This paper aims to develop geopolymer concrete (GPC) with flash-calcined soils cured under ambient conditions. Flash calcination is a heat thermal technique used to eliminate pollutants and organic content in excavated soils and allow them to be used in cementitious formulations. To develop GPC, the materials used in the development of the GP precursor binder should be rich in silicon (Si) and Aluminum (Al) that can react with alkaline silicates to yield Si-O-Al bonds that would form cementitious materials. The GP precursor binder is composed of Metakaolin (MK), flash-calcined soils, and granulated blast furnace slag (GBFS). The thermally treated soils are flash-calcined dredged sediments (FCS) and flash-calcined excavated clays (FCC) while potassium silicate is used as the alkaline reagent. This study aims to use the materials above to develop GPC cured under ambient conditions with high strength, good durability, and microstructure properties. Seven formulations are done to evaluate the effect of replacing MK with either FCS or FCC and GBFS on the mechanical compressive strength, water absorption, and freeze-thaw test. The findings reveal that using only metakaolin (MK0) in the formulation yielded the highest compressive strength. These results align with the porosity test outcomes, which show correlations between micropore and macropore percentages. Analysis of the durability freeze-thaw test suggests that as the proportion of macropores increases, formulations incorporating FCS and FCC exhibit improved resistance to extreme temperatures. Conversely, an increase in GBFS content leads to a finer microstructure and reduced resistance. Water absorption testing indicates that formulations with FCS and FCC display favorable sorptivity coefficients compared to MK0, with increased GBFS content enhancing durability. SEM/EDS and calorimetry tests were conducted to investigate the impact of substituting FCS and FCC for MK within the geopolymer matrix.

This paper presents a study on the potential of geopolymer (GP) as a substitute for ordinary Portland cement (OPC) in construction applications. OPC is widely used in construction due to its high strength and durability. However, manufacturing is extremely energy-intensive and produces large amounts of carbon dioxide (CO2) emissions. Also, In France, 130 million tons of excavated soils are generated each year [1] and classified as waste material without proper disposal methods. Therefore, the use of excavated clays coming from construction projects in GP formulations will have a positive impact on decreasing waste materials. Moreover, flash calcination used as heat thermal technique eliminate the organic matter and enhance the geopolymerization reaction with the alkaline reagent used in GP. On the other hand, GP are a type of alternative material made from industrial by-products such slags. This study used various methods to optimize GP mix design by evaluating the fresh and hardened properties. The results has shown that GP has a higher compressive strength than OPC in short term (between +5% and 76% at 1 day) and present a comparable strength in long term. The analysis of the microstructure throughout nuclear magnetic resonance (NMR), Fourier transform infrared (FTIR), X-ray diffraction (XRD) and Thermogravimetric analysis (TGA) has shown the GP designed has a stable reticulated polymeric structure. Mercury porosity has shown a finer nonometric porosity that corresponds to a compacted and fitted micelle structure. This study provides a solid contribution to the sustainability of the construction industry by developing a GP binder composed of flash-calcined excavated clay (FCC), metakaolin (MK), and slag (GBFS) that can achieve better results than OPC binder.