The solidification effect of contaminated soil degrades under wet-dry (W-D) cycles and acid rain. Acidic dry-wet cycle tests for Cr-contaminated soil solidified by alkali-activated granulated blast furnace slag (GGBS) are carried out. Toxic leaching test and accelerated leaching test are performed to study the leaching characteristic and mechanism. Scanning electron microscopy and energy spectrum analysis are used to investigate the microscopic mechanism. The long-term stability is evaluated through the apparent diffusion coefficient. The results show that a few W-D cycles at pH=7 will cause additional hydraulic reaction of GGBS and thus reduce the leaching concentration of total Cr and Cr(VI). Along with W-D cycles more AFt is generated. The expansion of AFt results in micro-fracture and thus more Cr leaching. In acidic W-D cycles, AFt dissolves first, releasing Cr immobilized by ion exchange. With the increasing acidity, C-S-H gels dissolve and more gypsum is generated, resulting in more micro-fractures. Consequently, the encapsulation effect weakens, resulting in more Cr leaching. However, the C-A-S-H gels remain stable. The slopes of the logarithmic curves of cumulative leached fraction versus time range from 0.373 to 0.675. The errors of fitting by a pure-diffusion analytical solution are mainly below 0.5%, indicating that diffusion is the dominant leaching mechanism. However, after 18 W-D cycles at pH=3, the effect of dissolution increases and the diffusion-dominated criteria are not satisfied. The mobility of Cr under neutral, weak acidic, and strong acidic W-D cycles is low, moderate, and high, respectively. It is necessary to take measures to reduce acid rain infiltration and W-D cycles when utilizing solidified soil. This research provides a reference for evaluating the long-term stability of solidified contaminated soil.

Municipal solid waste incineration bottom ash (MSWIBA) emerges as a potential alternative to natural aggregates due to its similar mineral composition and engineering properties as embanking fillings. However, the instability and environmental pollution risks of MSWIBA limit its large-scale application. This study proposes to employ Enzyme Induced Carbonate Precipitation (EICP) technology to enhance the mechanical properties of MSWIBA and reduce its environmental impact. Initial analyses focused on the basic physicochemical properties and morphological changes of MSWIBA before and after modification. Then the modified MSWIBA exhibited improvements in shear resistance, resilient modulus, and permanent deformation behavior. It was also found that existing resilient modulus and permanent deformation predicting models for soils are applicable to EICPmodified MSWIBA. The column leaching tests were conducted on samples subjected and not subjected to freeze-thaw and dry-wet cycles. The results revealed the modified MSWIBA released reduced heavy metal concentrations in both water and acid leaches. These findings establish a solid theoretical foundation for employing EICP-modified MSWIBA as an embankment fill material, highlighting the potential for wider adoption of this eco-friendly alternative in road constructions.

Contaminant leaching from asphalt pavements poses a significant environmental concern, potentially damaging soil and groundwater quality. The growing interest in incorporating recycled materials in asphalt pavements has further raised concerns over the potential environmental hazards due to contaminant leaching. Consequently, this paper offers a comprehensive review of the literature over the past three decades structured into six sections: groundwater contamination via leaching, methodologies for evaluating leaching, analysis of contaminants, contaminants and leaching from road materials incorporating recycled waste, other factors affecting leaching of pollutants from asphalt pavements, and mathematical models to predict leaching from asphalt pavements. Despite the importance of addressing leaching issues, there is a lack of standardised leaching tests and guidelines specific to asphalt materials, limited attention to evaluating contaminants beyond heavy metals and PAHs in asphalt leachates, insufficient understanding of optimal instrument parameters for asphalt leachate analysis, and a scarcity of mathematical models to predict future leaching potential.