The large coal production and consumption has caused environmental problems worldwide as a source of energy production with irreparable effects on soil, water, and the ecosystem. In addition, producing coal waste in coal washing plants and burying it intensifies the issue in nature. Due to the rising generation of coal waste from various sources, this study utilized several forms of coal waste obtained from a coal-washing plant in the production of both structural concrete (with a water-cement ratio of 0.54) and non-structural concrete (with a water-cement ratio of 0.7). The impact of coal waste on compressive strength (CS) was examined at curing ages of 7, 28, and 56 days. Various percentages of coal waste were substituted for both cement and sand. A superplasticizer was incorporated into the concrete mixtures to enhance the workability and achieve the desired slump and strength levels. According to the compressive strength findings, the ideal replacement level of sand with jig coal waste was 30 %. For 56-day-old specimens, the optimal substitution rates for cement with jig coal waste powder, flotation coal waste, and coal waste ash were found to be 10 %, 10 %, and 20 %, respectively. Notably, adding 10 % coal waste powder and coal waste ash increased compressive strength by 22 %, 23 %, and 44 % at 56 days.

Inverse vulcanized polymers have demonstrated significant potential as alternatives to conventional petrochemical polymers in various applications, including environmental remediation, where they are used to absorb heavy metals and pollutants from water and soil, and energy devices, such as in the development of high-capacity lithium-sulfur batteries. Despite their promise in these areas, the full application scope of these sulfur-based polymers remains unexplored. There is substantial potential for their use in other fields, such as advanced material coatings, medical devices, and as additives to improve the properties of existing polymers, yet these possibilities have not been thoroughly investigated. This study presents a sulfur-based polymer, synthesized via the inverse vulcanization of sulfur and styrene and partially crosslinked with divinylbenzene, as a novel plasticizer for polystyrene (PS). This polymer blend was prepared using an internal mixer to replace conventional organic-based plasticizers. The selected system was designed to maximize miscibility. Both virgin and plasticized PS were injection molded for comprehensive characterization. Differential Scanning Calorimetry (DSC) confirmed the complete consumption of sulfur, revealing a significant reduction in the glass transition temperature of PS upon the addition of the sulfur-based plasticizer. Morphological analysis showed a homogeneous surface with uniform single-phase morphology, indicating full miscibility of the blend. Tensile tests demonstrated enhanced ductility and reduced stiffness in plasticized PS, with strain at maximum tensile strength and elongation at break increasing by 22.0 % and 28.1 %, respectively. The plasticizer also improved the toughness of PS by 25.2 %. Rheological assessments corroborated the plasticization effect and confirmed the blend's full miscibility. Contact angle measurements indicated increased hydrophilicity of the plasticized PS samples. This newly developed sulfur-based plasticizer proved to be highly effective for PS, showcasing competitive efficiency comparable to commercial plasticizers. This advancement paves the way for new applications in the expanding field of sulfur-based polymers.

This paper focuses on the low cement content characteristic of soil slurry materials for mine reclamation, investigating the effects of three types of superplasticizers (polyester-based polycarboxylate (PCE), sodium lignosulfonate (SLS), and naphthalene-based (PNS)) on the flow properties of freshly mixed solidified soil slurry. It proposes a method combining shear rheology and micro-rheology experiments to complete the selection of superplasticizers. The rheological properties of the freshly mixed slurry were compared at different dosages of superplasticizers and various resting times. The results indicate that PCE at 0.4 % dosage exhibits the best dispersion effect in the solidified soil slurry. In-situ ATR FTIR, in-situ low-field NMR, and zeta-potential tests confirmed that PCE can effectively delay the solidification process of the soil slurry to maintain its fluidity. At a PCE dosage of 0.4 %, the spatial hindrance between slurry particles is reduced, increasing the proportion of free water in the solidified soil, with the zeta-potential not being the main factor affecting the rheological properties of the soil slurry. This study provides a theoretical foundation and solutions for regulating the early fluidity of solidified soil slurry materials used in the land reclamation of coal gangue in the Northwest mining areas of China.