To address the material requirements for grouting reinforcement in fine sand strata, a novel silicate-modified polymer two-component grouting material was designed. In this material, the traditional organic polyol component of the two-component polymer was replaced with an inorganic silicate (water glass) component, along with the addition of tertiary amine catalysts, organotin catalysts, water. The response surface methodology (RSM) was used to statistically predict the performance of the modified polymer grouting material. The effects of four parameters (two-component mass ratio, tertiary amine catalyst content, organotin catalyst content, and water content) and their interactions on response variables (gelation time, polymer solids strength, cemented body strength) were investigated. Based on a comprehensive consideration of various performance requirements for grouting materials in loose fine sand strata, multi-objective optimization was employed to determine the optimal formulation of the modified polymer grouting material (A/B ratio of 0.85, tertiary amine catalyst at 2.48 %, organotin catalyst at 0.63 %, and water at 1.87 %). A series of experimental tests were conducted to evaluate the material properties of the optimal formulation, and its mechanical performance and microstructural characteristics were compared with those of traditional polymer grouting materials to verify the proposed formation mechanism of the modified polymer. The results demonstrated that the proposed design method effectively determines the optimal grouting material formulation. The optimized modified polymer grouting material exhibited excellent comprehensive performance. Finally, the optimized modified polymer grouting material was applied in a pavement repair project on a of a highway. After grouting, the structural layer's uniform integrity was significantly restored, the damaged areas were effectively repaired, the modified polymer slurry showed good diffusion, and the repair effect was satisfactory, meeting the engineering requirements for grouting in loose fine sand strata.

A critical investigation of three constitutive models for clay by means of analyses of a sophisticated laboratory testing program and of centrifuge tests on monopiles in clay subjected to (cyclic) lateral loading is presented. Constitutive models of varying complexity, namely the basic Modified Cam Clay model, the hypoplastic model with Intergranular Strain (known as Clay hypoplasticity model) and the more recently proposed anisotropic visco-ISA model, are considered. From the simulations of the centrifuge tests with monotonic loading it is concluded that all three constitutive models give satisfactory results if a proper calibration of constitutive model parameters and proper initialisation of state variables is ensured. In the case of cyclic loading, the AVISA model is found to perform superior to the hypoplastic model with Intergranular Strain.

Alkali-activated materials have gained increasing popularity in the field of soil barrier materials due to their high strength and low environmental impact. However, barrier materials made from alkali-activated materials still suffer from long setting times and poor barrier performance in acidic, alkaline, and saline environments, which hinders the sustainable development of green alkali-activated materials. Herein, coconut shell biochar, sodium silicate-based adhesives, and polyether polyol/polypropylene polymers were used for multi-stage material modification. The modified materials were evaluated for barrier performance, rapid formation, and resistance to acidic, alkaline, and saline environments, using metrics such as compressive strength, permeability, mass loss, and VOC diffusion efficiency. The results indicated that adhesive modification reduced the material's setting time from 72 to 12 h. Polymer modification improved resistance to corrosion by 15-20%. The biochar-containing multi-stage modified materials achieved VOC diffusion barrier efficiency of over 99% in both normal and corrosive conditions. These improvements are attributed to the adhesive accelerating calcium silicate hydration and forming strength-enhancing compounds, the polymer providing corrosion resistance, and biochar enhancing the volatile organic compounds (VOC) barrier properties. The combined modification yielded a highly effective multi-stage green barrier material suitable for rapid barrier formation and corrosion protection. These findings contribute to evaluating multi-level modified barrier materials' effectiveness and potential benefits in this field and provide new insights for the development of modified, green, and efficient alkali-activated barrier materials, promoting the green and sustainable development of soil pollution control technologies.

Upon completing large-area layered filling, the foundation soil exhibits transverse isotropy and is predominantly. unsaturated, making post-construction settlement prediction challenging. Additionally, the creep model considering transverse isotropy and unsaturated characteristics has not been proposed. Therefore, the true triaxial apparatus for unsaturated soil was enhanced, and transversely isotropic unsaturated loess samples were prepared. The relationship between matrix suction and moisture content at various depths in transversely isotropic unsaturated loess was determined using soil-water characteristic curve tests. The creep characteristics of loess fill under varying moisture content, degree of compaction, deviatoric stress, and net confining pressure were examined using a consolidation drainage test system. According to the creep curve, the expressions for six parameters in the modified Burgers element model were determined, establishing a post-construction settlement prediction method for transversely isotropic unsaturated loess fill foundations. The results show that the transversely isotropic unsaturated loess exhibits distinet creep characteristics, primarily nonlinear attenuation creep. The degree of compaction, moisture content, deviatoric stress and net confining pressure significantly affect its creep characteristics. Creep stability strain is linearly related to the degree of compaction. Enhancing soil compaction can effectively reduce post-construction settlement of the fill foundation. A prediction algorithm based on the modified Burgers model, which reflects the influence of degree of compaction, moisture content, and stress level, and accurately describes the post-construction settlement behavior of transversely isotropic unsaturated loess fill foundations, is established. Actual engineering monitoring results demonstrate that the proposed settlement prediction algorithm is simple, practical, and effective. The research results can enrich and advance the creep model of unsaturated soil, and provide a scientific basis for solving the problem of deformation calculation of high fill foundation.

This study evaluated the physiological responses, hormonal signaling, osmotic and nutrient levels, as well as the performance of essential oils, antioxidant enzymes, and secondary metabolites in Lavender plants subjected to chromium and fluoride toxicity and biochar application. The findings indicated that the administration of raw and especially multiple-chemical engineered biochars decreased fluoride (about 16-40%) and chromium (39-60%) levels in Lavender leaves, whereas raised CEC and soil pH, nitrogen (10-37%), potassium (20-47%), phosphorus (10-60%), magnesium (30-49%), calcium (20-50%), zinc (39-240%), iron (40-120%), plant biomass, and photosynthetic pigments of Lavender plant leaves under toxic fluoride and chromium conditions. The treatments with multiple-chemical engineered biochars decreased the osmotic stress and osmolyte concentration (carbohydrates, soluble proteins, and proline) in the leaves of Lavender plants. Both raw and multiple-chemical engineered biochars significantly enhanced the water content of plant leaves, reaching up to 10% under toxic circumstances. Moreover, these treatments decreased the synthesis of stress hormones such as jasmonic acid (4-17%), salicylic acid (29-49%), and abscisic acid (30-66%), while increasing the production of Indole-3-acetic acid (IAA) (15-29%) in Lavender plants subjected to chromium and fluoride stress. The use of multiple-chemical engineered biochars showed notable efficacy in enhancing antioxidant enzyme's activity against oxidative damage induced by metal toxicity and decreasing proline accumulation. Maximum concentrations of linalyl acetate, borneol, camphor, and linalool were achieved under fluoride and chromium stress conditions by metaphosphoric acid-engineered biochar. Multiple-chemical engineered biochars application can be inferred as valuable approach to enhance both the quality and quantity of lavender essential oil under conditions of fluoride and chromium-induced stress.

Accurate characterization of soil dynamic response is paramount for geotechnical and protective engineering. However, the impact properties of unsaturated cohesive soil have not been well characterized due to lack of sufficient research. For this purpose, impact tests using the Split Hopkinson Pressure Bar (SHPB) were elaborately designed to investigate the dynamic stress-strain response of unsaturated clay with strain rates of 204 similar to 590 s(-1). As the strain rate increased up to 500 s(-1), a lock-up behavior was observed in the plastic flow stage, which can be explained as the breakage and rearrangement of soil gains under a high level of stress. Further, the strain rate dependency of the dynamic strength was quantitatively characterized by the Cowper Symonds (CS) model and the CS coefficients were determined to be the intercept of 55 and slope of 0.8 in the double logarithmic scale of Dynamic Increase Factor (DIF) and strain rate space. Furthermore, the SHPB test was reproduced using a modified Material Particle Method (MPM), which involves an improved dynamic constitutive model for unsaturated soil considering the strain rate effect. The simulated stress-strain curves basically agree with the experimental results, indicating the feasibility of MPM for investigating the dynamic properties of unsaturated soil under SHPB impact loading.

Addressing the current issues of poor resource utilization of waste fibers and ineffective vacuum preloading reinforcement for dredger fill, we developed a modified fiber plastic drainage plate based on the modification treatment of waste fibers. Using gradient ratio tests and indoor vacuum preloading model tests, we compared and analyzed the clogging characteristics of various modified fiber filter membranes, as well as the effects and patterns of vacuum preloading using different types of drainage plates on soft soils. The results show that the anti-clogging effect of the modified fiber filter membrane with a pore size of more than 119 mu m is better. The modified fiber drainage plate is superior to the ordinary split-type plastic drainage plate in terms of settlement, water output, vacuum degree, pore water pressure, soil moisture content, and vane shear strength. The drainage plate with a filter membrane pore size of 119 mu m exhibits the best reinforcement effect. Compared to the ordinary split-type plastic drainage plate, it has a lower cost, reduces moisture content by an average of 6.4%, and increases vane shear strength by an average of 7.8 kPa. This fully demonstrates that the modified fiber drainage plate not only provides excellent reinforcement in engineering applications but also reduces costs, aligning with the national goals for infrastructure construction and economic green sustainable development.

Localized rock failures, like cracks or shear bands, demand specific attention in modeling for solids and structures. This is due to the uncertainty of conventional continuum-based mechanical models when localized inelastic deformation has emerged. In such scenarios, as macroscopic inelastic reactions are primarily influenced by deformation and microstructural alterations within the localized area, internal variables that signify these microstructural changes should be established within this zone. Thus, localized deformation characteristics of rocks are studied here by the preset angle shear experiment. A method based on shear displacement and shear stress differences is proposed to identify the compaction, yielding, and residual points for enhancing the model's effectiveness and minimizing subjective influences. Next, a mechanical model for the localized shear band is depicted as an elasto-plastic model outlining the stress-displacement relation across both sides of the shear band. Incorporating damage theory and an elasto-plastic model, a proposed damage model is introduced to replicate shear stressdisplacement responses and localized damage evolution in intact rocks experiencing shear failure. Subsequently, a novel nonlinear mathematical model based on modified logistic growth theory is proposed for depicting the shear band's damage evolution pattern. Thereafter, an innovative damage model is proposed to effectively encompass diverse rock material behaviors, including elasticity, plasticity, and softening behaviors. Ultimately, the effects of the preset angles, temperature, normal stresses and the residual shear strength are carefully discussed. This discovery enhances rock research in the proposed damage model, particularly regarding shear failure mode. (c) 2025 Institute of Rock and Soil Mechanics, Chinese Academy of Sciences. Published by Elsevier B.V. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/

Roadbed engineering in alpine tundra environment is prone to frost heave and thaw settlement, cracking of pavement, uneven settlement, and other challenges under the action of seasonal freeze-thaw cycle. Wicking geotextile has important application value in frost damage control of roadbeds, but solar radiation, especially ultraviolet radiation, is one of the main factors leading to premature failure of wicking geotextile. In this study, different kinds of ultraviolet-resistant wicking fibers were developed by blending modification technology, and the various types of fibers were compared with each other in terms of their physical and mechanical properties, so as to obtain the optimal modified wicking fibers with the content of 2 % UV-1164 + 0.3 % B900 addition. Subsequently, a 20-day accelerated aging test was conducted on modified wicking geotextiles. The inhibitory effect of the modification treatment on the wicking geotextile indicating photo-oxidative aging was characterized by scanning electron microscope, and the effect on the mechanical properties maintenance of the wicking geotextile was characterized by tensile strength and top-breaking strength tests. Finally, a soil column drainage test was designed and carried out, based on which the horizontal hydraulic conductivity rate and 120-h drainage volume of wicking geotextiles before and after the modified treatment were predicted under the aging cycle of 40 d. The test and prediction dates showed that the hydraulic conductivity was deteriorated with the aging time, but the modification treatment could obviously inhibit the deterioration degree. Compared with the control group, the hydraulic conductivity of the modified wicking geotextile increased by about 0.35E-5 g/s, and the drainage capacity increased by 0.76 % at 200 h.

Insufficient hydrophobicity and mechanical properties pose significant challenges in the development of starchbased degradable films. This study prepared modified (crosslinked, acetylated, and crosslinked & acetylated) cassava starch films, and different concentrations of strengthening agents (polyvinyl alcohol, sodium alginate, gelatin, and hyaluronic acid) were added to produce modified starch composite films. The physical properties, structure characteristics, and degradability of these films were systematically evaluated. The dual-modified (crosslinked & acetylated) starch film exhibited superior hydrophobic properties (contact angle = 90.04 degrees), and the addition of strengthening agents significantly enhanced the tensile strength of the composite films (p < 0.05). Fourier transform infrared spectra confirmed that the strengthening agents interacted with starch through hydrogen bonding. Additionally, the hyaluronic acid-starch composite film exhibited the most rapid degradation in soil (53 % weight loss after 30 days of storage) and achieved the highest comprehensive score for physical properties. This film combined exceptional hydrophobicity and mechanical properties, making it an ideal candidate for food packaging applications. These findings suggest that the hyaluronic acid-starch composite film has broad potential applications in the field of degradable food packaging films.