Infrastructure construction on coastal areas such as ports, bridges and airports require ground improvements when marine soils contain soft ground which includes fine grains in general. Fine-grained soils consist of clastic or non-clastic grains. Based on the mineralogy of soils, compressibility of soils shows different behavior. Fine-grained clay mineral soils show plastic and time-dependent deformation due to consolidation during constructions while silty soils without clay minerals show low compressibility. However, biogenic soils such as diatomaceous earth are more compressible than other silty fine-grained soils. Although fine-grained soils with clastic minerals and biogenic minerals are classified as silt, the behavior of clastic soils are less compressible compared to biogenic soils which have inner pores. We conducted one-dimensional consolidation experiments to investigate compressibility of diatomaceous earth and non-plastic mineral fines such as silica silt. The coefficient of consolidation, and volumetric compressibility are estimated, and show that the trends of diatomaceous earth properties are different from other silty soil properties based on the consolidation tests. We found that particle breakage plays a crucial role in compressibility of diatomaceous soils. While the compressibility of diatomaceous soils is similar to clastic soils at low stress, the differences in compressional behavior between two soils are distinct at high stress. The diatomaceous earth shows time-dependent compressibility due to creep or secondary compression by particle breakage process. Thus, settlement analysis should include the impact of morphology and mineralogy of fine-grained soils.
Most Pb/Zn smelter contaminated sites in China are often encountered natural phenomenon known as freeze-thaw (F-T) cycles and acid rain. However, the coupled effects of F-T cycles and acidification on the release behavior of potentially toxic elements (PTEs) from soils remains unclear. A mechanistic study on PTEs release from soils was conducted by revealing the physicochemical weathering characteristics of minerals under F-T cycles combined with acidification. The results from F-T test indicated that among F-T parameters, F-T frequency were the more important factors influencing PTEs release, with the corresponding contribution ranges of 21.20-94.40 %. As pH decreased, the leaching concentrations of As, Cd, Cu, Mn, Pb and Zn did not increase under the same F-T frequency. As F-T frequency increased, the leaching concentrations of these studied PTEs also did not increase under the same pH condition. Microstructure characteristics revealed that the soils were a complex system with multi-mineral aggregates, which had experienced complex physicochemical weathering after F-T combined with acidification treatment. Combined with geochemical modeling results, PTEs release was found to be mainly influenced by the microstructure damage and proton corrosion of minerals, while little affected by their precipitation and dissolution. The mutual coupling relationships of mineral weathering and PTEs release were conducive to the better understanding of the migration behavior of PTEs in contaminated sites under complex environment scenarios. The present study results would provide theoretical instruction and technical support for the longevity evaluation of multi-metal stabilization remediation.
Over the past decade, there have been 45 tailings storage facility (TSF) disasters worldwide resulting in fatalities, serious environmental damage, and the destruction of entire ecosystems. These failures often stem from substandard design or operational practices. Many TSFs are constructed in regions associated with intrusive mafic rocks such as gabbro, norite, pyroxenite, and anorthosite, which are commonly found alongside platinum group metals in areas like the Bushveld Igneous Complex in South Africa and the Great Dyke in Zimbabwe. The stability of these structures can be significantly influenced by the residual soils present at the construction sites. Residual soils, both cohesive and non-cohesive, contain varying quantities of different minerals, which can impact the compaction characteristics and, consequently, the stability of the TSF foundations. Cohesive soils rich in clay minerals, such as kaolinite and smectite, exhibit properties that can hinder effective soil compaction. The expansive nature of smectite due to its ability to absorb large amounts of water and host free exchangeable cations counteracts the compaction process, reducing soil stability. Soil compaction is a complex process influenced by several factors, including compaction effort, method, water content, particle size distribution, and mineralogy. This study aimed to analyse these factors using a series of laboratory tests, including foundation indicators, MOD AASHTO compaction testing, and X-ray diffraction analysis, on residual soils from two TSF construction sites. The findings revealed that soils with high clay content tend to retain more water and have a higher optimum water content, adversely affecting their compaction properties. This study highlights the critical need to consider the mineralogical composition and weathering effects of residual soils in the design and construction of TSFs. By improving our understanding of these factors, we can enhance the stability of TSF foundations, reducing the likelihood of future failures. The insights gained from this research highlight the importance of thorough geotechnical assessments in the successful design and maintenance of TSFs.
In the summer of 2021, Greece experienced significant forest fires and mega-fires across multiple regions, leading to human casualties and damage to the natural environment, infrastructure, livestock, and agriculture. The current study aims to assess the ecosystem condition in terms of the natural regeneration and soil conditions of an area burnt by a forest fire (2021), specifically in the Ancient Olympia region situated in West Peloponnese (Ilia Prefecture), Greece. A standardized field sampling methodology was applied to record natural regeneration at chosen sites where a forest fire had also previously occurred (in 2007), resulting in the natural re-growth of the Pinus halepensis forest. Furthermore, an analysis was conducted on the geochemical, mineralogical, and sedimentological properties of soils obtained from this location. The findings of the research demonstrate the decline in the established natural regeneration of the Pinus halepensis forest and the overall tree layer. Species characteristic of post-fire ecological succession were observed in the shrub and herb layers, displaying varying coverage. The examination of soil mineralogy, sedimentology, and geochemistry indicated that the soil characteristics in the area are conducive to either natural or artificial regeneration. Ultimately, recommendations for landscape rehabilitation strategies are provided to inform decision-making processes, considering future climate conditions.
The effective separation of ore is based on two fundamental processes: liberation and separability. Liberation involves the reduction of size, yielding smaller particles with enhanced compositional homogeneity. Understanding liberation requires an understanding of rock breakage, as it impacts mineral liberation and helps identify ores suitable for pre-concentration. Non-random breakage, influenced by textural and mineral properties, introduces heterogeneity in mineral distribution across size fractions. Physical attributes, including ore and gangue mineralogy and texture, influence fractionation tendencies during breakage. Notably, the presence of mineralization in veins substantially assists early-stage liberation in mineral processing. The aim of this study is to develop a methodology that allows the prediction of natural fractionation tendencies based on geological, mineralogical, and textural data using Discrete Element Method (DEM) modeling. DEM simulations provide insights into granular material behavior, capturing phenomena such as crack initiation and propagation. The use of DEM, particularly with models such as the Flat Joint Model (FJM), enhances our understanding of rock damage mechanisms. In this paper, DEM is used to predict preferential grade by size deportment, and a numerical model is developed to reflect grade distributions across size fractions. A fragmentation analysis is conducted after rock breakage simulations using DEM to analyze the fragment sizes and grades and calculate the Response Rankings of synthetic specimens.
Freeze-thaw cycles are prevalent climatic phenomena with substantial effects on soils, leading to alterations in soil strength, stiffness, and hydraulic properties due to disruptions in the soil structure. With the ongoing climate change, weather patterns have grown progressively erratic, resulting in more frequent occurrences of extreme weather events, including heavy snowfall, intense rainfall, and windstorms, even in regions characterized typically with mild climates across the globe. The climate change can potentially threat manmade infrastructure constructed within or upon local soils, regardless of their susceptibility to freezing in temperate climates. The principal objective of this study is to assess the influence of freeze-thaw cycles on the California Bearing Ratio (CBR %) across 12 distinct soils with variations in granulometry and mineralogy. The freeze-thaw cycles resulted in a notable decrease in CBR (%) within the range of 40% to 70%. A strong inverse correlation with D50 was observed regarding the decrease in CBR (%). Nevertheless, it was discerned that the decrease in CBR (%) subsequent to freeze-thaw cycles varied among soil samples sharing identical D50 and liquid limit characteristics. The aim of this study is to enhance our comprehension of how freeze-thaw cycles can impact the bearing capacity of these soils, thereby providing essential insights for predicting their behavior and potential influence on infrastructure in the context of climate change.
In recent years, there has been an increasing interest in investigating the use of non-traditional additives for stabilizing problematic soils. As the demand for eco-friendly alternatives to cement rises, magnesium chloride, a widely used deicer and dust suppressor, has emerged as a potential choice. This study aims to provide a comprehensive understanding of the microstructural changes that occur and affect the macro behavior of treated bentonite (B) and yellow marl (YM). To achieve this, MgCl2 solution was added to the soils at 3, 6, 9, and 12 percent by dry weight of the soil, and samples were cured for 7, 14, and 28 days at 5 degrees C, 25 degrees C, and 35 degrees C. The mechanical properties of the treated soils were then evaluated using the unconfined compression test, direct shear test, and pressure chamber test (SWCC), while microstructural analysis techniques such as X-ray diffraction (XRD), scanning electron microscopy (SEM), energy-dispersive X-ray spectrometry (EDAX), and Fourier transform infrared spectroscopy (FTIR) were employed to examine the mechanism of MgCl2 stabilization. The results indicate that adding MgCl2 and extending the curing period significantly increased both soils' unconfined compressive strength (UCS). However, the UCS value decreased for treated samples cured at temperatures higher than 25 degrees C due to an incomplete cation exchange process and the reduction of apparent cohesion. A part of the gained strength from apparent cohesion and matric suction in the unsaturated samples was lost when the samples reached full saturation during the direct shear test. Changes in the particle size, pore size, and pore void distribution due to the MgCl2 stabilization affected the SWCCs of the treated soils. Microstructural analyses revealed the formation of magnesium hydration products, such as magnesium silicate hydrate (M-S-H) and magnesium aluminate hydrate (M-A-H), which contributed to the strength increase by increasing grain size, filling the pores, binding fine particles within coarse grains, and forming a flocculated structure through recrystallization of MgCl2 and the formation of cementitious gel. Additionally, for B, adding MgCl2 led to soil flocculation through ion exchange, while for YM, the same process occurred due to the greater surface tension of the saline solution encircling the particles.
Geomechanical parameters of intact metamorphic rocks determined from laboratory testing remain highly uncertain because of the great intrinsic variability associated with the degrees of metamorphism. The aim of this paper is to develop a proper methodology to analyze the uncertainties of geomechanical characteristics by focusing on three domains, i.e. data treatment process, schistosity angle, and mineralogy. First, the variabilities of the geomechanical laboratory data of Westwood Mine (Quebec, Canada) were examined statistically by applying different data treatment techniques, through which the most suitable outlier methods were selected for each parameter using multiple decision-making criteria and engineering judgment. Results indicated that some methods exhibited better performance in identifying the possible outliers, although several others were unsuccessful because of their limitation in large sample size. The well-known boxplot method might not be the best outlier method for most geomechanical parameters because its calculated confidence range was not acceptable according to engineering judgment. However, several approaches, including adjusted boxplot, 2MADe, and 2SD, worked very well in the detection of true outliers. Also, the statistical tests indicate that the best-fitting probability distribution function for geomechanical intact parameters might not be the normal distribution, unlike what is assumed in most geomechanical studies. Moreover, the negative effects of schistosity angle on the uniaxial compressive strength (UCS) variabilities were reduced by excluding the samples within a specific angle range where the UCS data present the highest variation. Finally, a petrographic analysis was conducted to assess the associated uncertainties such that a logical link was found between the dispersion and the variabilities of hard and soft minerals. (c) 2024 Institute of Rock and Soil Mechanics, Chinese Academy of Sciences. Production and hosting by Elsevier B.V. This is an open access article under the CC BY license (http://creativecommons.org/licenses/ by/4.0/).