Since leaving Vera Rubin ridge (VRr), the Mars Science Laboratory Curiosity rover has traversed though the phyllosilicate-bearing region, Glen Torridon, and the overlying Mg-sulfate-bearing strata, with excursions onto the Greenheugh Pediment and Amapari Marker Band. Each of these distinct geologic units were investigated using Curiosity's Mast Camera (Mastcam) multispectral instrument which is sensitive to iron-bearing phases and some hydrated minerals. We used Mastcam spectra, in combination with chemical data from Chemistry and Mineralogy, Alpha Particle X-ray Spectrometer, and Chemistry and Camera instruments, to assess the variability of rock spectra and interpret the mineralogy and diagenesis in the clay-sulfate transition and surrounding regions. We identify four new classes of rock spectra since leaving VRr; two are inherent to dusty and pyroxene-rich surfaces on the Amapari Marker Band; one is associated with the relatively young, basaltic, Greenheugh Pediment; and the last indicates areas subjected to intense aqueous alteration with an amorphous Fe-sulfate component, primarily in the clay-sulfate transition region. To constrain the Mg-sulfate detection capabilities of Mastcam and aid in the analyses of multispectral data, we also measured the spectral response of mixtures with phyllosilicates, hydrated Mg-sulfate, and basalt in the laboratory. We find that hydrated Mg-sulfates are easily masked by other materials, requiring >= 90 wt.% of hydrated Mg-sulfate to exhibit a hydration signature in Mastcam spectra, which places constraints on the abundance of hydrated Mg-sulfates along the traverse. Together, these results imply significant compositional changes along the traverse since leaving VRr, and they support the hypothesis of wet-dry cycles in the clay-sulfate transition. The clay-sulfate transition in Gale crater has long been hypothesized to record an environmental shift from warm and wet to cold and dry. The paleolake that once filled Gale crater allowed phyllosilicates to form. As Mars became cooler and drier, sulfates were able to precipitate above the phyllosilicates. This mineralogic transition has been observed in other places on Mars, implying a global environmental change. Different hydrated Mg-sulfates can reveal characteristics of the paleoenvironment at the time of deposition and thus clarify the geologic history. The goals of this study are to (a) characterize potential sulfate-bearing rocks with the Curiosity rover's multispectral imaging instrument, Mastcam; and (b) constrain Mastcam's Mg-sulfate detection threshold using laboratory techniques. We identify three new rock spectral classes inherent to the clay-sulfate transition and one new class associated with the Greeneheugh pediment. Our laboratory results indicate that it would be challenging to detect Mg-sulfate with Mastcam unless it is nearly pure. New rock spectral classes correspond to unique geologic units. One supports the hypothesis of wet-dry cycles in the clay-sulfate transition Cross instrument analyses imply that Mg- and Fe- sulfates are significant in the amorphous component of the clay-sulfate transition region The spectral signature of hydrated Mg-sulfates in visible to near infrared reflectance spectra are easily masked by phyllosilicates and/or basalt

We present reaction balancing and thermodynamic modeling based on microtextural observations and mineral chemistry, to constrain the history of phosphate crystallization within two lunar mare basalts, 10003 and 14053. Phosphates are typically found within intercumulus melt pockets (mesostasis), representing the final stages of basaltic crystallization. In addition to phosphates, these pockets typically consist of Fe-rich clinopyroxene, fayalite, plagioclase, ilmenite, SiO2, and a residual K-rich glass. Some pockets also display evidence for unmixing into two immiscible melts: A Si-K-rich and an Fe-rich liquid. In these cases, the crystallization sequence is not always clear. Despite petrologic complications associated with mesostasis pockets (e.g., unmixing), the phosphates (apatite and merrillite) within these areas have been recently used for constraining the water content in the lunar mantle. We compute mineral reaction balancing for mesostasis pockets from Apollo high-Ti basalt 10003 and high-Al basalt 14053 to suggest that their parental magmas have an H2O content of 25 +/- 10 ppm, consistent with reported estimates based on directly measured H2O abundances from these samples. Our results permit to constrain in which immiscible liquid a phosphate of interest crystallizes, and allows us to estimate the extent to which volatiles may have partitioned into other phases such as K-rich glass or surrounding clinopyroxene and plagioclase using a non-destructive method.

Self-secondaries are secondary craters that are formed on both the continuous ejecta deposits and interior of the parent crater. The possible existence of self-secondaries was proposed in the late 1960s, but their identity, formation mechanism, and importance were not revisited until the new generation of high-resolution images for the Moon have recently became available. Possible self-secondary crater populations have now been recognized not only on the Moon, but also on Mercury, Mars, 1Ceres, 4Vesta, and satellites of the ice giants. On the Moon and terrestrial planets, fragments that form self-secondaries are launched with high ejection angles via spallation during the early cratering process, so that self-secondaries can be formed both within the crater and on the continuous ejecta deposits at the end of the cratering process. Self-secondaries potentially possess profound effects on the widely used age-determination technique using crater statistics in planetary geology, because (1) self-secondaries cause nonuniform crater density across the continuous ejecta deposits, which cannot be solely explained by the effect of different target properties on crater size-frequency distributions; (2) crater chronologies for both the Moon and the other terrestrial bodies are largely based on crater counts on the continuous ejecta deposits of several young lunar craters. The effect of self-secondaries on crater chronology can be well addressed after the spatial distribution, size-frequency distribution, and density evolution of self-secondaries are resolved.