Frozen soil, covering most of the Tibetan Plateau (TP), critically influences land surface and climate simulations. Although some studies have made advancements in simulations, further investigation into the distinct mechanisms underlying relevant parameterization schemes remains essential. This study compares two frozen soil permeability schemes in Noah-MP (NY06: high-permeability; Koren99: low-permeability) to elucidate their distinct hydrological mechanisms. Although significant disparities exist in the simulation of soil water and ice content between the two schemes in permafrost regions, the simulated soil water content in the shallow layer exhibits similarity. Their underlying physical processes behind this similarity differ fundamentally: Koren99 relies on cross-seasonal ice melt recharge, whereas NY06 depends more on current-season precipitation and snowmelt. With greater soil depth, soil water differences progressively propagate downward, amplifying variations in hydraulic conductivity, and soil memory effects become increasingly dominant. Meanwhile, the Koren99 scheme more effectively impedes bottom-up melting water transport than top-down effect. However, the aforementioned disparities are not apparent in seasonally frozen soil. Notable disparities also exist in simulated evapotranspiration and surface runoff over permafrost regions, particularly during the summer months. This research investigates the differences in water transport within frozen soil over the TP, elucidates the distinct hydrological mechanisms underlying different frozen soil permeability schemes, and highlights that similar soil hydrothermal simulations are associated with different physical processes, leading to varying degrees of effectiveness in soil memory. Furthermore, this research elucidates the dual role of soil ice (permeability restriction and water storage) in hydrological processes, providing a theoretical basis for improving frozen soil parameterization.

Hydraulic conductivity plays a significant role in the evolution of liquefaction phenomena induced by seismic loading, influencing the pore water pressure buildup and dissipation, as well as the associated settlement during and after liquefaction. Experimental evidence indicates that hydraulic conductivity varies significantly during and after seismic excitation. However, most previous studies have focused on experimentally capturing soil hydraulic conductivity variations during the post-shaking phase, primarily based on the results at the stage of excess pore water pressure dissipation and consolidation of sand particles after liquefaction. This paper aims to quantify the variation of hydraulic conductivity during liquefaction, covering both the co-seismic and postshaking phases. Adopting a fully coupled solid-fluid formulation (u-p), a new back-analysis methodology is introduced which allows the direct estimation of the hydraulic conductivity of a soil deposit during liquefaction based on centrifuge data or field measurements. Data from eight well-documented free-field dynamic centrifuge tests are then analysed, revealing key characteristics of the variation of hydraulic conductivity during liquefaction. The results show that hydraulic conductivity increases rapidly at the onset of seismic shaking but gradually decreases despite high pore pressures persisting. The depicted trends are explained using the KozenyCarman equation, which highlights the combined effects of seismic shaking-induced agitation, liquefaction, and solidification on soil hydraulic conductivity during the co-seismic and post-shaking phases.

The application of coating materials to regulate nitrogen release is a crucial strategy for minimizing fertilizer loss and alleviating agricultural nitrogen pollution. However, it remains a significant challenge to develop ecofriendly coatings that are both biodegradable and effective in slow-release. In this study, Ca/Al layered double hydroxides (LDHs) were incorporated into a conventional polyvinyl alcohol/polyvinylpyrrolidone (PVA/ PVP) matrix to create PVA/PVP-LDHs composite films. The inclusion of LDHs (1.0 %, w/w) resulted in a 32 % enhancement in water resistance, a 10 % reduction in water vapor/ammonia permeability, and a 16 % improvement in mechanical properties. These enhanced performances by addition of LDHs were attributed to the combined effects of the tortuous diffusion pathways, and the formation of robust hydrogen bonding networks between the hydroxyl groups of LDHs and PVA/PVP at the organic-inorganic interface. These interactions could reduce free hydroxyl groups on the film surface, leading to hydrophobicity and structural integrity. The composite films exhibited significantly reduced nitrogen permeability under various pH conditions, indicating the improved stability in both acidic and alkaline soil environments. Degradation experiments revealed that the composite film lost 40 % of its mass over 120 days, with a half-life only 8.0 % longer than pure PVA/PVP. These results indicated that the incorporation of LDHs had minimal impact on biodegradability, maintaining the environmental compatibility of the films. These findings highlight the potential of PVA/PVP-LDHs composite films as sustainable, eco-friendly, and efficient slow-release fertilizer coatings, offering a practical solution for improving nitrogen use efficiency and reducing agricultural nitrogen pollution.

The use of nano-materials as a stabilizing agent in soils has a significant role, particularly in improving their mechanical properties. This study investigates the impact of stabilization using nano-materials, specifically nano-cement, on natural and contaminated clays. A series of laboratory tests, including Atterberg limits, compaction, unconfined compressive strength, permeability, and consolidation, are conducted to evaluate the soil properties. Various percentages of nano-cement (0 %, 0.5 %, 1 %, 1.5 %, and 2 %) are added to two sample groups; one prepared with water and the other with leachate. Based on the results of Atterberg limits tests, adding 2 % nano-cement to natural clay increases the liquid limit by 8.6 % and decreases the plasticity index by 16 %. These values diminish to 8.3 % and 13 % for contaminated clay. Furthermore, according to the compaction test results, increasing nano-cement content by up to 2 % leads to a reduction in maximum dry density by about 11.5 % and an increase in optimum moisture content by about 15.9 %. However, these values change to 5.77 % and 32.25 % for contaminated clay. The results indicate that increasing nano-cement content generally improves the strength and stiffness of the soil while reducing its permeability. On the other hand, contamination of the soil leads to a reduction in strength and stiffness, while permeability increases. Based on the Field Emission Scanning Electron Microscopy (FESEM) analysis, the incorporation of nano-cement improved the microstructure by decreasing pore spaces and enhancing bonding between particles. While chemical complexity of leachate negatively affects nano-cement dispersion, which leads to increased particle aggregation.

Compacted clays are extensively used as cover barriers to control rainfall infiltration and upward migration of greenhouse gases at municipal solid waste landfills and volatile organic compounds at industrially contaminated sites. Xanthan gum (XG) amendment offers a green and low-carbon solution to improve gas breakthrough pressure and reduce gas permeability of compacted clays, sustainably improve earthen structures. This study aimed to systematically investigate the effects of XG amendment on gas breakthrough pressure, gas permeability, and hydraulic conductivity of compacted clay liners. The gas breakthrough pressure increased from 0.6 kPa to 2.2 kPa (improve similar to 4 times) and the gas permeability decreased from 2.2 x 10(-14) m(2) to 4.8 x 10(-16) m(2) (reduce similar to 200 times) when the XG dosage increased from 0 % to 2 % and apparent degree of saturation was 100 %. Hydraulic conductivity of XG-amended soil at 1 % XG dosage was 2.6 x 10(-10) m/s, which was 3 % of the value measured in unamended soil. Mechanisms of enhanced gas barrier and hydraulic performance were interpreted by the combined effects of (i) soil pore filling substantiated by the analyses of scanning electron microscopy and pore size distribution; (ii) high viscosity of XG hydrogels, validated by the measurement of rheological properties; and (iii) increased diffuse double layer thickness of the amended soils evidenced by the zeta potential analysis.

Phosphogypsum (PG) is produced in large quantities, and its main resource utilization is in the construction sector. This study investigates the feasibility of using PG to manufacture phosphogypsum composite cement-based permeable bricks (PGCPB), focusing on the effects of aggregate size distribution, water-to-binder ratio, and slag powder (SP) content on their mechanical and durability properties and assesses the potential risks related to heavy metal content in PGCPB. The results indicate that the highest 3-day compressive strength of PGCPB is 21.1 MPa at a water-cement ratio of 0.26. The maximum 3-day compressive strength of 25.78 MPa is achieved when the fine-to-coarse aggregate ratio is 3:2. At 14 days, SEM observations reveal that incorporating 20% SP leads to an optimal crystalline microstructure and a denser matrix, corresponding to flexural and compressive strengths of 4.47 MPa and 15.25 MPa, respectively. The 14-day flexural and compressive strengths of the cementing material are 4.47 MPa and 15.25 MPa, respectively, when the SP content is 20%. With an increase in PG proportion, the 28-day compressive strength of PGCPB declines, the water permeability coefficient first rises and then falls, and its frost resistance progressively deteriorates. When PG content is 20-30%, PGCPB meets the JC/T 945-2005 permeability standard and reduces carbon emissions by 22.91% compared to conventional cement-based bricks. Environmental risk assessments confirm that PGCPB poses no risk to either soil ecology or human health, making it a safe and eco-friendly material for pavement applications.

Currently, studies on the permeability evolution characteristics of overlying aquiclude protective layers caused by coal mining focus on single lithological protective layers and assume the permeability coefficient remains constant. However, these studies fail to consider the variation characteristics of the combination protective layer structure and permeability coefficient. Therefore, an analytical method is proposed to study coal seam leakage under mining conditions in the blown-sand beach region based on the structure and permeability coefficient of the combination protective layer. First, the stress path of the overlying combination aquiclude under coal mining disturbance is comprehensively considered. Based on this, triaxial loading and unloading seepage creep experiments are conducted with different proportions of overlying combination aquiclude. The analytical relationship between the permeability coefficient of the samples and loess proportion, stress level, and soil depth in the stress recovery stage is determined, leading to the establishment of a creep permeability coefficient evolution model for the overlying combination aquiclude of the coal seam under the stress path of coal mining. Second, the creep permeability coefficient evolution model is integrated with a fusion algorithm in COMSOL numerical simulation software. Numerical simulations are then performed to examine the evolution law of phreatic leakage during coal seam mining and recovery, revealing a relationship curve in which leakage gradually decreases over time before stabilizing in the post-mining recovery stage. Finally, based on mathematical and statistical methods, a phreatic leakage evolution model is developed for both mining and post-mining stages to provide a theoretical basis for environmental protection.

This study investigates the effects of thermal treatment on the mechanical behavior of highly compressible Pak Phanang clay, a soft soil with low strength that typically requires advanced ground improvement methods. Heating is considered a promising technique for enhancing foundation stability, particularly for critical infrastructure. The research focuses on the thermo-mechanical behavior of the clay, emphasizing consolidation and solidification processes that influence load-bearing capacity. Isotropically consolidated undrained triaxial tests were conducted at temperatures of 30 degrees C, 40 degrees C, 50 degrees C, and 60 degrees C with over-consolidation ratios (OCR) of 1, 2, 4, and 8. The results showed that increasing temperature significantly enhanced both peak deviator stress (qu\documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}$${q}_{u}$$\end{document}) and the secant Young's modulus (E50\documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}$${E}_{50}$$\end{document}), with a strong linear correlation: E50=108.70xqu\documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}$${E}_{50}=108.70\times {q}_{u}$$\end{document}. Dry density increased and organic matter content slightly decreased under thermal treatment, particularly in normally consolidated clay. Excess pore water pressure (EPWP) increased linearly with temperature across all OCR values. Consolidation volume change also increased with temperature but decreased as OCR rose. The coefficient of consolidation (Cv\documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}$${C}_{v}$$\end{document}) improved with temperature, leading to faster consolidation, especially in normally consolidated specimens. The coefficient of permeability (k\documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}$$k$$\end{document}) increased with temperature but declined with higher OCR, with k rising by 14.6%-24.2% from 30 degrees C to 60 degrees C in normally consolidated samples. Predictive models for qu\documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}$${q}_{u}$$\end{document} and k\documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}$$k$$\end{document} based on temperature and OCR demonstrated high accuracy. Overall, the findings provide a reliable understanding of the thermal-mechanical response of this clay type, supporting its application in temperature-assisted ground improvement.

This experimental study is to find a solution to reduce the amount of waste and at the same time improve the geotechnical properties of fine soils. Compaction, odometer, direct shear tests, and unconfined compression tests were carried out on a clay with a very high degree of plasticity mixed with 0%, 10%, 20%, 30%, and 40% of recycled concrete aggregates (RCA). The addition of concrete aggregates to the clayey soil shows an increase in the maximum dry density and a reduction in the optimum water content. The odometer tests results showed that the increase in the recycled material content leads to a decrease in the compression index, swelling index and creep index. On the other hand, the pre-consolidation stress, the odometric modulus, the consolidation coefficient and the permeability coefficient increase with increasing RCA content. According to the direct shear test, the higher RCA content provided an improvement in shear strength which is accompanied by an increase in the dilatant character. For different curing times and for a content of 10% recycled concrete aggregate, the unconfined compressive strength increased compared to the untreated soil.

Structural damage and foundation leakage are major concerns for earthen dams. To minimize seepage, cutoff walls are typically installed beneath the dam core to act as impermeable barriers. While concrete cutoff walls are widely used, their limited ductility and strength incompatibility with foundation soil present design challenges. Plastic concrete, a modified form of conventional concrete incorporating bentonite and pond ash, offers improved ductility and reduced brittleness, making it a suitable alternative. This study investigates the use of pond ash-based flowable fill as a replacement for normal concrete in plastic concrete cutoff walls. The unconfined compressive strength (UCS) of plastic concrete mixes was analyzed using four advanced regression machine learning algorithms: multivariate adaptive regression splines, extreme neural network (ENN), extreme gradient boosting (XGBoost), and gradient boosting machine (GBM). Several performance indices were used to evaluate model accuracy. The MARS model achieved the highest accuracy, with R2 = 0.990 for training and R2 = 0.963 for testing, followed by XGBoost, GBM, and ENN. SHAP analysis revealed that curing period has the most significant positive effect on UCS, followed by water and cement contents, while bentonite showed the least impact. Key properties were evaluated to determine an optimal mix design. This research enhances the understanding of CLSM-based plastic concrete and supports its application in cutoff walls by developing accurate UCS prediction models, contributing to the improved suitability and sustainability of dam foundation systems.