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Although bioplastics and paper straws have been introduced as alternatives to single-use plastic straws, their potential environmental, economic, and social impacts have not been analyzed. This study addresses this gap by designing a polylactic acid layer interface adhesion on cellulose paper-based (PLA-P) composite straws by a dip molding process. This process is simple, efficient, and scalable for massive production. Optimizing key manufacturing parameters, including ice bath ultrasonic, overlapping paper strips (2 strips), winding angle (60 degrees), soaking time (5 min), and drying temperature (50 degrees C), were systematically evaluated to improve straw quality and manufacturing efficiency. PLA chains were found to deposit onto the cellulose network through intermolecular interactions to form a consistent sandwich structure, which can improve adhesion, water resistance, and mechanical properties. Interestingly, PLA-P straws effectively decomposed in soil and compost environments, with a 35-40 % degradation rate within 4 months. Besides, PLA-P straw residues affected seed germination and plant growth, but no significant toxic effects were detected. Further, microplastics were observed in soil and plant tissues (roots, stems, and leaves), and their possible diffusion mechanisms were explored. The results of a comprehensive life cycle assessment (LCA) and cost analysis showed that the process improvements reduced the ecological footprint of PLA-P straws and showed good prospects for commercial application. The study's findings

期刊论文 2024-12-05 DOI: 10.1016/j.jhazmat.2024.136101 ISSN: 0304-3894

Plastic-coated paper straws are insufficient to solve the plastic pollution problem because microplastics are formed during their degradation. In this study, upgraded paper straws were prepared by coating with biodegradable sodium alginate/cellulose nanofiber/stearic acid (SA/CNF/STA) on the surface of paper without additional adhesives. The tensile strength of the paper was enhanced synergistically by the coated SA and CNF after cross-linking with Ca2+ ions, reaching a maximum (26.46 MPa) when the mass ratio of SA to CNF was 4:1. The straws were prepared by spirally winding coated paper into tubes. Subsequent STA modification with different concentration (1-40%) improved the water stability of the paper straws. The paper straws exhibited excellent mechanical properties (including 13.45 MPa of flexural strength, 13.30 MPa of compressive strength) and hydrophobicity (103.67 degrees of maximum water contact angle). After 130 days of soil burial, the paper straws were completely degraded. The comprehensive performance of prepared straws exceeds that of commercially available products in the same category, and they are safe and biodegradable. Paper straw in the work is in line with the concept of green and low-carbon development.

期刊论文 2024-05-10 DOI: 10.1016/j.jclepro.2024.142243 ISSN: 0959-6526
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