This investigation examines the development of titanium slag-flue gas desulfurized gypsum-Portland cement ternary composites (the ternary composites) for the solidification and stabilization of Pb-contaminated soils. The efficacy of the ternary composites is systematically evaluated using a combination of experimental methodologies, including mechanical properties such as unconfined compressive strength, stress-strain behavior and elastic modulus, leaching toxicity, XRD, TG-DTG, FTIR, XPS, and SEM-EDS analyses. The results indicate that the mechanical properties of Portland cement solidified Pb-contaminated soils are inferior to those of Portland cement solidified Pb-free soil, both in the early and later stages. However, the mechanical properties of Pbcontaminated soils solidified by the ternary composites are superior to those of the ternary composites solidified Pb-free soils in the early stage but somewhat inferior in the later stage. The ternary composites significantly decrease the leached Pb concentrations of solidified Pb-contaminated soils, which somewhat increase with the Pb content and with the pH value decrease of the leaching agent. Moreover, with much lower carbon emissions index and strength normalized cost, the ternary composites have comparable stabilization effects on Pbcontaminated soils to Portland cement, suggesting that the ternary composites can serve as a viable alternative for the effective treatment of Pb-contaminated soils. Characterization via TG-DTG and XRD reveals that the primary hydration products of the ternary composite solidified Pb-contaminated soils include gypsum, ettringite, and calcite. Furthermore, FTIR, XPS and SEM-EDS analyses demonstrate that Pb ions are effectively adsorbed onto these hydration products and soil particles.

Cementation, even in small amounts, tends to alter the mechanical properties of soil significantly. Ordinary Portland Cement (OPC) is a widely used binding admixture, but there has been an increasing need for replacement owing to its carbon footprint. One such alternative is Calcium Sulfoaluminate cement (CSA), which has higher initial strength gain and lower carbon footprint than OPC. Since existing strength prediction models available from literature were developed for conventional cement types such as OPC and Portland Blast Furnace Cement (PBFC), those are not applicable for predicting the strength evolution of soil treated by other types of cements (e.g., underpredicting the initial strength of CSA treated sand). It is because the prediction models available are generally either soil-specific or cement-specific. This paper proposes a unified strength prediction model that works irrespective of cement and/or soil types by introducing a slope parameter that controls time-dependent strength gain. The proposed model is validated by data collected from literature on various soils and cement types. The three-parameter model demonstrates strong applicability for predicting the strength evolution over a wide range of water-to-cement ratios.

High-plasticity soils such as alluvial clay deform easily under heavy loads due to their strong plastic behavior. The tendency of these soils to expand and contract can cause deformation and cracking in structures, posing challenges in construction. To address these challenges, it's essential to improve these soils to enhance their strength and reduce plasticity before construction. Therefore, this study aims to evaluate the applicability of marble dust as a sustainable alternative to Portland cement in ground improvement applications, specifically to improve the behavior of alluvial clay. The performance of marble dust, Portland cement, and alluvial clay mixtures was evaluated using unconfined compressive strength (UCS), shear wave velocity, and mass loss due to weathering. The study tested three Portland cement contents (7, 10, and 13 %), two dry density (1.6 and 1.8 g/ cm3), and two marble dust contents (0, 10 and 20 %) across three curing ages (7, 28, and 60 days). Micro- structural analysis was performed using SEM. Results indicated a slight decrease in 7-day strength (up to 8.3 %) with 10 % marble dust replacement due to minimal pozzolanic activity, while 28-day strength loss was less significant. On the other hand, the 60-day strength increased up to 20 % upon replacing 10 % of cement with marble dust. The marble dust addition also increased the shear modulus of the soil by up to 9 % when compared with cement only. The adjusted porosity index of 0.32 correlated unconfined compressive strength (qu), initial shear modulus (G0), and accumulated loss of mass (ALM) across varying densities and blend proportions. ALM increased linearly with wet-dry cycles, with higher compaction and binder content reducing mass loss per cycle. More marble dust, however, led to greater mass loss at both curing ages, attributed to reduced cement content.

Most investigations in the literature concerning cement replacement with supplementary cementitious materials (SCMs) have predominantly focused on the utilization of fly ash and slag, which are not universally available. Laterite soil presents itself as a potential alternative to these commonly used SCMs, particularly where availability is an issue. Commonly found in tropical and subtropical regions, laterite soils have been extensively employed in building construction. Therefore, the present study aims to explore the incorporation of laterite soil calcined at 600 degrees C as a substitute for Portland cement (PC) in mortars, with the objective of producing sustainable construction materials. The effect of calcined laterite (CL) passing 75 mu m sieves as 10, 30 and 50% replacement of Portland cement (PC) on the fresh and hardened properties of mortars was investigated. Mortars were cured at room temperature, and subjected to setting time, flowability, ASR, mechanical strength, porosity, water absorption, bulk density test along with scanning electron microscopy analysis at 28 days. The obtained result revealed the reduction in mechanical properties with the incorporation of CL up to 50 wt% compared to the reference sample only used OPC. As incorporation rates of calcined increased, the flow and setting times (initial and final) values decreased from 197 to 138 mm and 156 to 24 min and 341 to 77 min, respectively.

The durability of soft soil stabilized by Portland cement -soda residue (PC -SR) subjected to dry -wet cycles remains relatively unclear now despite previous studies have extensively examined the engineering attributes of soft soil stabilized by PC -SR. Therefore, this study delineates the impacts of dry -wet cycles on the macro and micro features of soft soil stabilized by PC -SR. Based on the orthogonal test design, the unconfined compressive tests, Xray diffraction test, scanning electron microscopy, and mercury intrusion porosimetry tests were conducted to analyze the impact of dry -wet cycles on the strength, mineral components and microstructural characteristics of stabilized soil cured for 28 days. The experimental findings revealed that the strength of soil stabilized by PC -SR initially ascends and subsequently declines after dry -wet cycles. At the microscale, the tests showed that the drywet cycles transform the microstructure of stabilized soil by damaging the cementation among soil particles, expanding the pore diameter, and forming macropores and fissures. Combined with macro and micro results, it is shown that in the initial stage of the dry -wet cycle, the continuous hydration reaction promotes the increase of the microstructure density of solidified soil. However, under the continuous influence of the dry -wet cycle, the dissolution and expansion of mineral components lead to the degradation of the microstructure, which leads to the decline of the macro strength of the stabilized soil, further revealing the mechanism of the macro strength of the stabilized soil rising first and then decreasing. This study showed that Portland cement -soda residue treatment was efficient to prevent the deterioration from the dry -wet cycles.

In response to the environmental implications of the massive quantities of excavation soil generated by global urbanization and infrastructure development, recent research efforts have explored the repurposing of calcined excavation soils as sustainable supplementary cementitious materials (SCMs). As it is still at an early stage, current research lacks systematic analysis across diverse soil deposits regarding their reactivity and mechanical properties within cementitious binders, despite recognized geographical variability in kaolinite content. Through comprehensive experimentation with soils sourced from four major southern Chinese cities, this study presents a pioneering assessment of the compressive strength, pozzolanic reactivity (X-ray diffraction, Fourier-transform infrared spectroscopy, solid-state nuclear magnetic resonance), and microstructural development (mercury intrusion porosimetry, scanning electron microscopy) of mortars modified by various calcined excavation soils (up to 28 days curing). The experimental data suggest that soils with a kaolinite content above 53.39% produce mortars of equal or superior quality to plain cement mixes, primarily due to their refined pore structures, microstructural densification, and enhanced hydration reactions. The findings highlight kaolinite-specifically, aluminum content-as the principal indicator of excavation soil viability for SCM application, suggesting a promising avenue for sustainable construction practices.

The full-depth reclamation with Portland cement (FDR-PC) technology embodies an environmentally friendly approach to solving the damage to old asphalt pavement. Fatigue failure emerges as the predominant mode of degradation for FDR-PC pavement. The fatigue characteristics of the full-depth reclamation with Portland cement cold recycled mixtures were evaluated through four-point bending tests. Three contents (4%, 5%, 6%) of cement and three base-to-surface ratios (10:0, 8:2, 6:4) were utilized. The fatigue equations were derived for the mixtures using a two-parameter Weibull distribution. The results indicate that all correlation coefficients of the Weibull distribution model surpass 0.88, effectively projecting the lifespan of FDR-PC. With increases in cement contents and base-to-surface ratios, the fatigue life of the mixture extends, though with an augmentation of stress sensitivity. Comparative analysis with the fatigue equation model parameters of the current Chinese specifications for the design of highway asphalt pavement reveals that mixtures with a 4% cement content and combinations of a 5% cement content with a low base-to-surface ratio meet the requirements for inorganic-binder-stabilized soil. Additionally, mixtures with a 5% cement content and a high base-to-surface ratio, along with those with a 6% cement content, fulfill the specifications for inorganic-binder-stabilized granular materials.

It is increasingly important to find solutions for the problem of the aluminium anodising industry which generates a large amount of acid and alkaline wastewater, composed of high amounts of phosphates, sulphates, nitrates and aluminium. The sulphate removal trough ettringite precipitation is a simple process and involves a low-cost operating. The ettringite can be also formed during the cement hydration in soil-cement mixtures which causes several damages such as expansion. However, the effect of ettringite on the compressive strength, tensile strength and microstructure have few studies. This paper presents a novel experimental study on the influence of the industrial effluent treatment ettringite in resistance and microstructure of soil-cement mixtures. Experimental tests were performed using natural soil, soil mixed with 5% and 6% of cement and soil mixed with 5% and 6% of cement and ettringite for each material. The resistance of the materials was evaluated by unconfined compressive strength and indirect tensile strength, after 3, 7 and 14 days of cure. Additionally, several characterization tests and microstructure analysis were performed. Regarding the experimental results, the compressive strength and tensile strength decreases about 75% and 85%, respectively, when ettringite was added in soil-cement mixtures. The microstructure of natural soil, soil-cement and soil-cement-ettringite mixtures shows that the addition of cement and ettringite, simultaneously, increases the ettringite crystal formation mainly because the cement functions as a source of sulfate ions contributing with the formation of more crystals. Experimental results indicate that the incorporation of ettringite in soil-cement mixtures is not suitable for geotechnical applications.