated sample. Additionally, the secant modulus (E50) and energy absorption capacity (Eu) of the sample with the optimal combination content increased in comparison to the stabilized sample without RMSF. The CBR of the optimal sample reached 81 %, allowing for an 87 % reduction in pavement thickness compared to the untreated sample. According to the findings of this research, the combination of LKD, VA, and RMSF increased the compressive and tensile strength properties, bearing capacity, and durability of kaolin, making it an appropriate option for use in various practical civil projects like road construction.
The integration of industrial and biogenic waste materials in soil stabilization provides an environmentally sustainable alternative to conventional binders. This study evaluates the influence of mussel shell powder (MSP) on both untreated, cemented, and recycled soils, where the recycled soil was initially stabilized with calcium carbide residue, cured for one year, ground into powder, and then re-treated with MSP. Unconfined compression, ultrasonic pulse velocity, and direct shear tests were conducted to assess the strength, compaction, and shear behavior of MSP-stabilized pure, recycled, and cemented soils. The results indicate that MSP addition reduced plasticity and improved soil workability. In recycled soils, 5% MSP provided optimal strength enhancement, while in cemented soils, 20% MSP was required for significant strength gains due to its role in secondary cementation. Freeze-thaw tests demonstrated that MSP-treated soils exhibited up to a 40% reduction in strength loss compared to untreated samples, improving durability in cold climates. The ultrasonic pulse velocity measurements showed strong correlations with unconfined compressive strength, confirming its potential as a nondestructive assessment method for stabilized soils. These findings highlight the potential of MSP as a sustainable stabilizer for improving soil mechanical properties, durability, and resistance to freeze-thaw cycles.
The solidification of dredged marine sediments with high water content is important for maintenance dredging and reclamations. To reduce the carbon emission of solidification, low-carbon recycled wastes such as incinerated sewage sludge ash (ISSA) and ground granulated blastfurnace slag (GGBS) have been recently adopted as binding materials to replace conventional Portland cement. For soil slurry with ultra-high water content, using the consolidationsolidification combined method is an effective way to reduce the volume and improve the final mechanical properties. However, it is unclear how the consolidation interacts with solidification using the binding materials. In this study, a series of laboratory tests were conducted on dredged Hong Kong marine deposit slurry mixed with ISSA and GGBS with alkali activation by lime. The elemental consolidation tests controlled with different constant rates of strain and multistage loadings demonstrate that the rate of consolidation has significant effects on volume reduction and yielding stress development during consolidation-solidification treatment. Consolidationsolidification achieves higher volume reduction and yielding stress than pure solidification. As the rate of consolidation decreases, there is a smaller volume reduction at the same effective stress and less yielding stress enhancement at the same curing time. A scanning electron microscope with energy dispersive spectrometer was used to investigate hydration products and soil fabric after treatment. The slower rate of consolidation causes the looser structure and finer needleshaped products with the same curing period, which can explain the mechanical properties observed from the element tests.
The rapid depletion of natural aggregate resources has led to the exploration of recycled aggregates as sustainable alternatives. The steel industry annually generates 28 million tons of magnesia-based waste refractories (WMRs), making their incorporation into construction materials a potential strategy for resource conservation. However, WMR recycling poses a challenge because of its susceptibility to volume expansion during hydration. This study evaluated the feasibility of an environmentally friendly additive, lignosulfonate (LS), for stabilizing crushed waste magnesia refractory bricks (CWMR) to explore the potential application of WMR as construction aggregates. The swelling properties, including the free swell index (FSI) and the swell pressure (Ps), and mechanical properties including unconfined/uniaxial compressive strength (qU), shear wave velocity (VS), and thermal conductivity (lambda) of LS stabilized CWMR (CWMLS) were evaluated over different curing periods at varying LS contents (LSc). Hydration transformed CWMR from sandlike to highly plastic silt-like, resulting in a significant FSI of 250 % and Ps of 5.2 MPa. LS effectively stabilized CWMR, as indicated by decreased FSI and Ps, and enhanced qU and VS. Microscopic observation and mineralogy analyzes confirmed that LS stabilizes CWMR by adsorbing onto its surface. Stabilization of thermal conductivity at higher LSc over curing periods further supports these interactions. Macroscopic behavioral analyzes give stabilized effect of 94.3 % at LSc = 5 % with minimal improvement at higher LSc. These findings highlight LS as a promising stabilizer for mitigating hydration-induced expansion and improving the mechanical properties of CWMR, supporting its application as a recycled aggregate in construction.
The escalating environmental challenges posed by waste rubber tyres (WRTs) necessitate innovative solutions to address their detrimental effects on the geoenvironment. Thus, the knowledge about the recent advancements in material recovery from WRTs, emphasising their utilisation within the framework of the United Nations Sustainable Development Goals (SDGs) and the circular economy principles, is the need of the hour. Keeping this in mind, various techniques generally used for material recovery, viz., ambient, cryogenic, waterjet, and so on, which unveil innovative approaches to reclaiming valuable resources (viz., recycled rubber, textiles, steel wires, etc.) from WRTs and various devulcanisation techniques (viz., physical, chemical, and microbial) are elaborated in this paper. In parallel, the paper explores the utilisation of the WRTs and recovered materials, highlighting their application in geotechnical and geoenvironmental engineering development projects while addressing the necessary environmental precautions and associated environmental risks/concerns. This paper incorporates circular economy principles into WRTs utilisation and focuses on achieving SDGs by promoting resource efficiency and minimising their environmental impact.