Expansive soil, characterized by significant swelling-shrinkage behavior, is prone to cracking under wet-dry cycles, severely compromising engineering stability. This study combines experimental and molecular dynamics (MD) simulation approaches to systematically investigate the improvement effects and micromechanisms of polyvinyl alcohol (PVA) on expansive soil. First, direct shear tests were conducted to analyze the effects of PVA content (0 %-4 %) and moisture content (30 %-50 %) on the shear strength, cohesive force, and internal friction angle of modified soil. Results show that PVA significantly enhances soil cohesive force, with optimal improvement achieved at 3 % PVA content. Second, wet-dry cycle experiments revealed that PVA effectively suppresses crack propagation by improving tensile strength and water retention. Finally, molecular dynamics simulations uncovered the distribution of PVA between montmorillonite (MMT) layers and its influence on interfacial friction behavior. The simulations demonstrated that PVA forms hydrogen bonding networks, enhancing interlayer interactions and frictional resistance. The improved mechanical performance of PVAmodified soil is attributed to both nanoscale bonding effects and macroscale structural reinforcement. This study provides theoretical insights and technical support for expansive soil stabilization.

Clayey sand soils require improvement in civil engineering projects due to their low density, high porosity, and inadequate shear behavior. On the other hand, the extensive use of cement in soil stabilization is associated with environmental concerns such as high COQ emissions. In this study, the effect of partial replacement of cement with zeolite (up to 50 %) and the addition of polyvinyl alcohol (PVA) fibers (up to 0.8 wt%) on improving the mechanical, microstructural and environmental properties of clayey sand soil was investigated. Samples were prepared with different cement contents (3 and 6 %) and, after 7 and 28 days of curing, were subjected to compaction, unconfined compressive strength (UCS), indirect tensile strength (ITS), ultrasonic pulse velocity (UPV), scanning electron microscope (SEM), X-ray diffraction (XRD), atomic force microscopy (AFM) and toxicity characteristic leaching procedure (TCLP) tests. The compaction test results showed that maximum dry density (MDD) decreases and optimum moisture content (OMC) increases with increasing zeolite content. The performance of different mixtures showed that the optimum mixture consisted of 6 % cement, 20 % zeolite, and 0.8 % fibers, which increased UCS, ITS, and UPV by 320 %, 194 %, and 35 %, respectively, compared to unstabilized soil. Micro-structural analyses showed the formation of CSH and CAH gels and improved interfacial transition zone bonds. Also, TCLP results showed that zeolite reduced heavy metal leaching. This study, with an innovative approach, investigated the simultaneous effectiveness of zeolite, cement, and fibers and introduced the potential of the UPV method as a non-destructive method for evaluating the mechanical performance of stabilized soil.

This study presents the results of consolidated drained triaxial tests conducted to investigate the influence of various parameters on the volumetric change behavior of cemented sand reinforced with polyvinyl alcohol (PVA) fibers. The primary objective is to explore the interaction between fiber weight ratio, cement weight ratio, confining pressure, and relative density on the dilatation behavior of cemented sand reinforced with PVA fibers. PVA fibers were incorporated into dry sand-cement mixtures at weight ratios of 0.0%, 0.3%, and 0.6%. The specimens were prepared with cement content of 0%, 2%, and 4% by weight of dry sand and cured for 7 days. Two relative densities were used in specimen preparation, and triaxial compression tests were conducted under different confining pressures. The results reveal that decreasing relative density, increasing cement content, and adding fibers all contribute to a reduction in sample dilatation. Specifically, the peak dilation rate increases with higher relative density and cement content, while it decreases with higher fiber content and confining pressure. A notable aspect of this study is its investigation of how these parameters interact when combined, offering a deeper understanding of their collective effects on soil behavior.

Gels are transversal materials with key applications in multiple scientific and technological sectors, including the preservation of Cultural Heritage that is a fundamental drive for socioeconomic resilience. Recently, the new class of twin-chain (TC) polymer gel networks was developed, using freeze-thaw (FT) cycles on solutions of polyvinyl alcohol (PVA) with two different hydrolysis degree and molar mass. Taking advantage of polymerpolymer phase separation in the pre-gel solutions, a sponge-like, interconnected porosity is templated in the hydrogels during FT, which concurs to boost the cleaning capability of the gels versus soil and aged coatings that jeopardize paintings and other iconic artworks. This review covers the latest developments in this new class of gels, and their use in the conservation of works of art. The TC gels allowed time-effective restoration of masterpieces (paintings by Picasso, Pollock, Lichtenstein), which would have been risky and time-consuming with conventional restoration materials in wet cleaning. The review discusses gelation mechanisms, the partial replacement or decoration of PVA with non-toxic synthetic or bio-based polymers, the counterintuitive role of gels' tortuosity in the cleaning process, and the upload of these gels with nanostructured cleaning fluids (microemulsions, micelles). Overall, the TC PVA hydrogels constitute an advanced tool to preserve Cultural Heritage and transfer it to future generations; moreover, they represent a class of sustainable soft matter materials with potential impact in several fields, spanning from detergency to the cosmetic, pharmaceutical and food industries, tissue engineering, and others.

This research investigates the production of biodegradable films using a combination of gum odina (GO) and polyvinyl alcohol (PVA) with varied ratio. The study focuses on the chemical, physical, and mechanical properties of PVA-GO composite films, emphasizing how versatile and biodegradable they may be for a range of packaging applications. Solvent-cast PVA-GO films with different ratios are subjected to a methodical analytical process to determine several parameters like mechanical qualities, thermal stability, biodegradability in soil, contact angle, transparency, water vapor permeability, moisture content, thickness, density, water solubility, microstructure, and FTIR analysis. The outcomes demonstrate that GO improves UV barrier qualities and water vapor permeability. Additionally, the films showed notable biodegradability, acceptable thermal stability, and mechanical qualities. In short, PVA-GO films can provide an eco-friendly packing substitute with adaptable qualities fit for a range of uses. Therefore, this research may further contribute promising information in the field of biodegradable packaging materials in the future. image

Biodegradable plastics offer a promising alternative to traditional plastics in agriculture, particularly where rapid and controlled degradation is required. This study investigates the properties and degradation behavior of blends of Polybutylene Adipate Terephthalate (PBAT) and Polyvinyl Alcohol (PVA). Mechanical testing revealed that incorporating PVA significantly enhanced both tensile and flexural strengths. For example, pure PBAT had a tensile strength of 14.51 MPa, while the 20PBAT/80PVA blend achieved 53.48 MPa. However, higher PVA content led to reduced elongation at break and fracture toughness. Water immersion tests showed that PVA dissolution and PBAT degradation caused notable reductions in mechanical properties after 5 days, with blends containing 80 % PVA exhibiting an 80.1 % weight loss, and the 40PBAT/60PVA blends showing a 41.75 % weight loss after 30 days. Soil degradation experiments confirmed that the degradation rate increased with higher PVA content. These results highlight the superior degradation performance of PBAT/PVA blends and demonstrate that adjusting the PVA content effectively modulates both degradation rates and mechanical properties. This offers valuable insights for the development of environmentally friendly materials.

Adding cement to soft soils may lead to brittle behavior and the occurrence of sudden damage. Methods to further improve the tensile and flexural properties of cemented clay are noteworthy topics. This paper mainly focuses on the effect of cement and moisture content on the strength and flexural properties of cemented clay reinforced by PVA fiber. The selected clayey soil was a kaolin with cement content of 5%, 10%, and 15% and moisture content of 50%, 56%, 63%, and 70%. The results show that the incorporation of 0.6% fiber can effectively improve the deformability of cemented clay in unconfined compression tests (UCS). The strengthening effect of fiber, as seen in the peak strength and post-peak strength of UCS, was significantly related to cement content. As the water content increased, the compressive strength of the fiber-reinforced cemented clay decreased, but its load-bearing capacity enhanced. When the cement content was 15%, the splitting tensile strength of fiber-reinforced cemented specimens increased by 11% compared to cemented soil, but the deformability of the specimens became poor. In the cement-content interval from 5% to 10%, the bending toughness was significantly improved. Sufficient cement addition ensures the enhancement of PVA fibers on strength and flexural properties of cement-stabilized clayey soil.

The objective of the current study was to evaluate the feasibility of Aloe vera gel as a plasticizer and crosslinker in improving the properties of starch-polyvinyl alcohol blends that could find applications in packaging. The concentration of Aloe vera gel was varied (1%, 3%, 5% and 7% wt/wt) to produce SPA-1, SPA-3, SPA-5 and SPA-7 films, respectively. The plasticizing and crosslinking characteristics associated with Aloe vera gel had a positive influence on the mechanical properties of the films. Addition of Aloe vera gel increased the tensile strength of films from 27.45 MPa (control) to 32.98, 32.53 and 32.32, for SPA-1, SPA-3 and SPA-5 films, respectively. Among all the films, highest elongation at break (20.62%) was observed for SPA-3 films. Due to crosslinking, degree of swelling, water solubility and water vapour permeability for SPA-3 films decreased by 5.58%, 38.29% and 21.44%, respectively, compared to control films. The contact angle of the SPA-3 film significantly increased by 49.25% when compared to control samples. Scanning electron microscope images revealed compact and smooth surface microstructure of control films, and crosslinking was evident in presence of Aloe vera gel. The rate of degradation for SPA-3 films in soil after 40 days was enhanced by 32.25% compared to control films. SPA-1 and SPA-3 films were tested for use as packaging material for storage of green chillies. Chillies under unpacked conditions, in control and SPA-1 films, turned red in 3 days. Those stored in films with 3% Aloe vera gel began to change colour later (after 5 days) with no visual evidence of microbial or fungal growth. In summary, starch-polyvinyl alcohol matrix films with 3% Aloe vera gel (SPA-3) were effective as a sustainable alternative in increasing shelf life of foodstuff.

The most common ways to produce nanoparticles are through chemical and physical processes, which can be expensive and environmentally hazardous. Using plant extracts (green synthesis) as reducing and capping agents is a simple, cost-effective, and environmentally friendly method of lowering the usage of dangerous chemicals in the synthesis of metal nanoparticles. This study covers the environmentally friendly synthesis of cadmium sulphide nanoparticles (CdS NPs) using a blend of flaxseed extracts (FM), polyvinyl alcohol (PVA), and chitosan (Cs). The composites are then exposed to gamma irradiation at doses of 20 kGy and 40 kGy. UV-VIS absorption spectroscopy, SEM, HRTEM, EDX, and FTIR were used to analyse the produced nanocomposite films. UV-Vis absorption spectra showed considerable surface Plasmon resonance (SPR) bands at 396-440 nm, indicating that CdS NPs had been successfully synthesized. A progressive red shift in wavelength was noted, along with the broadening of the absorption band as the irradiation dose increased. Transmission electron microscopy pictures revealed that the generated CdS nanostructures were dispersed as spherical nanoparticles with remarkable structural homogeneity. Tensile strength and elongation measurements of the films revealed that the inclusion of CdS NPs improved their mechanical properties. The addition of CdS NPs to the current blends limits biodegradation in soil. Thermal gravimetric analysis findings showed that CdS NPs included in FM/PVA films had improved thermal stability. The antimicrobial activities of the tested films were performed against Staphylococcus aureus, Escherichia coli, and Candida albicans. The results revealed that all of the films exhibited more antibacterial activity against S. aureus than the two others, with the highest activity observed in nanocomposites with a high concentration of CdS.

Adding fibers into cement to form fiber-reinforced soil cement material can effectively enhance its physical and mechanical properties. In order to investigate the effect of fiber type and dosage on the strength of fiber-reinforced soil cement, polypropylene fibers (PPFs), polyvinyl alcohol fibers (PVAFs), and glass fibers (GFs) were blended according to the mass fraction of the mixture of cement and dry soil (0.5%, 1%, 1.5%, and 2%). Unconfined compressive strength tests, split tensile strength tests, scanning electron microscopy (SEM) tests, and mercury intrusion porosimetry (MIP) pore structure analysis tests were conducted. The results indicated that the unconfined compressive strength of the three types of fiber-reinforced soil cement peaked at a fiber dosage of 0.5%, registering 26.72 MPa, 27.49 MPa, and 27.67 MPa, respectively. The split tensile strength of all three fiber-reinforced soil cement variants reached their maximum at a 1.5% fiber dosage, recording 2.29 MPa, 2.34 MPa, and 2.27 MPa, respectively. The predominant pore sizes in all three fiber-reinforced soil cement specimens ranged from 10 nm to 100 nm. Furthermore, analysis from the perspective of energy evolution revealed that a moderate fiber dosage can minimize energy loss. This paper demonstrates that the unconfined compressive strength test, split tensile strength test, scanning electron microscopy (SEM), and mercury intrusion porosimetry (MIP) pore structure analysis offer theoretical underpinnings for the utilization of fiber-reinforced soil cement in helical pile core stiffening and broader engineering applications.