Biodegradability and eco-friendliness are the most importance topic to consider in the development of new products. Commercial hydrogels for agriculture applications are made from fully synthetic polymers, which is non-biodegradable and harmful to environment. The utilization of polysaccharide in hydrogels production has sparked the rise of biodegradable hydrogels (BHs). However, using it alone results in poor mechanical properties and very fast degradation. Therefore, combining it with other materials as a composite is necessary. This article reviewed the development of BHs in the last 5 years. Classifications, materials resources, preparation methods, biodegradability of BHs, seeds germination and plant growth performance are critically investigated. Fundamental concepts such as definitions and application methods of BHs are described. Finally, important conclusions and outlook have been mentioned at the end of this article.

Crop management techniques and sustainable agriculture offer a comprehensive farming method that incorporates social, economic, and ecological factors. Sustainable agriculture places a high priority on soil health, water efficiency, and biodiversity conservation in order to develop resilient and regenerative food systems that can feed both the current and future generations. Our goal in this review is to give a thorough overview of current developments in the use of polysaccharides as raw materials for the encapsulation of natural chemicals in nanoparticles as novel crop protection products. The search for recent research articles and latest reviews has been carried out through pubmed, google scholar, BASE as search engines. Offer cutting-edge solutions for sustainable crop management that satisfy the demands of an expanding population, comply with changing legal frameworks, and address environmental issues by encasing natural compounds inside polysaccharide-based nanoparticles. A variety of natural substances, such as essential oils, plant extracts, antimicrobials compounds and miRNA, can be included in these nanoparticles. These materials have many advantages, such as biocompatibility, biodegradability and controlled release of active compounds. Thanks to their action mechanism, they are able to mediate hormone signaling and gene expression in different plant physiological aspects, as well as enhance their tolerance to abiotic stress conditions. Sustainable agriculture can be supported by this type of treatments, correctly developing food safety through the production of non-toxic nanoparticles, low-cost industrial scale-up and the use of biodegradable materials. Polysaccharide-based nanoparticles have a wide range of uses in agriculture: they improve crop yields, encourage eco-friendly farming methods and can decrease the concentrations of active ingredient used, providing an accurate and affective dosage without damaging further species, as well as avoiding treatment resistance risks. These nanoparticles can also reduce the negative effects of chemical fertilizers and pesticides, contributing to the environmentally friendly agricultural development. Furthermore, the application of polysaccharide-based nanoparticles is consistent with the expanding trend of green and sustainable agriculture.

The issue of water and wind erosion of soil remains critically important. Polymeric materials offer a promising solution to this problem. In this study, we prepared and applied an interpolyelectrolyte complex (IPEC) composed of the biopolymers chitosan and sodium carboxymethyl cellulose (Na-CMC) for the structuring of forest sandy soils and the enhancement of the pre-sowing treatment of Scots pine (Pinus sylvestris L.) seeds. A nonstoichiometric IPEC [Chitosan]:[Na-CMC] = [3:7] was synthesized, and its composition was determined using gravimetry, turbidimetry, and rheoviscosimetry methods. Soil surface treatment with IPEC involved the sequential application of a chitosan polycation (0.006% w/w) and Na-CMC polyanion (0.02% w/w) relative to the air-dry soil weight. The prepared IPEC increased soil moisture by 77%, extended water retention time by sixfold, doubled the content of agronomically valuable soil fractions > 0.25 mm, enhanced soil resistance to water erosion by 64% and wind erosion by 81%, and improved the mechanical strength of the soil-polymer crust by 17.5 times. Additionally, IPEC application resulted in slight increases in the content of humus, mobile potassium, mobile phosphorus, ammonium nitrogen, and mineral salts in the soil while maintaining soil solution pH stability and significantly increasing nitrate nitrogen levels. The novel application technologies of biopolymers and IPEC led to a 16-25% improvement in Scots pine seed germination and seedling growth metrics.

Conventional nondegradable packaging and mulch films, after reaching the end of their use, become a major source of waste and are primarily disposed of in landfills. Accumulation of non-degradable film residues in the soil leads to diminished soil fertility, reduced crop yield, and can potentially affect humans. Application of degradable films is still limited due to the high cost, poor mechanical, and gas barrier properties of current biobased synthetic polymers. In this respect, natural polysaccharides and proteins can offer potential solutions. Having versatile functional groups, three-dimensional network structures, biodegradability, ease of processing, and the potential for surface modifications make polysaccharides and proteins excellent candidates for quality films. Besides, their low-cost availability as industrial waste/byproducts makes them cost-effective alternatives. This review paper covers the performance properties, cost assessment, and in-depth analysis of macromolecular structures of some natural polysaccharides and proteins-based films that have great potential for packaging and mulch applications. Proper dissolution of biopolymers to improve molecular interactions and entanglement, and establishment of crosslinkages to form an ordered and cohesive polymeric structure can help to obtain films with good properties. Simple aqueous-based film formulation techniques and utilization of waste/byproducts can stimulate the adoption of affordable biobased films on a large-scale.