In the exploration of the moon and outer space, our preliminary mission lies in the construction of lunar base. To make lunar concrete with local materials on the moon becomes the key technology to promote the construction of lunar bases. In order to further study the feasibility of using lunar in-situ resources to prepare concrete and build a lunar base, the environment and resources on the lunar surface are analyzed, and the severe challenges brought by extreme environment to concrete preparation and the prerequisites of in-situ resources are clarified. In this paper, the research progress of lunar concrete is summarized from the aspects of raw material acquisition, concrete preparation methods and performance, and the comparative analysis of cement concrete, sulfur concrete, geopolymer concrete and polymer concrete is carried out. Existing studies have shown that in the acquisition of raw materials, sulfur concrete has more advantages, cement concrete and geopolymer concrete are also feasible, but polymer, as a scarce resource on the moon, is difficult to obtain. In terms of preparation methods, cement concrete and geopolymer concrete are more suitable for the production of prefabricated components in artificial environment due to the limitation of external environment and the demand of water circulation, while the in-situ preparation methods represented by sulfur concrete and polymer concrete can be used for the connection and node reinforcement of prefabricated components on the moon. In terms of performance, the mechanical properties of the four kinds of concrete all meet the basic requirements, but the service performance in the harsh environment of the moon needs to be further studied. Meanwhile, the key location characteristics for lunar base construction in different regions are analyzed in terms of topography, environment and in-situ resources. Finally, the future exploration direction of the construction of the lunar bases is proposed.
Smelting used to be less efficient; therefore, wastes obtained from historical processing at smelter plants usually contain certain quantities of valuable metals. Upon the extraction of useful metal elements, metallurgical slag can be repurposed as an alternative mineral raw material in the building sector. A case study was conducted, which included an investigation of the physico-chemical, mineralogical, and microstructural properties of Pb-Zn slag found at the historic landfill near the Topilnica Veles smelter in North Macedonia. The slag was sampled using drill holes. The mineralogical and microstructural analysis revealed that Pb-Zn slag is a very complex and inhomogeneous alternative raw material with utilizable levels of metals, specifically Pb (2.3 wt.%), Zn (7.1 wt.%), and Ag (27.5 ppm). Crystalline mineral phases of wurtzite, sphalerite, galena, cerussite, akermanite, wustite, monticellite, franklinite, and zincite were identified in the analyzed samples. The slag's matrix consisted of alumino-silicates, amorphous silicates, and mixtures of spinel and silicates. Due to the economic potential of Pb, Zn, and Ag extraction, the first stage of reutilization will be to transform metal concentrates into their collective concentrate, from which the maximum amount of these crucial components can be extracted. This procedure will include combination of gravity concentration and separation techniques. The next step is to assess the Pb-Zn slag's potential applications in civil engineering, based on its mineralogical and physico-mechanical properties. Alumino-silicates present in Pb-Zn slag, which contain high concentrations of SiO2, Al2O3, CaO, and Fe2O3, are suitable for use in cementitious building composites. The goal of this research is to suggest a solution by which to close the circle of slag's reutilization in terms of zero waste principles. It is therefore critical to thoroughly investigate the material, the established methods and preparation processes, and the ways of concentrating useful components into commercial products.