Current research predominantly emphasizes elemental carbon (EC) light absorption, while ignoring its relationship with aerosol hygroscopic scattering. In this study, concentrations and optical properties of aerosol components were measured during a full-year monitoring campaign at an urban site in Suzhou. Results from a multiple linear regression model suggested that secondary organic carbon was a primary contributor to high mass absorption efficiency of EC in summer. Through the estimation of aerosol scattering coefficients under both dry and ambient atmospheric conditions, it was found that hygroscopic growth accounted for more than 35.0 % of the total aerosol scattering coefficient. Hygroscopic growth of nitrate and sulfate enhanced their annual mean scattering contributions by 42.1 % and 45.2 %, respectively. A negative correlation between EC concentration and the hygroscopic growth factor (f(RH)) was observed under varying relative humidity (RH) conditions. Associated with the decrease in f(RH), reductions in PM2.5 scattering coefficients (14.0 f 2.2, 29.4 f 5.2, and 24.5 f 8.2 Mm-1) were linked to EC concentration increases of 0.37 f 0.1, 0.40 f 0.1, and 0.21 f 0.1 mu g/m3 under low, medium, and high RH conditions, respectively. An increase in EC concentration by 0.19-0.37 mu g/m3 elevated the PM2.5 absorption coefficient by 2.66-5.41 Mm-1, and reduced the scattering coefficient by 10.53-17.91 Mm-1. Collectively, increased EC concentrations reduced aerosol single scattering albedo (SSA), particularly under high RH conditions. This study reveals that EC not only reduces aerosol extinction coefficients but also shifts aerosol radiative forcing in a positive direction by suppressing hygroscopic scattering.
Amid global climate change, freeze-thaw cycles in cold regions have intensified, reducing the stability of infrastructures and significantly increasing the demand for grouting reinforcement. However, the deterioration in the durability of existing grouting materials under the combined effects of freeze-thaw cycles and low temperatures has become a major technical bottleneck restricting their application in cold regions. This paper focuses on polyurethane (PU) grouting materials with foaming and lifting characteristics, systematically reviewing the research progress and technical challenges associated with their engineering applications in cold regions. First, in terms of material composition and preparation, the core components and modified additives are detailed to establish a theoretical foundation for performance regulation. Second, addressing the application requirements in cold regions, standardized testing methods and comprehensive evaluation systems are summarized based on key indicators such as heat release temperature, impermeability, diffusion properties, mechanical strength, and expansion properties. Combined with microstructural characteristics, the deformation behavior and failure mechanisms of PU grouting materials under freeze-thaw cycles and salt-freezing environments are revealed. At the engineering application level, the challenges faced by PU grouting materials in cold regions-such as inhibited low-temperature reactivity and insufficient long-term durability-are highlighted. Finally, considering current research gaps, including the unclear mechanisms of microscopic dynamic evolution and the lack of studies on the combined effects of complex environments, future research directions are proposed. This paper aims to provide theoretical support for the development and application of PU grouting materials in cold-region geotechnical engineering.
Understanding the mechanical behaviour of water ice-bearing lunar soil is essential for future lunar exploration and construction. This study employs discrete element method (DEM) simulations, incorporating realistic particle shapes and a flexible membrane, to investigate the effects of ice content, initial packing density, and gravitational conditions on lunar soil behaviour. Initially, we calibrated DEM model parameters by comparing triaxial tests on lunar soil without ice to physical experiments and the angle of repose simulations, validating the accuracy of our approach. Building on this, we conducted simulations on water ice-bearing lunar soil, examining stress-strain responses, shear strain, bond breakage, deviatoric fabric, and N-ring structures. DEM simulations demonstrate that increasing ice content from 0 % to 10 % elevates peak strength from 85 kPa to 240 kPa in loose samples and from 0.2 MPa to 1.62 MPa in dense samples. This strengthening aligns with microstructural stabilization evidenced by 5-ring configurations and narrowed branch vector distributions. Strain field analysis reveals greater deformation magnitudes in icy regolith, suggesting a trade-off between enhanced load-bearing capacity and reduced ductility. These quantified mechanical responses, including strength gain, structural stabilization, and strain localization, reveal the dual engineering implications of water ice in lunar soil.
This study investigates the microhardness and geometric degradation mechanisms of interfacial transition zones (ITZs) in recycled aggregate concrete (RAC) exposed to saline soil attack, focusing on the influence of supplementary cementitious materials (SCMs). Ten RAC mixtures incorporating fly ash (FA), granulated blast furnace slag (GBFS), silica fume (SF), and metakaolin (MK) at 10 %, 15 %, and 20 % replacement ratios were subjected to 180 dry-wet cycles in a 7.5 %MgSO4-7.5 %Na2SO4-5 %NaCl solution. Key results reveal that ITZ's microhardness and geometric degradation decreases with exposure depth but intensifies with prolonged dry-wet cycles. The FAGBFS synergistically enhances ITZ microhardness while minimizing geometric deterioration, with ITZ's width and porosity reduced to 67.6-69.0 mu m and 25.83 %, respectively. In contrast, FA-SF and FA-MK exacerbate microhardness degradation, increasing porosity and amplifying microcrack coalescence. FA-GBFS mitigates the diffusion-leaching of aggressive/original ions and suppresses the formation of corrosion products, thereby inhibiting the initiation and propagation of microcracks. In contrast, FA-SF and FA-MK promote the formation of ettringite/gypsum and crystallization bloedite/glauberite, which facilitates the formation of trunk-limb-twig cracks.
The discrete element method (DEM) has demonstrated significant advantages in simulating soil-tool interaction and an appropriate contact model notable affected the simulation accuracy. The accuracy of numerical simulation is compromised due to the variations in soil properties when tillage implements are employed in clay-moist soil conditions. This study aims to establish a discrete element model of clay-moist soil based on the Edinburgh Elasto-Plastic Adhesion (EEPA) contact model. Calibration tests using a combination of direct shear tests and cone penetration tests were conducted to identify sensitive parameters that need to be calibrated in the model and analyze the effects of each parameter. The results indicated that contact plasticity ratio and surface energy had significant influence on representing the mechanical properties of clay-moist soil. Then, by utilizing scanning technology to acquire furrow shape data, soil bin test was conducted to validate the reliability of the calibration parameters. Using sensitive parameters as variables, the actual value of clay-moist soil with a moisture content of 33 % as the target value obtained from experimental tests. The optimal combination was: the coefficient of static friction of 0.45, the coefficient of rolling friction of 0.18, and the surface energy of 27.95 J.m-2, the contact plasticity ratio of 0.59. The relative error between the simulated draft force value and the actual measured value was 7.98 %, and the relative errors in the furrow type parameters did not exceed 5 %. The accuracy of the calibration results was verified through comparative analysis of simulation and empirical results. This study provides a scientific approach for employing DEM in modeling clay-moist soil-tool interaction.
In performance-based design, it is crucial to understand deformation characteristics of geocell layers in soil under footing loads. To explore this, a series of laboratory loading tests were carried out to investigate the influence of varying parameters on the strain levels within the geocell layer in a sandy soil under axial strip footing loading. The results were analyzed in terms of maximum strain levels, strain variation along the geocell layer and the correlation between horizontal and vertical strains. In this study, the maximum observed strain levels for geocellreinforced strip footing systems reached 2.3 % for horizontal (tensile) strain and 1.4 % for vertical (compressive) strain. Furthermore, most strain levels were concentrated within a distance of 1.5 times the footing width from the axis of strip footing. In geocell-reinforced footing systems, the interaction between horizontal and vertical strains becomes a key factor, with the ratio of horizontal to vertical cell wall strains ranging approximately from 1 to 2.5. The outcomes of this study are expected to contribute to the practical applications of geocell-reinforced footing systems.
This paper deals with the contribution of the soil-structure interaction (SSI) effects to the seismic analysis of cultural heritage buildings. This issue is addressed by considering, as a case study, the Mosque-Cathedral of Cordoba (Spain). This study is focussed on the Abd al-Rahman I sector, which is the most ancient part, that dates from the 8th century. The building is a UNESCO World Heritage Site and it is located in a moderate seismic hazard zone. It is built on soft alluvial strata, which amplifies the SSI. Since invasive tests are not allowed in heritage buildings, in this work a non-destructive test campaign has been performed for the characterisation of the structure and the soil. Ambient vibration tests have been used to calibrate a refined 3D macro-mechanical-based finite element model. The soil parameters have been obtained through an in situ geotechnical campaign, that has included geophysical tests. The SSI has been accounted for by following the direct method. Nonlinear static and dynamic time-history analyses have been carried out to assess the seismic behaviour. The results showed that the performance of the building, if the SSI is accounted for, is reduced by up to 20 % and 13 % in the direction of the arcades and in the perpendicular direction, respectively. Also, if the SSI is taken into account, the damage increased. This study showed that considering the SSI is important to properly assess the seismic behaviour of masonry buildings on soft strata. Finally, it should be highlighted that special attention should be paid to the SSI, which is normally omitted in this type of studies, to obtain a reliable dynamic identification of the built heritage.
Microbial Induced Calcium Carbonate Precipitation (MICP), recognized as a low-carbon and environmentally sustainable consolidation technique, faces challenges related to inhomogeneous consolidation. To mitigate this issue, this study introduces activated carbon into uranium tailings. The porous structure and adsorption capacity of activated carbon enhance bacterial retention time, increase the solidification rate, and promote the growth and distribution of calcium carbonate, resulting in more uniform consolidation and improved mechanical properties of the tailings. Additionally, a novel independently developed grouting method significantly enhances the mechanical strength of the tailing sand samples. To perform a micro-scale analysis of the samples, distinct activated carbon-tailings DEM models are constructed based on varying activated carbon dosages. Physical experiments and parameter calibration are employed to investigate the micro-mechanical properties, such as velocity field and force chain distribution. Experimental and simulation results demonstrate that incorporating activated carbon increases the calcium carbonate production during the MICP process. As the activated carbon content increases, the peak stress of the tailings initially rises and then declines, reaching its maximum at 1.5 % activated carbon content. At 100 kPa confining pressure, the peak stress is 2976.91 kPa, 1.23-1.59 times that of samples without activated carbon and 6.08-7.86 times that of unconsolidated samples. Micro-scale motion analysis reveals that particle movement is predominantly axial at the ends and radial near the central axis. The initial direction of the primary force chains aligns with the loading direction. Following failure, some primary force chains dissipate, while new chains form, predominantly along the axial direction and secondarily in the horizontal direction. Compared with samples without activated carbon, those containing activated carbon exhibit more uniform force chain distribution, higher stress levels, and greater peak stress. This study offers a novel approach to enhance the stabilization and solidification efficiency of MICP and establishes a DEM model that provides valuable insights into the structural deformation and micro-mechanical characteristics of MICPcemented materials.
Subsea pipelines in Arctic environments face the risk of damage from ice gouging, where drifting ice keels scour the seabed. To ensure pipeline integrity, burial using methods like ploughs, mechanical trenchers, jetting, or hydraulic dredging is the conventional protection method. Each method has capabilities and limitations, resulting in different trench profiles and backfill characteristics. This study investigates the influence of these trenching methods and their associated trench geometries on pipeline response and seabed failure mechanisms during ice gouging events. Using advanced large deformation finite element (LDFE) analyses with a Coupled Eulerian-Lagrangian (CEL) algorithm, the complex soil behavior, including strain-rate dependency and strainsoftening effects, is modeled. The simulations explicitly incorporate the pipeline, enabling a detailed analysis of its behavior under ice gouging loads. The simulations analyze subgouge soil displacement, pipeline displacement, strains, and ovalization. The findings reveal a direct correlation between increasing trench wall angle and width and the intensification of the backfill removal mechanism. Trench geometry significantly influences the pipeline's horizontal and vertical displacement, while axial displacement and ovalization are less affected. This study emphasizes the crucial role of trenching technique selection and trench shape design in mitigating the risks of ice gouging, highlighting the value of numerical modeling in optimizing pipeline protection strategies in these challenging environments.
Pile penetration in soft ground involves complex mechanisms, including significant alterations in the soil state surrounding the pile, which influence the pile negative skin friction (NSF) over time. However, the pile penetration process is often excluded from finite element analysis. This paper investigates the impact of pile penetration on the generation of NSF and dragload. A stable node-based smoothed particle finite element method (SNS-PFEM) framework is introduced for two-dimensional axisymmetric conditions and coupled consolidation, incorporating the ANICREEP model of soft soil with a modified cutting-plane algorithm. A field case study with penetration process is simulated to verify the numerical model's performance, followed by a parametric analysis on the effect of penetration rate on NSF during consolidation. Results indicate that without the pile penetration process in NSF analysis can result in an unsafely low estimation of NSF and dragload magnitudes. The penetration rate affects dragload only at the initial consolidation stage. As consolidation progresses, dragload converges to nearly the same magnitude across different rates. Additionally, current design methods inadequately predict the beta value (where beta is an empirical factor correlating vertical effective stress of soil with the pile skin friction) and its time dependency, for which a new empirical formula for the time-dependent beta value is proposed and successfully applied to other field cases.