Due to the lack of rock samples directly from the deep part of the Moon, experiments and numerical simulation are effective methods to understand the early evolution of the Moon. Since the 1970s, the Lunar Magma Ocean (LMO) evolution model has been verified and modified by a large number of experimental petrology and geochemical work. However, the original composition of the Moon and the depth of its magma ocean, which are the two most critical parameters of LMO models remain controversial. The different lunar crust thickness estimated from lunar seismic data compared to that estimated from gravity data, the volatile content of lunar samples, and the widespread of Mg and Al-rich spinet (Cr (#) <5) discovered from interpreting the new remote sensing data affect our assessment on the starting composition and the depth of LMO, and the fractional crystallization process thereafter. In this paper, we review a series of high temperature and high pressure experimental petrology and experimental geochemistry results on the Moon's early evolution by focusing on: (1) The influence of refractory elements and volatile content of LMO's composition and its depth on the thickness of lunar crust and the Moon's mineral constitution formed through early differentiation. (2) The rationality of stability of high pressure mineral garnet deep inside lunar mantle and it effect on the distribution of trace elements during the evolution of lunar. (3) The petrogenesis of the Moon's special components, including volcanic glasses and Mg-suite, and their indication on the composition of the Moon's deep interior. (4) The constraint of lunar core composition on the Moon's material source, especially the abundance of trace elements. Based on the latest observation and the new analysis results of lunar samples, we evaluate the existing LMO evolution models and propose a LMO model with garnet as an important constituent mineral inside the Moon. We also discuss the necessary work need to be done to improve the new LMO model.

Many space agencies have now consolidated road-maps foreseeing intensive Lunar exploration during this and the next decades. The new era of Moon exploration is seen as a precursor of future more ambitious Mars missions and as such will imply intensive in situ activities involving both humans and rovers. Although the operational concepts will substantially change with respect to the Apollo era and a more immersive situation awareness even of scintists on the ground segment can be easily foreseeable, the main science goals will be largely represented by the open questions leaved behind in the Seventies and only partly covered by the following orbital and limited rover missions. They include the understanding of Lunar crustal and mantle evolutions, a better definition of its inner structure, volcanism and cratering history and the assessment of the regolith properties. To these subjects can be added some important ones more related to future settlements such as the Lunar volatiles and in situ resources. All these goals will greatly benefit of the involvement of astronauts and the use of flexible and managiable instrumention that should guarantee a prompt and correct sampling although not a comprehensive catherization of the Lunar materials.

Volatile-bearing lunar surface and interior, giant magmatic-intrusion-laden near and far side, globally distributed layer of purest anorthosite (PAN) and discovery of Mg-Spinel anorthosite, a new rock type, represent just a sample of the brand new perspectives gained in lunar science in the last decade. An armada of missions sent by multiple nations and sophisticated analyses of the precious lunar samples have led to rapid evolution in the understanding of the Moon, leading to major new findings, including evidence for water in the lunar interior. Fundamental insights have been obtained about impact cratering, the crystallization of the lunar magma ocean and conditions during the origin of the Moon. The implications of this understanding go beyond the Moon and are therefore of key importance in solar system science. These new views of the Moon have challenged the previous understanding in multiple ways and are setting a new paradigm for lunar exploration in the coming decade both for science and resource exploration. Missions from India, China, Japan, South Korea, Russia and several private ventures promise continued exploration of the Moon in the coming years, which will further enrich the understanding of our closest neighbor. The Moon remains a key scientific destination, an active testbed for in-situ resource utilization (ISRU) activities, an outpost to study the universe and a future spaceport for supporting planetary missions.