Oppenheimer crater is a floor-fractured crater located within the South Pole-Aitken basin on the Moon, and exhibits more than a dozen localized pyroclastic deposits associated with the fractures. Localized pyroclastic volcanism on the Moon is thought to form as a result of intermittently explosive Vulcanian eruptions under low effusion rates, in contrast to the higher-effusion rate, Hawaiian-style fire fountaining inferred to form larger regional deposits. We use Lunar Reconnaissance Orbiter Camera images and Diviner Radiometer mid-infrared data, Chandrayaan-1 orbiter Moon Mineralogy Mapper near-infrared spectra, and Clementine orbiter Ultraviolet/visible camera images to test the hypothesis that the pyroclastic deposits in Oppenheimer crater were emplaced via Vulcanian activity by constraining their composition and mineralogy. Mineralogically, we find that the deposits are variable mixtures of orthopyroxene and minor clinopyroxene sourced from the crater floor, juvenile clinopyroxene, and juvenile iron-rich glass, and that the mineralogy of the pyroclastics varies both across the Oppenheimer deposits as a whole and within individual deposits. We observe similar variability in the inferred iron content of pyroclastic glasses, and note in particular that the northwest deposit, associated with Oppenheimer U crater, contains the most iron-rich volcanic glass thus far identified on the Moon, which could be a useful future resource. We propose that this variability in mineralogy indicates variability in eruption style, and that it cannot be explained by a simple Vulcanian eruption. A Vulcanian eruption should cause significant country rock to be incorporated into the pyroclastic deposit; however, large areas within many of the deposits exhibit spectra consistent with high abundances of juvenile phases and very little floor material. Thus, we propose that at least the most recent portion of these deposits must have erupted via a Strombolian or more continuous fire fountaining eruption, and in some cases may have included an effusive component. These results suggest that localized lunar pyroclastic deposits may have a more complex origin and mode of emplacement than previously thought. (C) 2016 Elsevier Inc. All rights reserved.

The surfaces of the large uranian satellites are characterized by a mixture of H2O ice and a dark, potentially carbon-rich, constituent, along with CO2 ice. At the mean heliocentric distance of the uranian system, native CO2 ice should be removed on timescales shorter than the age of the Solar System. Consequently, the detected CO2 ice might be actively produced. Analogous to irradiation of icy moons in the Jupiter and Saturn systems, we hypothesize that charged particles caught in Uranus' magnetic field bombard the surfaces of the uranian satellites, driving a radiolytic CO2 production cycle. To test this hypothesis, we investigated the distribution of CO2 ice by analyzing near-infrared (NIR) spectra of these moons, gathered using the SpeX spectrograph at NASA's Infrared Telescope Facility (IRTF) (2000-2013). Additionally, we made spectrophotometric measurements using images gathered by the Infrared Array Camera (IRAC) onboard the Spitzer Space Telescope (2003-2005). We find that the detected CO2 ice is primarily on the trailing hemispheres of the satellites closest to Uranus, consistent with other observations of these moons. Our band parameter analysis indicates that the detected CO2 ice is pure and segregated from other constituents. Our spectrophotometric analysis indicates that IRAC is not sensitive to the CO2 ice detected by SpeX, potentially because CO2 is retained beneath a thin surface layer dominated by H2O ice that is opaque to photons over IRAC wavelengths. Thus, our combined SpeX and IRAC analyses suggest that the near-surfaces (i.e., top few 100 mu m) of the uranian satellites are compositionally stratified. We briefly compare the spectral characteristics of the CO2 ice detected on the uranian moons to icy satellites elsewhere, and we also consider the most likely drivers of the observed distribution of CO2 ice. (C) 2015 Elsevier Inc. All rights reserved.

A thermophysical model is presented that considers surface roughness, cast shadows, multiple or single scattering of radiation, visual and thermal infrared self heating, as well as heat conduction in one or three dimensions. The code is suitable for calculating infrared spectral energy distributions for spatially resolved or unresolved minor Solar System bodies without significant atmospheres or sublimation, such as the Moon, Mercury, asteroids, irregular satellites or inactive regions on comet nuclei. It is here used to explore the effects of surface roughness on spatial scales small enough for heat conduction to erase lateral temperature gradients. Analytically derived corrections to one-dimensional models that reproduce the results of three-dimensional modeling are presented. We find that the temperature of terrains with such small-scale roughness is identical to that of smooth surfaces for certain types of topographies and non-scattering material. However, systematic differences between smooth and rough terrains are found for scattering materials, or topographies with prominent positive relief. Contrary to common beliefs, the roughness on small spatial scales may therefore affect the thermal emission of Solar System bodies. (C) 2014 Elsevier Inc. All rights reserved.