Black carbon (BC) is a major short-lived climate pollutant (SLCP) with significant climate and environmentalhealth impacts. This review synthesizes critical advancements in the identification of emerging anthropogenic BC sources, updates to global warming potential (GWP) and global temperature potential (GTP) metrics, technical progress in characterization techniques, improvements in global-regional monitoring networks, emission inventory, and impact assessment methods. Notably, gas flaring, shipping, and urban waste burning have slowly emerged as dominant emission sources, especially in Asia, Eastern Europe, and Arctic regions. The updated GWP over 100 years for BC is estimated at 342 CO2-eq, compared to 658 CO2-eq in IPCC AR5. Recent CMIP6-based Earth System Models (ESMs) have improved attribution of BC's microphysics, identifying a 22 % increase in radiative forcing (RF) over hotspots like East Asia and Sub-Saharan Africa. Despite progress, challenges persist in monitoring network inter-comparability, emission inventory uncertainty, and underrepresentation of BC processes in ESMs. Future efforts could benefit from the integration of satellite data, artificial intelligence (AI)assisted methods, and harmonized protocols to improve BC assessment. Targeted mitigation strategies could avert up to four million premature deaths globally by 2030, albeit at a 17 % additional cost. These findings highlight BC's pivotal roles in near-term climate and sustainability policy.
Light-absorbing carbonaceous aerosols, comprising black carbon (BC) and brown carbon (BrC), significantly influence air quality and radiative forcing. Unlike traditional approaches that use a fixed value of absorption & Aring;ngstrom exponent (AAE), this study investigated the absorption and optical properties of carbonaceous aerosols in Beijing for both local emission and regional transport events during a wintertime pollution event by using improved AAE results that employs wavelength-dependent AAE (WDA). By calculating the difference of BC AAE at different wavelengths using Mie theory and comparing the calculated results to actual measurements from an Aethalometer (AE31), a more accurate absorption coefficient of BrC can be derived. Through the analysis of air mass sources, local emission was found dominated the pollution events during this study, accounting for 81 % of all cases, while regional transport played a minor role. Carbonaceous aerosols exhibited a continuous increasing trend during midday, which may be attributed to the re-entrainment of nighttime-accumulated carbonaceous aerosols to the surface during the early planetary boundary layer (PBL) development phase, as the mixed layer rises, combined with the variation of PBL and anthropogenic activity. At night, variations in the PBL height, in addition to anthropogenic activities, effectively contributed to surface aerosol concentrations, leading to peak surface aerosol values during local pollution episodes. The diurnal variation of AAE470/880 exhibited a decreasing trend, with a total decrease of approximately 12 %. Furthermore, the BrC fraction showed a constant diurnal variation, suggesting that the declining AAE470/880 was primarily influenced by BC, possibly due to enhanced traffic contributions.
Permafrost degradation under climate warming plays a crucial role in hydrological and ecological processes, including the regional water cycle and terrestrial carbon balance. The Tibetan Plateau (TP), which contains the largest expanse of high-altitude permafrost globally, remains understudied in terms of how permafrost degradation affects surface water resources and regional carbon dynamics. Using permafrost simulation models and quantitative analysis, we assess the spatiotemporal impacts of permafrost degradation on surface water resources and carbon dynamics. In the inner endorheic regions of the TP, ground ice meltwater contributed 12.6% of the total lake volume increase from 2000 to 2020, accelerating lake expansion and affecting nearby infrastructure and ecosystems. Cryospheric meltwater accounted for 4.6% of total runoff in the source areas of the Yangtze, Yellow, Lancang, Yarlung Zangbo, and Nujiang Rivers in 2002-2018. This cryospheric meltwater contribution is projected to peak in the 2030s-2040s, followed by a decline, with potentially profound implications for downstream water availability. From 2000 to 2020, carbon sequestration of alpine grassland in permafrost regions is 1.05-1.29 Tg C a-1 in 2000-2020. This estimate is underestimated by approximately 35.5% to 48.1% without considering the impact of permafrost degradation. Top-down thawing of permafrost from 2002 to 2050 is projected to release 129.39 +/- 21.02 Tg C a-1 of thawed soil organic carbon (SOC), with 20.82 +/- 3.06 Tg C a-1 decomposed annually. Additionally, permafrost collapse and thermokarst lake are estimated to reduce ecosystem carbon sinks by 0.41 (0.29-0.52) Tg C a-1 in 2020. (c) 2025 The Authors. Published by Elsevier B.V. and Science China Press. This is an open access article under the CC BY license (http://creativecommons.org/licenses/by/4.0/).
Carbonaceous aerosols play a crucial role in air pollution and radiative forcing, though their light-absorbing and isotopic characteristics remain insufficiently understood. This study analyzes optical absorption and isotopic composition in PM10 and PM2.5 particles from primary emission sources, focusing on traffic-related and solid fuel categories. We analyzed key optical properties, including the Angstrom absorption exponent (AAE), the contributions of black carbon (BC) and brown carbon (BrC) to total light absorption and the mass absorption efficiencies (MAE) of carbonaceous aerosols. AAE values were lower for traffic emission sources (0.9 to 1.3) than solid fuel emission sources (1.5 to 3), with similar values for both particle sizes. BrC contributions were more prominent at shorter wavelengths and were notably higher in solid fuel emission sources (61% to 88%) than in traffic emission sources (8% to 40%) at 405 nm. MAE values of BC at 405 nm were 2 to 20 times higher than BrC across different emissions. Particle size significantly affect MAE(BC) with PM2.5 higher when compared to PM10. Emissions from diesel concentrate mixer and raw coal burning exhibited the highest MAE(BC) for PM2.5 and PM10, respectively. Conversely, Coke had the lowest MAE(BC) but the highest MAE(BrC) for both sizes. Traffic emissions showed more stable carbon isotope ratios (delta C-13) enrichment (-29 parts per thousand to -24 parts per thousand) than solid fuels (-31 parts per thousand to -20 parts per thousand). delta C-13 of solid fuel combustion, unlike traffic sources, is found to be independent of size variation. These findings underscore the importance of source and size-specific aerosol characterization for unregulated emission sources.
Permafrost peatlands store substantial amounts of carbon, though persistence of this soil carbon is unknown in a rapidly warming Arctic. To investigate potential carbon production from soils at different stages of permafrost degradation, we incubated soils from a palsa mire in northern Fennoscandia. Three soil horizons from four thaw stages were included within the transect, beginning with intact permafrost and ending in an established post-thaw wetland. Samples were incubated anaerobically for a year at different temperatures (4 degrees C, 20 degrees C) with the aim of investigating drivers of carbon degradation rates. Additional subsamples from the intact palsa were incubated under aerobic conditions, or inoculated with thermokarst pond water to further explore thaw processes on soil. Total CO2 and CH4 produced ranged from 9,910 +/- 626 (from the surface peat of the established post-thaw wetland, at 20 degrees C) to 1,921 +/- 126 mu g C g-1 DW (from the intermediate thaw stage of the palsa permafrost, incubated at 20 degrees C). The CH4 temperature sensitivity was markedly higher in permafrost soils, with Q 10 s more than four times larger than that of the active layer (active layer average: 1.7 +/- 1.6, permafrost average: 8.4 +/- 5). Methanogenesis generally increased with thaw, but the largest increase of cumulative methane production was between the wetland thaw stages (from 633 to 2,880 mu g CH4-C g-1 DW), where graminoids colonized the post-thaw environment. This uptick in CH4 production 30+ years after post-thaw wetland establishment implies that increases in CH4 production are largely due to vegetation inputs rather than thawed permafrost carbon contributions.
The present paper sets out a comparative analysis of carbon emission and economic benefit of different performance gradients solid waste based solidification material (SSM). The macro properties of SSM were the focus of systematic study, with the aim of gaining deeper insight into the response of the SSM to conditions such as freeze-thaw cycles, seawater erosion, dry-wet cycles and dry shrinkage. In order to facilitate this study, a range of analytical techniques were employed, including scanning electron microscopy (SEM), X-ray diffraction (XRD) and mercury intrusion porosimetry (MIP). The findings indicate that, in comparison with cement, the carbon emissions of SSM (A1) are diminished by 77.7 %, amounting to 190 kg/t, the carbon-performance ratio (24.4 kg/ MPa), the cost-performance ratio (32.1RMB/MPa) and the carbon-cost ratio (0.76kg/RMB) are reduced by 86 %, 56 % and 68 % respectively. SSM demonstrated better performance in terms of freeze-thaw resistance, seawater erosion resistance and dry-wet resistance when compared to cement. The dry shrinkage value of SSM solidified soil was reduced by approximately 35 % at 40 days compared to cement solidified soil, due to compensatory shrinkage and a reduction in pores. In contrast to the relatively minor impact of seawater erosion and the moderate effects of the wet-dry cycle, freeze-thaw cycles have been shown to cause the most severe structural damage to the micro-structure of solidified soil. The conduction of durability tests resulted in increased porosity and the most probable aperture. The increase in pores and micro-structure leads to the attenuation of macroscopic mechanical properties of SSM solidified soil. The engineering application verified that with the content of SSM of 50 kg/m, 4.5 % and 3 %, the strength, bearing capacity and bending value of SSM modified soil were 1.9 MPa, 180 kPa and 158, respectively in deep mixing piles, shallow in-situ solidification, and roadbed modified soil field.
The terrestrial program of the Arctic Challenge for Sustainability-II (ArCS II) is dedicated to clarifying the complex responses of Arctic boreal ecosystems and biogeochemical cycles to a warming climate. Focusing on ecosystem function, terrestrial greenhouse gas dynamics, and permafrost and biogeochemical cycles, ArCS II targets key challenges posed by climate change across terrestrial ecosystems. Biodiversity and ecosystem function research emphasizes the interactions between plant and soil microbial communities across Arctic boreal regions, with discoveries such as new fungal species contributing valuable information elucidating the status of Arctic ecosystems. Our study revealed that vegetation has a significant impact on the composition and network structure of microbial communities, and these interactions may influence ecosystem responses to environmental changes. Greenhouse gas dynamics were analyzed using long-term carbon and methane emissions data collected in boreal forests, tundra, wetlands, and glacial termini, as emissions from these regions can accelerate warming. Plant-mediated methane transport was identified as the primary process driving methane emission from wetlands, and elevated methane concentrations were detected in some glacial meltwaters. ArCS II advances permafrost modeling to assess the impacts of thawing on terrestrial processes, emphasizing freeze-thaw cycles and their impact on greenhouse gas dynamics. Excess ice formed within permafrost plays a role in suppressing permafrost warming and may induce anomalous variations in greenhouse gas emissions. Despite limitations imposed on field surveys by COVID-19, the ArCS II project elucidated ecosystem changes using long-term data. ArCS II terrestrial research lays a foundation for the exploration of climate impacts on Arctic boreal ecosystems.
Atmospheric brown carbon (BrC) from wildfires is a key component of light-absorbing carbon that significantly contributes to global radiative forcing, but its atmospheric evolution and lifetime remain poorly understood. In this study, we investigate BrC evolution by synthesizing data from one laboratory campaign and four aircraft campaigns spanning diverse spatial scales across North America. To estimate initial conditions for evaluating plume evolution, we develop a method to parametrize the emission ratios of BrC and other species using commonly measured inert tracers, acetonitrile and hydrogen cyanide. The evolution of BrC absorption in the free troposphere is characterized as a function of hydroxyl radical (OH) exposure, yielding an effective photochemical rate constant of 9.7-1.6 +4.8 x 10-12 cm3 molecule-1 s-1. The relatively slow reaction rate results in small BrC decay within the first few hours after emission, making it difficult to distinguish from source variability. This helps explain the absence of clear evolutionary trends in near-field studies. Assuming an OH concentration of 1.26 x 106 molecules cm-3, this rate constant corresponds to an e-folding lifetime of approximately 23 h. After extensive photooxidation (OH exposure similar to 1012 molecules cm-3 s), 4 +/- 2% of the emitted BrC persists, representing a recalcitrant fraction with potential long-term climate impacts. These results improve our understanding of BrC variability and photochemical processing and provide critical constraints for modeling its impacts on climate.
Permafrost thaw represents one of Earth's largest climate feedback risks, potentially releasing vast carbon (C) stores as greenhouse gases (GHG). However, our ability to predict emissions remains limited by poor understanding of how changing organic matter (OM) composition affects microbial carbon processing. We test a metabolism-centered redox framework, which views microbial processes as coupled oxidative-reductive reactions, to mechanistically explain how organic matter metabolite quality controls greenhouse gas production in permafrost-affected peatland ecosystems. Rather than relying solely on geochemical redox measurements, our approach examines how microbes balance electron flow through metabolic pathways. Using active layer peat (9-19 cm) from contrasting environments (bog and fen), we employed multi-omics approaches, including metabolomics, metagenomics, and metatranscriptomics, to link OM chemistry to microbial function. Our results reveal distinct dissolved organic matter metabolite composition, with fen systems enriched in compounds with higher substrate quality (low molecular weight (MW) sugars with high H:C ratios and low aromaticity) and bog systems dominated by compounds with lower substrate quality (high MW phenols with lower H:C ratios and higher aromaticity). In fen samples, these sugar-like compounds correlated with higher oxidative metabolism and methanogenesis, supported by increased glycolysis gene expression. Initially, electrons from increased oxidative metabolism were balanced through nitrate and sulfate reduction, but as these electron acceptors were depleted, methanogenesis increased to maintain redox balance. Fen samples showed rapid degradation of both high- and low-substrate-quality compounds, suggesting sufficient energy for efficient C cycling. Conversely, bog samples exhibited more polyphenolic compounds, lower glycolysis activity, and higher stress-related gene expression, suggesting energy was diverted towards cell maintenance under acidic conditions rather than C processing. This approach suggests that predicting greenhouse gas emissions requires an understanding of how organic matter quality shapes microbial energy allocation strategies, providing a mechanistic framework for improving emission predictions from permafrost-affected peatlands and similar ecosystems.
Soil salinization is a growing concern that degrades soil quality and inhibits agricultural productivity. Miscanthus species have received wide attention because of their high calorific potential, their value as an energy plant, and their ability to maintain high biomass accumulation. However, most studies focused on the biochemical and physiological responses to salt stress while neglecting the osmotic adjustment processes and the contribution of both organic and inorganic substances to these processes. This study evaluates the response mechanism of Miscanthus sinensis to salt stress (0-300 mM of NaCl) by evaluating the growth and photosynthetic parameters, photosynthetic response to light, and contribution of organic and inorganic substances to osmotic potential. The results revealed that M. sinensis adopted Na + compartmentalization and reallocation of biomass to the aboveground parts to mitigate the negative impact of salinity stress. Specifically, Na+ accumulated more in the root and leaf, with an increment magnitude of 75.4-173.9 and 56.7-217.1 times, respectively. This was supported by the changing trend of the stem/leaf ratio (25.1 %-55.9 %) compared to the root/shoot ratio (12.3 %-18.3 %). Also, salt-induced stress decreased the leaf's water content and water use efficiency as a result of low intracellular osmosis, and to mitigate osmotic damage, M. sinensis enhanced the accumulation of proline. These results offer theoretical and scientific insights into managing the cultivation and improving the yield of M. sinensis and other energy herbaceous plants in saline soils.
