A significant amount of open-pit-mine broken sandstone (OMBS) is produced during open-pit mining. The mechanical strength of the loose sandstone is critical for ensuring dump slope stability and sustainable mine construction. This study investigates the modification of OMBS using artemisia sphaerocephala krasch (ASK) gum to enhance its engineering properties. Unconfined compressive strength, shear strength and permeability tests were conducted to quantitatively analyze the modification effect. And the stability was evaluated using FLAC3D simulation methods. The modification mechanism was characterized through SEM, FT-IR, XRD. The results demonstrated that the addition of 2 % ASK gum significantly improved OMBS mechanical performance and reduced permeability. Meanwhile, the failure mode of OMBS changed with the ASK gum content increasing. The simulation result indicated the stability of modified dump slope was better under the drying-wetting cycle. From the perspective of microstructure and chemical characteristics, the addition of ASK gum created new hydrogen bonds through intermolecular interactions with the hydrophilic groups between OMBS particles and formed a dense and stable structure through three reinforcement modes: surface encapsulation, pore filling, and bonding connection. This study provides a new idea for resource saving and environmentally friendly mining area development.

A two-lift gradient design for airport pavements has been proposed to mitigate the functional degradation, especially the salt-frost (S-F) damage induced by deicing slat fluids. Herein, this study focuses on elucidating the mechanism and improvement of incorporating mineral admixtures in the development of a novel S-F resistant surface concrete material, which is of great significance for delaying the functional deterioration of pavement surface in northern China. The results indicated that the filling effect and secondary hydration reaction between the fly ash (FA) and silica fume (SF) and cement hydration products results in a dense spatial network structure, effectively reducing porosity and optimizing pore structure. It was found that SF can effectively improve the frost resistance and salt corrosion resistance of cement mortar, while the influence of FA depends on its content and environmental conditions. The incorporation of FA and SF significantly enhanced the structural density of cement concrete and reduced chloride ion permeability. The improvement in impermeability is most pronounced when both FA and SF are used in combination. In addition, a fitting equation between the admixture content and chloride ion permeability has been established, demonstrating good fitting results. In non-frozen saline soil areas, a large amount of FA or SF could be incorporated; in seasonally frozen areas, the priority should be given to SF to ensure salt corrosion resistance and frost resistance. The findings of this study provide a scientific basis for sustainable airport pavement construction in northern China.

The large amount of slag generated during the construction of earth pressure balance shield (EPBS) not only incurs significant disposal costs, but also exacerbates environmental pollution. To improve the utilization of the shield slag, silty clay with additive is proposed as a slag conditioner instead of bentonite. Firstly, various macroscopic properties of the bentonite and silty clay slurries are tested. Subsequently, the relationships between the macroscopic properties of the silty clay slurries containing additives and the modification mechanism are evaluated at microscopic, mesoscopic, and macroscopic scales by using infrared spectroscopy (IR), scanning electron microscope (SEM), and Zeta potential tests, respectively. Based on these tests, reasons for variations in modification effects of different slurries are identified. The results show that addition of 3 % sodium carbonate to the silty clay can effectively improve the rheological properties of the slurry. The modification mechanism of sodium carbonate involves the formation of hydrogen bonds between water molecules and inner surface hydroxyl groups within the lattice layer of kaolinite. This process significantly enhances the rheological properties of the silty clay slurry. Furthermore, sodium carbonate alters the contact relationships between the silty clay particles, which increases viscosity and reduces permeability of the slurry. Finally, sodium carbonate increases thickness of the electrical double layer of the silty clay particles. This allows the particles to bind more water molecules, therefore improving slurry-making capacity of the silty clay. This paper presents an innovative multiscale analysis of the modification process of silty clay. The substitution of recycled silty clay for bentonite as a slag conditioner not only substantially reduces the cost of purchasing materials, but also considerably decreases the expenses associated with transportation and disposal of the soil discharged by EPBS.

Environmental issues caused by plastic films promote the development of biodegradability packaging materials. Copper ion-modified nanocellulose films were prepared through a one-pot reaction and systematically investigated their structural characteristics, thermal stability, mechanical properties, antibacterial activity, and biodegradability. The results indicate that the film prepared by co-soaking CNCs and copper in NaOH solution for 12 h has favorable performance. Introduction of copper ions as crosslinkers increases tensile strength of film from 36.8 MPa to 56.4 MPa and water contact angle of film from 46 degrees to 92 degrees. Copper coordination also endows the film excellent antibacterial activity, inhibiting growth of Escherichia coli and Staphylococcus aureus. Moreover, biodegradability tests indicate that although the introduction of copper ions slightly reduce biodegradation rate of films, they could still be decomposed significantly within four weeks as burying in soil. This simple process for preparing cellulosic films with water resistance, thermal stable, antibacterial ability, and biodegradable shows potential application in flexible packaging film.

Tobacco is one of China's key economic crops, known for its wide distribution, high yield, and renewability. Tobacco stalk fibers (TSFs) share a similar chemical composition to wood fibers, making them a potential reinforcement for plant fiber composites. However, the waste tobacco stalk fibers raw material utilization rate is very low, and wasteful phenomenon is very serious. In this study, we prepared biodegradable TSF/PBAT composites using waste tobacco stalk fibers and polybutylene adipate-co-terephthalate (PBAT) through melt blending and injection molding techniques. The effects of different modifiers on the performance of the composites were systematically investigated, with a particular focus on their influence on the degradation behavior. The results showed that the waste tobacco straw fiber can be used as a reinforcing fiber for PBAT. The addition of modifiers significantly improved the mechanical properties of the composites and effectively slowed down the degradation rate in the soil environment. Among the modifiers, the combined use of maleic anhydride (MA) and hydroxylated multi-walled carbon nanotubes (OM) produced the best results, with the tensile strength and flexural strength of the composite reaching 17.3 MPa and 28.0 MPa, respectively-representing increases of 74.7% and 57.3% compared to the untreated composite. After 16 weeks of soil degradation, the mass loss rate of the MA/OM-modified composite decreased from 10.50 to 6.34%. This study provides a comprehensive exploration of the entire lifecycle of TSF-reinforced PBAT composites and offers important theoretical support for the resource utilization and value-added application of waste tobacco stalks in the field of green composite materials.

To enhance the mechanical properties and water resistance of chitosan (CS) films while imparting additional functionalities, this study incorporated a hydrophobic deep eutectic solvent (DES) composed of menthol and pyruvic acid into the CS matrix. At an optimal DES content of 15 %, compared to pure CS films, the elongation at break increased by 77 %, while swelling degree and solubility decreased by 94.44 % and 60.71 %, respectively. The lowest water vapor permeability (11.55 x 10-11 g & sdot;m- 1 & sdot;s- 1 & sdot;Pa- 1) demonstrated enhanced moisture barrier properties. These improvements were attributed to the synergistic effects of hydrogen bonding and ionic crosslinking, reinforcing the network structure and restricting water penetration while maintaining molecular mobility. The films also exhibited excellent ultraviolet-shielding (ultraviolet C transmittance of 3 %) with high transparency, making them suitable for light-sensitive packaging. Additionally, they achieved complete biodegradation in soil within 10 weeks, highlighting their potential as sustainable alternatives to petroleumbased plastics. This study presents a novel approach to enhancing bio-based packaging materials through hydrophobic DES, expanding their applications in sustainable food and pharmaceutical packaging.

Expanded Polystyrene (EPS) granular lightweight soil (ELS) is an eco-friendly material made of EPS particles, cement, soil, and water. This study investigates the modification of ELS using a silane coupling agent (SCA) solution to improve its performance. Various tests were performed, including flowability, dry shrinkage, unconfined compressive strength (UCS), triaxial, hollow torsional shear, and scanning electron microscopy (SEM) analysis, to evaluate the physical and mechanical properties at different SCA concentrations. The results show that the optimal SCA concentration was 6%, improving flowability by 13% and increasing dry shrinkage weight by 4%. The UCS increased with SCA concentration, reaching 266 and 361 kPa after 7 and 28 days, respectively, at 6% SCA. Triaxial and shear tests indicated improved shear strength, with the maximum shear strength reaching 500 kPa, internal friction angle rising by 4%, and cohesion reaching 114 kPa at 6% SCA. Hollow torsion shear tests showed that 6% SCA enhanced stiffness and resistance to deformation, while reducing the non-coaxial effect. SEM analysis revealed that SCA strengthened the bond between EPS particles and the cement matrix, improving the interfacial bond. This study highlights the potential of modified ELS for sustainable construction.

The construction of high-speed railway in Southwest China must traverse extensive regions of red mudstone. However, due to the humid subtropical monsoon climate in Southwest region, the red mudstone is often exposed to a high-water content or saturated state for extended time, and the poor mechanical properties under such condition cannot satisfy the requirements of high-speed railway subgrade. This paper proposes the use of lime and cement to improve the saturated unconfined compression strength (UCS) of the red mudstone fill material. Comprehensive tests, including UCS tests and scanning electron microscopy, were conducted on cement-lime modified red mudstone. Results show that lime stabilisation can significantly enhance the UCS and elastic modulus with the increase of dry density and modifier content. For the specimens with 4% lime and 6% cement, both peak strength and elastic modulus of the modified samples are more than 10 times higher than those of the untreated ones. The modulus exhibits nonlinear degradation with the development of shear stress, but the degradation can be improved with the increase of dry density and modifier content. At 60% of initial tangent modulus, the corresponding stress for untreated soil, lime stabilised and cement-lime modified filler are 0.74, 0.92 and 0.99. As for the energy evolution, the increasing dry density can enhance elastic and dissipated energies through denser particle arrangements, while a higher modifier content raises total energy. When the cement content is 6%, the total energy is more than 8 times higher than that of the untreated material, reflecting increased brittleness to a sudden fracture. The improvements are attributed to the formation of acicular and platy hydration products, which can tighten the pore structure. The study underscores the importance of lime and cement in ensuring subgrade stability for high-speed railways in Southwest China's red bed regions.

Soil stabilizers are environmentally friendly engineering materials that enable efficient utilization of local soil-water resources. The application of nano-modified stabilizers to reinforce loess can effectively enhance the microscopic interfacial structure and improve the macroscopic mechanical properties of soil. This study employed nano-SiO2 and nano-CaCO3 to modify cement-based soil stabilizers, investigating the enhancement mechanisms of nanomaterials on stabilizer performance through compressive and flexural strength tests combined with microscopic analyses, including SEM, XRD, and FT-IR. The key findings are as follows: (1) Comparative analysis of mortar specimen strength under identical conditions revealed that nano-SiO2 generally demonstrated superior mechanical enhancement compared to nano-CaCO3 across various curing ages (1-3% dosage). At 1% dosage, the compressive strength of both modified stabilizers increased with curing duration. Early-stage strength differences (3 days) remained below 3% but showed a significant divergence with prolonged curing: nano-SiO2 groups exhibited 10.3%, 11.3%, and 7.2% higher compressive strengths than nano-CaCO3 at 7, 14, and 28 days, respectively. (2) The strength enhancement effect of nano-SiO2 on MBER soil stabilizer followed a parabolic trend within 1-3% dosage range, peaking at 2.5% with over 15% strength improvement. (3) The exceptional performance of nano-SiO2 originates from its high reactivity and ultrafine particle characteristics, which induce nano-catalytic hydration effects and demonstrate strong pozzolanic activity. These properties accelerate hydration processes while promoting the formation of interlocking C-S-H gels and hexagonal prismatic AFt crystals, ultimately creating a robust three-dimensional network that optimizes interfacial structure and significantly enhances strength characteristics across curing periods. These findings provide scientific support for the performance optimization of soil stabilizers and their sustainable applications in eco-construction practices.

Complex adverse weather conditions such as rain erosion and frost are frequently encountered in practical construction projects, particularly in the Inner Mongolian region of China. In this study, a new biopolymer (GGPAM) with an interpenetrating crosslinked network structure was developed by chemically modifying GG to address the poor resistance of soil to rainwater erosion, frost, and other complex environmental conditions in open-air construction buildings. First, GG-PAM was synthesized by chemically modifying guar gum (GG) through graft copolymerization, and thermogravimetric (TG) analysis confirmed its favorable thermal stability. Subsequently, experiments were conducted to investigate the mechanical properties and microstructural characteristics of GG-PAM-solidified soil. Then, using GG as a control, dry-wet cycle and freeze-thaw cycling tests were performed to compare the changes in unconfined compressive strength (UCS) of GG- and GG-PAM-solidified soil. Finally, water erosion, crack propagation, and permeability tests were conducted to evaluate the resistance of GG-PAM-solidified soil to external forces. The results indicated that the mechanical strength, durability, and erosion resistance of the GG-PAM-solidified soil were significantly superior to those of GG. When the GG-PAM content reaches 1 %, both the mechanical strength and erosion resistance of the solidified soil are significantly improved. These findings provide a theoretical basis for the construction and maintenance of roadbeds.